Citation: Xiao-Li GAO, Mei-Rong HAN, Hui-Fang REN, Si-Si FENG. Synthesis, Structures, Luminescence and Photocatalytic Properties of Three Lanthanide Complexes Based on Ditoluoyl-Tartrate[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 375-384. doi: 10.11862/CJIC.2021.033 shu

Synthesis, Structures, Luminescence and Photocatalytic Properties of Three Lanthanide Complexes Based on Ditoluoyl-Tartrate

1.
Department of Chemistry, Taiyuan Normal University, Jinzhong, Shanxi 030619, China
2.
Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Shanxi University, Taiyuan 030006, China

Corresponding author: Si-Si FENG, ssfeng@sxu.edu.cn
Received Date: 24 July 2020
Revised Date: 28 October 2020

Figures(8)

Three one-dimensional (1D) lanthanide complexes[Ln(HDTTA)₃(CH₃OH)₃]_n (Ln=Ce (1), Pr (2), Sm (3)) (D-H₂DTTA=(+)-di(p-toluoyl)-D-tartaric acid) were synthesized at room temperature and normal pressure. They were fully structurally characterized by IR, elemental analysis, single-crystal and powder X-ray diffraction. The structure analysis shows that complexes 1~3 are isomorphic. They belong to chiral R3 space group of trigonal system and display infinite 1D chains structure along c axis. Photoluminescence measurements indicated that D-H₂DTTA ligand can partly sensitize the f-f transition luminescence of Pr³⁺ and Sm³⁺ cations but Ce³⁺ at 609 nm, which is attributed to the mismatching between the excited state energy levels of metal cations and ligands. Additionally, Complex 1 exhibited photocatalytic property for the degradation of methylene blue under UV light irradiation in the solution. The photocatalytic performance was up to 76% within 160 min without any other reagents. CCDC: 2017862, 1; 2017863, 2; 2017864, 3.
- Ln³⁺ complexes,
- di(p-toluoyl) tartaric acid,
- crystal structure,
- luminescence,
- photocatalysis
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1.
沈阳化工大学材料科学与工程学院沈阳 110142