Citation: GAO Zi-Cheng, LIU Jing, REN Zhi-Bo, SUN Xiao, XIA Yun-Sheng. Preparation Methods of Co_xZr_1-xO₂ Catalysts and Their Properties of Oxidizing Toluene and Formaldehyde[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2340-2348. doi: 10.11862/CJIC.2020.260 shu

Preparation Methods of Co_xZr_1-xO₂ Catalysts and Their Properties of Oxidizing Toluene and Formaldehyde

College of Chemistry and Materials Engineering, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: XIA Yun-Sheng, xiayunsheng@bhu.edu.cn
Received Date: 30 April 2020
Revised Date: 14 October 2020

Figures(8)

Co_xZr_1-xO₂ catalysts were prepared by precipitation, hydrothermal, thermal decomposition and impregnation methods. The physicochemical properties of the catalysts were characterized by thermogravimetric (TG), X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), N₂ adsorption/ desorption test. The results showed that the cobalt species and zirconium species on the catalysts prepared by hydrothermal method had good dispersion, uniform spherical particles, and large specific surface area up to 102 m²·g^-1, and well-developed pore structure. The activity of oxidized toluene and formaldehyde on the catalyst Co_xZr_1-xO₂-H (1 :1) prepared by hydrothermal method consisting of Co and Zr was better than that of other catalysts. The apparent activation energies were 65.2 and 53.6 kJ·mol^-1. The excellent catalytic performance of Co_xZr_1-xO₂-H (1:1) was associated with the species dispersion, strong synergistic effect, surface area and pore structure. The well-controlled method for creation of Co-Zr catalysts with good physicochemical properties could be adopted for the generation of other catalytic materials with mixed metal oxides.
- heterometallic compound oxide,
- heterogenous catalysis,
- porous materials,
- volatile organic compounds oxidation,
- synthesis methods
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Preparation Methods of CoxZr1-xO2 Catalysts and Their Properties of Oxidizing Toluene and Formaldehyde

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Preparation Methods of Co_xZr_1-xO₂ Catalysts and Their Properties of Oxidizing Toluene and Formaldehyde