Citation: RUAN Ding-Shan, LIN Bo, HU Guo-Rong, DU Ke, LIU Wei-Jian, CHEN Xi-Wen, XU Shuai-Jun, LUO Cui-Ping, MIAO Jian-Lin, CHEN Xi, LI Chang-Dong. Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi_0.88Co_0.06Mn_0.06O₂ for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2289-2298. doi: 10.11862/CJIC.2020.263 shu

Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi_0.88Co_0.06Mn_0.06O₂ for Lithium-Ion Batteries

RUAN Ding-Shan ^1,2,# ,
LIN Bo ^2,# ,
HU Guo-Rong ^1,, ,
DU Ke ¹ ,
LIU Wei-Jian ² ,
CHEN Xi-Wen ² ,
XU Shuai-Jun ² ,
LUO Cui-Ping ² ,
MIAO Jian-Lin ² ,
CHEN Xi ² ,
LI Chang-Dong ²

1.
School of Metallurgy and Environment, Central South University, Changsha 410083, China
2.
Guangdong Brunp Recycling Technology Co., Ltd., Foshan, Guangdong 528100, China

Corresponding author: HU Guo-Rong, 1044283793@qq.com
Received Date: 28 May 2020
Revised Date: 16 September 2020

Figures(10)

The precursor Ni_0.88Co_0.06Mn_0.06(OH)₂ was prepared by coprecipitation method. Ni-rich material with good primary particles dispersion were synthesized by high temperature solid-state sintering. The effects of ZrO₂ and WO₃ doped on the primary particles morphology and electrochemical properties of cathode materials was explored. The results showed that Zr doped had little effect on the morphology of LiNi_0.88Co_0.06Mn_0.06O₂ (NCM-Z), especially on the size of primary particles, but it could improve the cycle performance of the material. When W was introduced to form Zr and W co-doped, the primary particles of NCM-ZW obtained become smaller obviously, and the morphology of the material changed from dispersed primary particles to secondary aggregates, so W could inhibit the crystal growth. Furthermore, in order to synthesize Zr and W co-doped Ni-rich material with good primary particles dispersion, the influence of sintering temperature on the synthesis of Ni-rich material was studied. Finally, the Ni-rich material with primary particles dispersion morphology could be obtained by sintering at 900 ℃ for 12 hours. XRD results showed that Zr and W co-doped sample which was sintered at 900 ℃ had batter layered structure and lower cation mixing. The first discharge capacity of the sample was 203.7 mAh·g^-1 at 0.1C. In addition, the capacity was 151.2 mAh·g^-1 at 5C, after 100 cycles, the retention rate of discharge capacity was 84.6%.
- Li-ion battery,
- cathode material,
- primary particles,
- Zr-doped,
- W-doped
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi0.88Co0.06Mn0.06O2 for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi_0.88Co_0.06Mn_0.06O₂ for Lithium-Ion Batteries