Citation: LIU Heng-Fa, XIE Yu, LIU Qi, CHENG Gao, SUN Ming, YU Lin. Preparation, Characterization and Catalytic Activity of 3D Heterogeneous α-MnO₂@Co₃O₄ Material[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 47-54. doi: 10.11862/CJIC.2021.003 shu

Preparation, Characterization and Catalytic Activity of 3D Heterogeneous α-MnO₂@Co₃O₄ Material

School of Chemical Engineering and Light Industry, Key Laboratory of Clean Chemistry Technology of Guangdong Regular Higher Education, Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: SUN Ming, sunmgz@gdut.edu.cn
Received Date: 8 June 2020
Revised Date: 21 September 2020

Figures(6)

The α-MnO₂ nanowires were used as the substrates for the in-situ growth of ZIF-67, and then converted into 3D α-MnO₂@Co₃O₄ heterogeneous material by calcination, and its catalytic combustion of toluene performance was studied. The results show that Co₃O₄ nanoparticles with a particle size of about 12 nm grew uniformly on the outer surface of MnO₂ nanowires, forming a heterogeneous interface. The composite material has better low-temperature reducibility and possesses more surface-active oxygen species. Compared with α-MnO₂ nanowires, α-MnO₂@Co₃O₄ exhibited more excellent toluene catalytic combustion performance with an ignition temperature (10% conversion) T₁₀ of 202℃ and a complete combustion temperature (90% conversion) T₉₀ of 235℃.
- manganese oxide,
- heterogeneous structure,
- controlling synthesis,
- catalytic combustion
1. [1]
  Huang N, Qu Z, Dong C, Qin Y, Duan X. Appl. Catal. A, 2018, 560:195-205 doi: 10.1016/j.apcata.2018.05.001
2. [2]
  Sun M H, Huang S Z, Chen L H, Li Y, Yang X Y, Yuan Z Y, Su B L. Chem. Soc. Rev., 2016, 45(12):3479-3563
3. [3]
  Li X, Yu J, Jaroniec M. Chem. Soc. Rev., 2016, 45(9):2603-2636
4. [4]
  ZHANG D F, NIU L Y, GUO L. Acta Phys.-Chim. Sin., 2010, 26(11):2865-2876 doi: 10.3866/PKU.WHXB20101104
5. [5]
  Miao Q, Du Y, Wang G, Sun Z, Zhao Y, Zhang S. J. Mater. Chem. A, 2019, 7(11):5967-5980
6. [6]
  CHENG H, XIE J, CHEN Z, TU J, CAO G S, ZHAO X B. Chinese J. Inorg. Chem., 2018, 34(6):1173-1182
7. [7]
  ZHUANG X, PAN S, WANG Z H, WANG B, TANG L D. Journal of Functional Materials, 2020, 51(2):2126-2130 doi: 10.3969/j.issn.1001-9731.2020.02.020
8. [8]
  Cui C Q, Du G J, Zhang K, An T, Li B, Liu X G, Liu Z L. J. Alloys Compd., 2020, 814:152239-152246
9. [9]
  Han L J, Tang P Y, Zhang L. Nano Energy, 2014, 7:42-51
10. [10]
  Li Z, Lian X, Wu M, Zheng F, Gao Y, Niu H. Dalton Trans., 2020, 49(20):6644-6650 doi: 10.1039/D0DT00980F
11. [11]
  Liu H, Cao K, Li W, Han Q, Zheng R, Shu J, Jiao L. J. Power Sources, 2019, 437:226904 doi: 10.1016/j.jpowsour.2019.226904
12. [12]
  Pan L, Wang K X, Zhu X D, Xie X M, Liu Y T. J. Mater. Chem. A, 2015, 3(12):6477-6483 doi: 10.1039/C5TA00266D
13. [13]
  Lyu Y, Li C, Du X, Zhu Y, Zhang Y, Li S. Environ. Sci. Pollut. Res. Int., 2020, 27:2482-2501 doi: 10.1007/s11356-019-07037-2
14. [14]
  He C, Cheng J, Zhang X, Douthwaite M, Pattisson S, Hao Z. Chem. Rev., 2019, 19(7):4471-4568
15. [15]
  Lan B, Sun M, Lin T, Cheng G, Yu L, Peng S M, Xu J. Mater. Lett., 2014, 121:234-237 doi: 10.1016/j.matlet.2014.01.055
16. [16]
  Wang Q, Gao F, Xu B, Cai F, Zhan F, Gao F, Wang Q. Chem. Eng. J., 2017, 327:387-396 doi: 10.1016/j.cej.2017.06.124
17. [17]
  Wang F, Liu Z B, Wang K X, Zhu X D, Fan X H, Gao J, Feng Y J, Sun K N, Liu Y T. Chem. Commun., 2018, 54:5138-5141
18. [18]
  Wang C, Zhu X D, Mo Y C, Wang F, Gao X T, Qiu S Y, Le S R, Sun K N. Chem. Commun., 2019, 55:1237-1240 doi: 10.1039/C8CC09699F
19. [19]
  Chang T, Shen Z, Huang Y, Lu J, Ren D, Sun J, Cao J, Liu H. Chem. Eng. J., 2018, 348:15-25
20. [20]
  FENG Y N, ZENG Y Q, JIANG W, JI W J. Chinese J. Inorg. Chem., 2019, 35(7):1230-1238
21. [21]
  Yu L, Diao G, Ye F, Sun M, Zhou J, Li Y, Liu Y. Catal. Lett., 2010, 141:111-119
22. [22]
  Reddy V G, Jampaiah D, Chalkidis A, Sabri Y M, Mayes E L H, Bhargava S K. Catal. Commun., 2019, 130:105763
23. [23]
  Tang W, Yao M, Deng Y, Li X, Han N, Wu X, Chen Y. Chem. Eng. J., 2016, 306:709-718 doi: 10.1016/j.cej.2016.07.107
24. [24]
  Sun M, Li W P, Zhang B T, Cheng G, Lan B, Ye F, Zheng Y Y, Cheng X L, Yu L. Chem. Eng. J., 2018, 331:626-635
1. [1]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
2. [2]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
7. [7]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
8. [8]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
9. [9]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
10. [10]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
11. [11]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
12. [12]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
13. [13]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
14. [14]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
15. [15]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
16. [16]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
19. [19]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
20. [20]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1729)
HTML views(451)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation, Characterization and Catalytic Activity of 3D Heterogeneous α-MnO2@Co3O4 Material

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation, Characterization and Catalytic Activity of 3D Heterogeneous α-MnO₂@Co₃O₄ Material