Citation: Miao-Ling HUANG, Geng-Geng LUO, Jin-Qing LIN. Synthesis, Crystal Structure and Fluorescence Properties of Cadmium Complexes of Pyridine-2-formaldehyde Hydrazone[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 251-258. doi: 10.11862/CJIC.2021.023 shu

Synthesis, Crystal Structure and Fluorescence Properties of Cadmium Complexes of Pyridine-2-formaldehyde Hydrazone

1.
Key Laboratory of Environmental Friendly Function Materials Ministry of Education, College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021, China
2.
College of Chemical Engineering and Materials, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: Jin-Qing LIN, linlab@hqu.edu.cn
Received Date: 7 August 2020
Revised Date: 27 October 2020

Figures(10)

Three complexes, [Cd(HL)Cl₂]₂ (1), [Cd(HL)₂Br₂] (2) and[Cd(HL)I₂] (3) (HL=2-(4-chlorophenoxy)-N'-(pyridin-2-ylmethylene)acetohydrazide), were synthesized using a common solution method. The crystal structure and properties were studied by X-ray single crystal diffraction, infrared spectrum, ultraviolet spectrum, fluorescence spectrum and thermogravimetric analysis. The analysis of single crystal diffraction structure shows that complex 1 belongs to monoclinic system, C2/c space group, and is a dimer bridged by chlorine ions. Complex 2 belongs to monoclinic system, P2₁/c space group. It is a butterfly shaped mononuclear molecule containing two organic ligands. The central Cd²⁺ ions of complexes 1 and 2 are in a distorted octahedral position. Complex 3 belongs to triclinic system, P1 space group, in which there is only one organic ligand. The coordination polyhedron of Cd²⁺ ion of complex 3 is distorted trigonal bipyramid. Solid fluorescence analysis showed that both ligand and complexes had strong fluorescence and emitted green light. CCDC: 2011521, 1; 2011522, 2; 2011523, 3.
- acylhydrazone,
- p-chlorophenoxyacetic acid,
- cadmium complex,
- crystal structure,
- fluorescence properties
1. [1]
  Purandara H, Raghavendra S, Sabine F, Prashant P, Thimme Gowad B, Dharmaprakash S M, Vishwanatha P. J. Mol. Struct., 2019, 1185:205-211 doi: 10.1016/j.molstruc.2019.02.079
2. [2]
  Burhan K, Muhammad K, Muhammad R S, Muhammad N T, Hafiz M A, Hossein A R A, Ajaz H. J. Mol. Struct., 2020, 1200:127-140 doi: 10.1016/j.molstruc.2019.127140
3. [3]
  Rosemberg F N R, Leonardo D A, Florisberto G S, Paulo S C, Wanderson C S, Kleber S M, Gilberto L B A, Clodoaldo V, Hamilton B N, Basílio B. PLoS ONE, 2017, 12(4):1-26
4. [4]
  Poonam R, Singh R N. Spectrochim. Acta Part A, 2015, 140:344-355 doi: 10.1016/j.saa.2014.12.080
5. [5]
  Hu J H, Li J B, Qi J, Sun Y. New J. Chem., 2015, 39:4041-4046 doi: 10.1039/C5NJ00089K
6. [6]
  Marko V R, Vukadin M L, Ljiljana S J, Vojislav S, Milan D J, Tatjana S, Ivana Z M, Ljiljana S V, Violeta M. Eur. J. Med. Chem., 2016, 115:75-81 doi: 10.1016/j.ejmech.2016.03.003
7. [7]
  Yu X F, Shi L Q, Ke S Y. Bioorg. Med. Chem. Lett., 2015, 25(24):5772-5776 doi: 10.1016/j.bmcl.2015.10.069
8. [8]
  Filho J M S, Leite A C L, Oliveira B G, Moreira D R M, Lima M S, Soares M B P, Leite L F C C. Bioorg. Med. Chem., 2009, 17:6682-6691 doi: 10.1016/j.bmc.2009.07.068
9. [9]
  Patole J, Sandbhor U, Padhye S, Dileep N D, Christopher E A, Annie P. Bioorg. Med. Chem. Lett., 2003, 13(1):51-55 doi: 10.1016/S0960-894X(02)00855-7
10. [10]
  Walcourt A, Loyevsky M, Lovejoy D B, Gordeuk V R, Richardson D R. Int. J. Biochem. Cell Biol., 2004, 36:401-407 doi: 10.1016/S1357-2725(03)00248-6
11. [11]
  Benessere V, Cucciolito M E, Esposito R, Lega M, Turco R, Ruffo F, Serio M D. Fuel, 2016, 171:1-4 doi: 10.1016/j.fuel.2015.12.040
12. [12]
  Diana R, Panunzi B, Shikler R, Nabha S, Caruso U. Inorg. Chem. Commun., 2019, 104:186-189 doi: 10.1016/j.inoche.2019.04.016
13. [13]
  Piscopo M, Trifuoggi M, Scarano C, Gori C, Giarra A, Febbraio F. Sci. Rep., 2018, 8(1):7414-7414 doi: 10.1038/s41598-018-25784-z
14. [14]
  WANG W W, WAMG Y, ZHANG L, Song Y F, Wu W N, Chen Z. Chinese J. Inorg. Chem., 2019, 35(3):563-568
15. [15]
  Kuppusamy S, Shovan K S, Ramalingam N, Ramasamy S, Balasubramanian M. J. Org. Chem., 2018, 83:10770-10775 doi: 10.1021/acs.joc.8b01377
16. [16]
  Jin Y X, Zhong A G, Zhang Y J, Pan F Y. J. Mol. Struct., 2011, 1002:45-50 doi: 10.1016/j.molstruc.2011.06.042
17. [17]
  RAO X J. Thesis for the Master of Huaqiao University. 2014.
18. [18]
  Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, German, 1997.
19. [19]
  Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, German, 1997.
20. [20]
  Ikai M, Ishikawa F, Aratani N, Osuka A, Kawabata S, Kajioka T. Adv. Funct. Mater., 2006, 16:515-519 doi: 10.1002/adfm.200500492
21. [21]
  YU S L, LI Y W. Spectral Analysis. 2nd ed. Chongqing:Chongqing University Press, 2000:9-11
22. [22]
  TANG B B. Thesis for the Doctorate of Beijing Institute of Technology. 2014.
23. [23]
  XU J G, WANG Z B. Fluorescence Analysis. 3rd ed. Beijing:Science Press, 2006:21-22
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沈阳化工大学材料科学与工程学院沈阳 110142