Citation: ZHOU Meng-Xue, REN Ning, ZHANG Jian-Jun. Four Rare Earth Complexes with Chlorinated Carboxylic Acids and Bipyridine Ligands: Crystal Structures, Thermal Analysis and Luminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2349-2358. doi: 10.11862/CJIC.2020.258 shu

Four Rare Earth Complexes with Chlorinated Carboxylic Acids and Bipyridine Ligands: Crystal Structures, Thermal Analysis and Luminescence Properties

ZHOU Meng-Xue ^1,2 ,
REN Ning ^3,, ,
ZHANG Jian-Jun ^1,2,,

1.
Testing and Analysis Center, Hebei Normal University, Shijiazhuang 050024, China
2.
College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China
3.
College of Chemical Engineering & Material, Hebei Key Laboratory of Heterocyclic Compounds, Handan University, Handan, Hebei 056005, China

Corresponding author: REN Ning, ningren9@163.com ZHANG Jian-Jun, jjzhang6@126.com
Received Date: 29 April 2020
Revised Date: 21 September 2020

Figures(10)

Four new complexes were successfully synthesized by solvothermal method or conventional solution method, namely [Ln₂(5, 5'-DM-2, 2'-bipy)₂(3, 4-DClBA)₆(H₂O)(C₂H₅OH)] (Ln=Sm (1), Eu (2)) and [Ln(5, 5'-DM-2, 2'-bipy) (3, 5-DClBA)₃]₂ (Ln=Sm (3), Eu (4); 3, 4-HDClBA=3, 4-dichlorobenzoic acid, 3, 5-HDClBA=3, 5-dichlorobenzoic acid, 5, 5'-DM-2, 2'-bipy=5, 5'-dimethyl-2, 2'-bipyridine). Complexes 1 and 2 are isostructure and each metal center is eight-coordinated forming a distorted square antiprismatic. Complexes 1 and 2 are connected to form 2D supermolecular structure by C-H…Cl hydrogen bonding and π-π interactions. The geometry of complex 3 is a nine coordinated distorted monocapped square antiprismatic, and the two-dimensional supramolecular structure is formed by different π-π stacking interactions between molecules. Thermogravimetric-infrared combined technology revealed the thermal stability and thermal decomposition mechanism of complexes 1~4. The fluorescence and lifetime of complexes 2 and 4 were studied. The results showed that both complexes could emit the characteristic fluorescence of Eu³⁺ ions. CCDC: 1939324, 1; 1939325, 2; 1939326, 3.
- rare earth complexes,
- synthesis,
- crystal structures,
- thermal analysis,
- luminescent properties
1. [1]
  Allendorf M D, Bauer C A, Bhakta R K, et al. Chem. Soc. Rev., 2009, 38:1330-1352 doi: 10.1039/b802352m
2. [2]
  Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
3. [3]
  Jia L N, Hou L, Wei L, et al. Cryst. Growth. Des., 2013, 13:1570-1576 doi: 10.1021/cg301810y
4. [4]
  Luo Y D, Sun G M, Li D M, et al. Inorg. Chem. Commun., 2011, 14:778-780 doi: 10.1016/j.inoche.2011.03.014
5. [5]
  Andiappan K, Sanmugam A, Deivanayagam E, et al. Int. J. Biol. Macromol., 2019, 124:403-410 doi: 10.1016/j.ijbiomac.2018.11.251
6. [6]
  Lima P P, Paz F A A, Brites C D S, et al. Org. Electron., 2014, 15:798-808 doi: 10.1016/j.orgel.2014.01.009
7. [7]
  Jiang H L, Xu Q. Chem. Commun., 2011, 47:3351-3370 doi: 10.1039/c0cc05419d
8. [8]
  Hua Y R, Flood A H. Chem. Soc. Rev., 2010, 39:1262-1271 doi: 10.1039/b818033b
9. [9]
  Heffern M C, Matosziuk L M, Meade T J. Chem. Rev., 2014, 114:4496-4539 doi: 10.1021/cr400477t
10. [10]
  Ge Y, Cui Y F, Huang Y, et al. Polyhedron, 2019, 159:64-71 doi: 10.1016/j.poly.2018.11.052
11. [11]
  Ahmed Z, Iftikhar K. Inorg. Chem., 2015, 54:11209-11225 doi: 10.1021/acs.inorgchem.5b01630
12. [12]
  Bernini M C, Gomez G E, Brusau E V, et al. Isr. J. Chem., 2018, 58:1044-1061 doi: 10.1002/ijch.201800095
13. [13]
  Bunzli J C, Piguet C. Chem. Soc. Rev., 2005, 34:1048-1077 doi: 10.1039/b406082m
14. [14]
  He D H, Di Y Y, Tan Z C, et al. Sol. Energy Mater. Sol. Cells, 2011, 95:2897-2906 doi: 10.1016/j.solmat.2011.06.014
15. [15]
  He M, Chen Z, Pineda E M, et al. Eur. J. Inorg. Chem., 2016, 2016:5512-5518 doi: 10.1002/ejic.201600851
16. [16]
  Carter K P, Pope S J A, Cahill C L. CrystEngComm, 2014, 16:1873-1884 doi: 10.1039/c3ce42267d
17. [17]
  Carter K P, Thomas K E, Pope S J, et al. Inorg. Chem., 2016, 55:6902-6915 doi: 10.1021/acs.inorgchem.6b00408
18. [18]
  Carter K P, Zulato C H F, Cahill C L. CrystEngComm, 2014, 16:10189-10202 doi: 10.1039/C4CE01806K
19. [19]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
20. [20]
  Wang Y, Jin C W, He S M, et al. J. Mol. Struct., 2016, 1125:383-390 doi: 10.1016/j.molstruc.2016.07.007
21. [21]
  Wu J C, Li H, Ren N, et al. J. Rare Earths, 2016, 34:1083-1088 doi: 10.1016/S1002-0721(16)60138-2
22. [22]
  Liu J Y, Ren N, Zhang J J, et al. Ind. Eng. Chem. Res., 2013, 52:6156-6163 doi: 10.1021/ie400228j
23. [23]
  Wu J C, Shi Q, Geng L N, et al. J. Therm. Anal. Calorim., 2017, 131:2993-3001
24. [24]
  ZHOU Meng-Xue, REN Ning, ZHANG Jian-Jun. Acta Phys.-Chim. Sin., DOI: 10.3866/PKU.WHXB202004071
25. [25]
  Zhu M M, Ren N, Zhang J J, et al. Appl. Organomet. Chem., 2018, 32:e4438 doi: 10.1002/aoc.4438
26. [26]
  Zhu M M, Ren N, Zhang J J. Inorg. Chim. Acta, 2018, 480:140-148 doi: 10.1016/j.ica.2018.05.022
27. [27]
  Wu X F, Ba Y X, Wang X, et al. Bioresour. Technol., 2018, 266:407-412 doi: 10.1016/j.biortech.2018.07.005
28. [28]
  Qi X X, Ren N, Zhang D H, et al. Chem. Res. Chin. Univ., 2015, 31:1039-1045 doi: 10.1007/s40242-015-5052-z
29. [29]
  Shi S K, Li K Y, Wang S P, et al. J. Mater. Chem. C, 2017, 5:4302-4309 doi: 10.1039/C7TC00727B
30. [30]
  Li Y J, Yan B. Inorg. Chem., 2009, 48:8276-8285 doi: 10.1021/ic900971h
31. [31]
  Shi S K, Wei D, Li K Y, et al.Appl.Surf.Sci., 2019, 472:150-157 doi: 10.1016/j.apsusc.2018.03.060
32. [32]
  Kumar M, Kariem M, Sheikh H N, et al. Dalton Trans., 2018, 47:12318-12336 doi: 10.1039/C8DT02429D
33. [33]
  Bünzli J C G, Chauvin A S, Kim H K, et al. Coord. Chem. Rev., 2010, 254:2623-2633 doi: 10.1016/j.ccr.2010.04.002
1. [1]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
2. [2]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
3. [3]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
4. [4]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
5. [5]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
6. [6]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
7. [7]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
8. [8]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
9. [9]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
10. [10]
  Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532
11. [11]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
12. [12]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
13. [13]
  Wenzhong Zhang , Zirui Yan , Lingcheng Chen , Yi Xiao . Sn-fused perylene diimides: Synthesis, mechanism, and properties. Chinese Chemical Letters, 2024, 35(10): 109582-. doi: 10.1016/j.cclet.2024.109582
14. [14]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
15. [15]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
16. [16]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
17. [17]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
18. [18]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
19. [19]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
20. [20]
  Tingting Huang , Zhuanlong Ding , Hao Liu , Ping-An Chen , Longfeng Zhao , Yuanyuan Hu , Yifan Yao , Kun Yang , Zebing Zeng . Electron-transporting boron-doped polycyclic aromatic hydrocarbons: Facile synthesis and heteroatom doping positions-modulated optoelectronic properties. Chinese Chemical Letters, 2024, 35(4): 109117-. doi: 10.1016/j.cclet.2023.109117

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(616)
HTML views(124)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142