Citation: YANG Jian-Hui, MENG Xiang-Yu, TANG Ming-Yu, ZHOU Jie, SUN Yue-Ming, DAI Yun-Qian. Controllable Preparation of High Concentration Nitrogen-Doped Porous Graphene toward Enzyme-like Catalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2315-2324. doi: 10.11862/CJIC.2020.259 shu

Controllable Preparation of High Concentration Nitrogen-Doped Porous Graphene toward Enzyme-like Catalytic Properties

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: DAI Yun-Qian, daiy@seu.edu.cn
Received Date: 6 July 2020
Revised Date: 8 September 2020

Figures(8)

Graphene oxide (GO) was synthesized by modified Hummer's method. Nitrogen-doped reduced graphene oxide (N-RGO) meshes with enriched nano-pores were prepared through one-step and mild hydrothermal reaction, by using ammonium hydroxide as the nitrogen-dopant source. The N-RGO exhibited high enzyme-like catalytic activity and could catalyze the organic compounds to induce chromogenic reaction, such as 3, 3', 5, 5'-tetramethylbenzidine (TMB), o-phenylenediamine (OPD) and 2, 2'-azino-di(3-ethylbenzothiazoline sulfonic acid) (ABTS), etc. The N-RGO meshes were systematically characterized by transmission electron microscope (TEM), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Control experiments revealed that the catalytic oxidation of TMB by NRGO was processed by an effective 4-electron transfer reaction involving oxygen. Catalytic performance indicated that the N-RGO meshes had stronger tolerance than horseradish peroxidase (HPR), which maintained catalytic activity in a wider range (temperature of 25~85 ℃, pH value of 4~7, and NaCl concentration of 0~100 mmol·L^-1). From the fitting calculation by using the Michaelis-Menten model, the N-RGO meshes generated in optimized GO concentration of 5 mg·mL^-1 possessed the lowest Michaelis constant (K_m≈0.2 mmol·L^-1) and the highest reaction velocity (v_max≈0.07 μmol·L^-1).
- physical chemistry,
- enzyme-like catalysis,
- spectroscopy,
- nitrogen-doped graphene
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