Citation: LI Qian, MA Xue-Dong, WANG Wei, ZHANG Cun-She. Schiff Bases Containing p-Phenylenediamine and p-Phenylenedicarbaldehyde and Their Complexes: Preparation and Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2271-2280. doi: 10.11862/CJIC.2020.253 shu

Schiff Bases Containing p-Phenylenediamine and p-Phenylenedicarbaldehyde and Their Complexes: Preparation and Electrochemical Properties

LI Qian ¹ ,
MA Xue-Dong ¹ ,
WANG Wei ^1,2,, ,
ZHANG Cun-She ³

1.
Department of Chemical engineering, School of Water and Environment, Chang'an University, Xi'an 710054, China
2.
Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas, Ministry of Education, Chang'an University, Xi'an 710054, China
3.
Key Laboratory of Petroleum Fine Chemicals of Shaanxi Province, Shaanxi Research Design Institute of Petroleum and Chemical Industry, Xi'an 710054, China

Corresponding author: WANG Wei, wwchem@chd.edu.cn
Received Date: 11 May 2020
Revised Date: 28 September 2020

Figures(14)

The polymeric Schiff base (PT) was synthesized by the condensation reaction of p-phenylenediamine and terephthalaldehyde, and electrochemical properties of PT with different molar ratios of monomers were investigated. The lone pair electron of the nitrogen atom in the PT can coordinate with various metal ions (PT-M), and the results measured indicate that PT-M possesses better electrochemical performance compare with PT. The as-prepared samples were characterized by X-ray diffraction (XRD), infrared spectrum (IR), thermogravimetry-differential scanning calorimetry (TG-DSC), scanning electron microscope (SEM) and energy spectrum (EDS). The intensity of XRD peaks of PT-M decreased in comparison with the PT, indicating that the tendency of molecular chain arrangement from order to disorder because metal ions entering polymer molecular skeleton through coordination chemical bonds. Electrochemical properties of PT and PT-M were evaluated by means of cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The results show that the polymeric Schiff base aluminum complex (PT-Al) exhibits outstanding electrochemical performance, and its capacitance can reach 649.6 F·g^-1 at a current density of 0.5 A·g^-1, together with remaining 80.9% after 1 000 GCD cycles at the current density of 8 A·g^-1.
- polymeric Schiff base,
- coordination polymer,
- electrochemical performance,
- supercapacitor
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