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Citation: YAO Shou-Guang, DOU Fei, LIU Dun, CHENG Jie. Electrochemical Performance of Mn and Mg Co-doped Ni(OH)2[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 95-102. doi: 10.11862/CJIC.2021.014 shu

Electrochemical Performance of Mn and Mg Co-doped Ni(OH)2

  • 1.

    School of Energy and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

  • 2.

    Chilwee Power Co., Ltd., Huzhou, Zhejiang 313100, China

  • Corresponding author: YAO Shou-Guang, zjyaosg@126.com
  • Received Date: 16 July 2020
    Revised Date: 12 November 2020

Figures(7)

  • To reduce costs and improve performance of the positive electrode materials, the buffer solution method was used to prepare manganese and magnesium doped nickel hydroxide, labeled as Ni0.82Mn0.18-xMgx(OH)2 (x=0.06, 0.09, 0.12). XRD, XPS and SEM tests were used to characterize the crystal structure, manganese valence state and morphology of the samples. Cyclic voltammetry and constant current charge-discharge tests were used to study the influence of Mn and Mg doping ratio on the electrochemical performance of Ni(OH)2. The results showed that the samples doped Mn and Mg were all β-phase and the crystal particles were smaller; Ni0.82Mn0.09Mg0.09(OH)2 showed excellent electrode reaction reversibility and charge-discharge performance. Specific discharge capacity (290.6 mAh·g-1) of Ni0.82Mn0.09Mg0.09(OH)2 was better than that of the commercial β-Ni(OH)2 (281.1 mAh·g-1) at 100 mA·g-1; moreover, after cycling for 30 cycles at a current density of 500 mA·g-1, the specific discharge capacity of Ni0.82Mn0.09Mg0.09(OH)2 was no decay, indicating its cycle stability is better than that of the commercial β-Ni(OH)2.
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    1. [1]

      CHENG J. CN101127393. 2008-02-20.

    2. [2]

      Cheng J, Zhang L, Yang Y S, Yue H W, Gao P C, Xin D W. Electrochem. Commun., 2007, 9(11):2639-2642  doi: 10.1016/j.elecom.2007.08.016

    3. [3]

      Zhang L, Cheng J, Yang Y S, Yue H W, Xin D W, Gao P C. J. Power Sources, 2008, 179:381-387  doi: 10.1016/j.jpowsour.2007.12.088

    4. [4]

      Cheng J, Wen Y H, Cao G P, Yang Y S. J. Power Sources, 2011, 196(3):1589-1592  doi: 10.1016/j.jpowsour.2010.08.009

    5. [5]

      Wang Y X, Hu Z A, Wu H Y. Mater. Chem. Phys., 2011, 126(3):580-583

    6. [6]

      Zhang Q, Xu Y H, Wang X L. Mater. Chem. Phys., 2004, 86(2):293-297

    7. [7]

      CHANG Y Q, CHEN Y L, WANG H W, FU G R, JIN X Q, XIE L J, HU Z A. New Chemical Materials, 2011, 39(2):79-83
       

    8. [8]

      PAN Y, LEI H, GUO R G, HAN X, YU L M, JIANG W Q. Chemical Reagents, 2014, 36(10):949-952
       

    9. [9]

      WEN S S, LIANG X L, YAO J H, PAN G L, LI Y W, ZHANG L Z. Rare Metal Materials Engineering, 2015, 44(12):3151-3155
       

    10. [10]

      Wu X H, Feng Q P, Wang M, Huang G W. J. Power Sources, 2016, 329:170-178  doi: 10.1016/j.jpowsour.2016.08.072

    11. [11]

      LÜ X. Thesis for the Master of Kunming University of Science and Technology. 2017.

    12. [12]

      Miao C C, Zhu Y J, Huang L G, Zhao T Q. Ionics, 2015, 21(8):2295-2302  doi: 10.1007/s11581-015-1387-1

    13. [13]

      Zhao L, Liu Z H, Jin L. Trans. Nonferrous Met. Soc. China, 2013, 23(4):1033-1038  doi: 10.1016/S1003-6326(13)62563-7

    14. [14]

      Masound S, Hamideh S, Omid A, Fatemeh D. J. Cluster Sci., 2013, 24(1):365-376  doi: 10.1007/s10876-013-0558-3

    15. [15]

      Shangguan E B, Chang Z R, Tang H G, Yuan X Z, Wang H J. Int. J. Hydrogen Energy, 2010, 35(18):9716-9724  doi: 10.1016/j.ijhydene.2010.06.096

    16. [16]

      LI X F, LI Z, DONG H C, XIA T C. Journal of Zhengzhou University of Light Industry (Natural Science), 2012, 27(1):7-11
       

    17. [17]

      LI X F, LI Z, SONG Y H, DONG H C, XIA T C. Chinese Journal of Power Sources, 2013, 37(2):240-242, 300
       

    18. [18]

      HAN E S, KANG H X, DONG Q, WEI Z H, YUAN Z Q. Chinese Journal of Applied Chemistry, 2007(9):84-87
       

    19. [19]

      WANG X, FU X Z, LIANG Y, LIAO D W. Chinese Journal of Power Sources, 2007(9):732-735
       

    20. [20]

      LIU C J, CHEN S J, LI P P. Rare Metal Materials Engineering, 2012, 41(S2):348-352
       

    21. [21]

      CHEN J M, SUN J T, SONG Y H. Journal of Synthetic Crystals, 2016(6):1539-1543
       

    22. [22]

      YAO S G, DOU F, XING R Y, CHENG J, XIAO M. Chinese J. Inorg. Chem., 2019, 35(8):1403-1410
       

    23. [23]

      PAN G X, CAO F, TANG P S, CHEN H F, XU M H, TONG Y H. Journal of Minerals, 2012, 32(2):244-248
       

    24. [24]

      XIAO M, XING R Y, YAO S G, CHENG J, SHEN Y J, YANG Y S. J. Inorg. Mater., 2019, 34(7):703-708
       

    25. [25]

      WANG J R, GONG J B, YANG Z Y. Powder Metallurgy Industry, 2012, 22(2):22-26
       

    26. [26]

      ZHI H J. Xinjiang Youse Jinshu, 2003(1):25-27

    27. [27]

      PENG M X, SHEN X Q, WEI Y H. Materials Reports, 2007, 22(11):121-124
       

    28. [28]

      Klug H P, Alexander L E C. X-ray Diffraction Procedures for Poly-crystalline and Amorphous Materials. 2nd ed. New York; Wiley-Inter-science, 1974:511-517

    29. [29]

      Meyer M, Bée A, Talbot D, Cabuil V, Boyer J M, Répetti B, Garrigos R. J. Colloid Interface Sci., 2004, 277:309-315

    30. [30]

      LI Y J, HUANG Y G, OU L F, YANG W, FENG Y Y, LU Z T. Carbon Techniques, 2019, 38(1):28-31, 40
       

    31. [31]

      SUN H F, JIANG W Q, YU L M, FU Z Z, GUO R G, LI T, YANG H. Materials Reports, 2011, 25(4):49-52
       

    32. [32]

      WANG Y M, ZHANG Y L, MA L L, LEI D, WEI Z G. Journal of Lanzhou University of Technology, 2014, 40(3):5-9
       

    33. [33]

      LI X S, HAO W X, ZHANG Y Q, MENG J, YU H Y. J. Funct. Mater., 2016, 8(47):8200-8204, 8210
       

    34. [34]

      LUO F C, CHEN Q Y, LI X H. Chinese Journal of Power Sources, 2007, 31(8):640-643
       

    35. [35]

      WU M Y. Thesis for the Master of Zhejiang University. 2006.

    36. [36]

      DENG M M, ZHANG D W, SHAO Y, HE X D, CEHN C H. Chin. J. Chem. Phys., 2020, 33(4):485-494
       

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