Citation: WU Jia-Qi, MENG Yin-Shan, ZHU Hai-Lang, JIAO Cheng-Qi, LIU Tao. Synthesis and Magnetism of Cyano-bridged Fe₂Ni₂ Single-Molecule Magnets[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2331-2339. doi: 10.11862/CJIC.2020.252 shu

Synthesis and Magnetism of Cyano-bridged Fe₂Ni₂ Single-Molecule Magnets

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Tao, liutao@dlut.edu.cn
Received Date: 14 March 2020
Revised Date: 3 August 2020

Figures(8)

Two cyano-bridged Fe₂Ni₂ complexes were synthesized via the reaction of tricyanometallate building block Bu₄N[Fe^Ⅲ(PzTp)(CN)₃] (PzTp=tetrakis(pyrazolyl)borate) and 4, 4'-dimethoxy-2, 2'-bipyridine (4, 4'-dmobpy) ligand. X-ray diffraction study reveals that complexes [Fe^Ⅲ (PzTp) (CN)₃]₂[Ni₂^Ⅱ(4, 4'-dmobpy)4] [Fe^Ⅲ (PzTp) (CN)₃]₂·2CH₃OH (1) and [Fe^Ⅲ (PzTp) (CN)₃]₂[Ni₂^Ⅱ(4, 4'-dmobpy)₄] (PF₆)₂ (2) exhibit a tetranuclear square structure. Direct current susceptibility measurements indicate that 1 and 2 show intramolecular ferromagnetic interactions between Fe(Ⅲ) and Ni(Ⅱ) ions. Complexes 1 and 2 show the magnetic relaxation property in the absence of dc field, behaving as single-molecule magnets. The fitted relaxation energy barrier E_a/k_B for 1 and 2 were 12.8 and 13.0 K, respectively. CCDC: 1988983, 1; 1988982, 2.
- cyano-bridged,
- single-molecule magnet,
- ferromagnetic interaction
1. [1]
  Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993, 115:1804-1816 doi: 10.1021/ja00058a027
2. [2]
  Sessoli R, Gatteschi D, Caneschi A, et al. Nature, 1993, 365:141-143 doi: 10.1038/365141a0
3. [3]
  Wernsdorfer W, Aliaga-Alcalde N, Hendrickson D N, et al. Nature, 2002, 416:406-409 doi: 10.1038/416406a
4. [4]
  Corrales S A, Cain J M, Uhlig K A, et al. Inorg. Chem., 2016, 55:1367-1369 doi: 10.1021/acs.inorgchem.6b00058
5. [5]
  Leuenberger M N, Loss D. Nature, 2001, 410:789-793 doi: 10.1038/35071024
6. [6]
  Liu R N, Li L C, Wang X L, et al. Chem. Commun., 2010, 46:2566-2568 doi: 10.1039/b918554b
7. [7]
  Milios C J, Inglis R, Vinslava A, et al. J. Am. Chem. Soc., 2007, 129:12505-12511 doi: 10.1021/ja0736616
8. [8]
  Bogani L, Wernsdorfer W. Nat. Mater., 2008, 7:179-186 doi: 10.1038/nmat2133
9. [9]
  Mannini M, Pineider F, Sainctavit P, et al. Nat. Mater., 2009, 8:194-197 doi: 10.1038/nmat2374
10. [10]
  Qian K, Huang X C, Zhou C, et al. J. Am. Chem. Soc., 2013, 135:13302-13305 doi: 10.1021/ja4067833
11. [11]
  Pedersen K S, Bendix J, Clérac R. Chem. Commun., 2014, 50:4396-4415 doi: 10.1039/C4CC00339J
12. [12]
  Li D F, Parkin S, Wang G, et al. J. Am. Chem. Soc., 2006, 128:4214-4215 doi: 10.1021/ja058626i
13. [13]
  Wang C F, Zuo J L, Bartlett B M, et al. J. Am. Chem. Soc., 2006, 128:7162-7163 doi: 10.1021/ja061788+
14. [14]
  Li D F, Clérac R, Parkin S, et al. Inorg. Chem., 2006, 45:5251-5253 doi: 10.1021/ic060379b
15. [15]
  Li D F, Parkin S, Clérac R, et al. Inorg. Chem., 2006, 45:7569-7571 doi: 10.1021/ic060695q
16. [16]
  Zhang Y Z, Mallik U P, Rath N, et al. Chem. Commun., 2010, 46:4953-4955 doi: 10.1039/c0cc00317d
17. [17]
  Wang S, Ding X H, Zuo J L, et al. Coord. Chem. Rev., 2011, 255:1713-1732 doi: 10.1016/j.ccr.2011.01.057
18. [18]
  Zhang Y Z, Mallik U P, Clérac R, et al. Chem. Commun., 2011, 47:7194-7196 doi: 10.1039/c1cc10679a
19. [19]
  Beltran L M C, Long J R. Acc. Chem. Res., 2005, 38:325-334 doi: 10.1021/ar040158e
20. [20]
  Li D F, Parkin S, Wang G B, et al. Inorg. Chem., 2005, 44:4903-4905 doi: 10.1021/ic048367i
21. [21]
  Aguilà D, Prado Y, Koumousi E S, et al. Chem. Soc. Rev., 2016, 45:203-224 doi: 10.1039/C5CS00321K
22. [22]
  Li D F, Parkin S, Wang G B, et al. Inorg. Chem., 2006, 45:1951-1959 doi: 10.1021/ic051044h
23. [23]
  Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003, 42:268-297 doi: 10.1002/anie.200390099
24. [24]
  Ruamps R, Maurice R, Batchelor L, et al. J. Am. Chem. Soc., 2013, 135:3017-3026 doi: 10.1021/ja308146e
25. [25]
  Zhuang P F, Zhang Y J, Zheng H, et al. Dalton. Trans., 2015, 44:3393-3398 doi: 10.1039/C4DT03365E
26. [26]
  Rebilly J, Mallah T. Single-Molecule Magnets and Related Phenomena. Winpenny R. Ed., Berlin, Heidelberg:Springer, 2006:103-131
27. [27]
  Lescouëzec R, Vaissermann J, Lloret F, et al. Inorg. Chem., 2002, 41:5943-5945 doi: 10.1021/ic020374o
28. [28]
  Zhuang P F, Luo L, Liu T, et al. Inorg. Chem. Commun., 2014, 48:8-11 doi: 10.1016/j.inoche.2014.08.004
29. [29]
  SMART, SAINT and XPREP, Area Detector and Integration and Reduction Software, Bruker Analytical Instruments Inc., Madison, WI, 1995.
30. [30]
  Sheldtrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
31. [31]
  Dolomanov O, Bourhis L, Howard J, et al. J. Appl. Crystallogr., 2009, 42:339-341 doi: 10.1107/S0021889808042726
32. [32]
  Wu D Y, Zhang Y J, Huang W, et al. Dalton. Trans., 2010, 39:5500-5503 doi: 10.1039/b925698a
33. [33]
  Pardo E, Verdaguer M, Herson P, et al. Inorg. Chem., 2011, 50:6250-6262 doi: 10.1021/ic200616p
34. [34]
  Zhang Y Z, Mallik U P, Clérac R, et al. Polyhedron, 2013, 52:115-121 doi: 10.1016/j.poly.2012.10.039
35. [35]
  Jiao C Q, Jiang W J, Wen W, et al. Inorg. Chem. Commun., 2016, 74:12-15 doi: 10.1016/j.inoche.2016.10.030
36. [36]
  Hu J X, Zhang Y J, Xu Y, et al. Inorg. Chem. Commun., 2014, 47:155-158 doi: 10.1016/j.inoche.2014.07.039
37. [37]
  Liu W, Wang C F, Li Y Z, et al. Inorg. Chem., 2006, 45:10058-10065 doi: 10.1021/ic061347r
38. [38]
  Li D F, Clérac R, Wang G B, et al. Eur. J. Inorg. Chem., 2007:1341-1346
39. [39]
  Wang C F, Liu W, Song Y, et al. Eur. J. Inorg. Chem., 2008:717-727
40. [40]
  Liu X R, Jiao C Q, Meng Y S, et al. Z. Anorg. Allg. Chem., 2019, 645:428-432 doi: 10.1002/zaac.201800401
41. [41]
  Jiao Y S, Jiao C Q, Meng Y S, et al. Inorg. Chem. Commun., 2018, 93:87-91 doi: 10.1016/j.inoche.2018.05.015
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Synthesis and Magnetism of Cyano-bridged Fe₂Ni₂ Single-Molecule Magnets