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Citation: Guo-Qiang LIU. Preparation and Electrocatalytic Activities for Oxygen Evolution Reaction of CoBx/Co3O4 Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 267-275. doi: 10.11862/CJIC.2021.022 shu

Preparation and Electrocatalytic Activities for Oxygen Evolution Reaction of CoBx/Co3O4 Catalyst

  • School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China

  • Corresponding author: Guo-Qiang LIU, gqliu@issp.ac.cn
  • Received Date: 21 August 2020
    Revised Date: 19 November 2020

Figures(6)

  • Herein, the room temperature treatment of Co3O4 nanorods via NaBH4 aqueous solution results in situ generation of amorphous CoBx nanosheets on nanorods (CoBx/Co3O4) electrocatalyst with abundant oxygen vacancies. The X-ray diffractometer (XRD), field emission scanning electron microscope (FESEM), transmission electron microscope (TEM), and X-ray photoelectron spectroscope (XPS) were applied to investigate the crystal structures, morphologies, element distribution, and chemical states of the prepared electrocatalysts. The activity, stability, and electrochemical impedance spectroscopy (EIS) were recorded by an electrochemical workstation. The amorphous CoBx and oxygen vacancies were formed on surface of Co3O4 nanorods as active sites after treatment via NaBH4. The CoBx/Co3O4 showed excellent performance for oxygen evolution reaction (OER) with lower overpotential of 298 mV than that of Co3O4 (346 mV) to achieve a current density of 10 mA·cm-2 in 1.0 mol·L-1 KOH.
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