Citation: Yu LI, Hui-Feng JIANG, Xiao-Ling CHEN, Wen-Da QIU. Syntheses, Crystal Structures, and Photocatalytic Properties of Cobalt(Ⅱ) and Manganese(Ⅱ) Coordination Polymers Assembled from 4-((Carboxymethyl)thio)benzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 361-367. doi: 10.11862/CJIC.2021.028 shu

Syntheses, Crystal Structures, and Photocatalytic Properties of Cobalt(Ⅱ) and Manganese(Ⅱ) Coordination Polymers Assembled from 4-((Carboxymethyl)thio)benzoic Acid

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: Xiao-Ling CHEN, ggcxl@163.com Wen-Da QIU, qiuwd123@163.com
Received Date: 19 June 2020
Revised Date: 28 October 2020

Figures(11)

Two 2D cobalt(Ⅱ) and manganese(Ⅱ) coordination polymers, namely {[Co(μ₃-L)(4, 4'-bipy)]·H₂O}_n (1) and {[Mn(μ-L)(4, 4'-bipy)(H₂O)₂]·H₂O}_n (2), have been constructed hydrothermally using 4-((carboxymethyl)thio)benzoic acid (H₂L), 4, 4'-bipyridine(4, 4'-bipy), and cobalt or manganese chlorides. Single-crystal X-ray diffraction analyses reveal that 1 and 2 crystallize in the triclinic and monoclinic systems, space groups P1 and P2₁/c, respectively. Complexes 1 and 2 show two different 2D sheets composed of dimer Co(Ⅱ) or 1D Mn(Ⅱ) chain units. The structural difference of 1 and 2 is driven by the metal (Ⅱ) nodes. The photocatalytic properties of two complex were investigated, showing that 2 is a promising photocatalyst for the UV-light-driven degradation of methylene blue as a model organic dye pollutant. CCDC: 1967233, 1; 1967234, 2.
- coordination polymer,
- dicarboxylic acid,
- photocatalytic properties
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1.
沈阳化工大学材料科学与工程学院沈阳 110142