Citation: WU Jia-Qi, MENG Yin-Shan, ZHU Hai-Lang, JIAO Cheng-Qi, LIU Tao. Synthesis and Magnetism of Cyano-bridged Fe₂Ni₂ Single-Molecule Magnets[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2331-2339. doi: 10.11862/CJIC.2020.252 shu

Synthesis and Magnetism of Cyano-bridged Fe₂Ni₂ Single-Molecule Magnets

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Tao, liutao@dlut.edu.cn
Received Date: 14 March 2020
Revised Date: 3 August 2020

Figures(8)

Two cyano-bridged Fe₂Ni₂ complexes were synthesized via the reaction of tricyanometallate building block Bu₄N[Fe^Ⅲ(PzTp)(CN)₃] (PzTp=tetrakis(pyrazolyl)borate) and 4, 4'-dimethoxy-2, 2'-bipyridine (4, 4'-dmobpy) ligand. X-ray diffraction study reveals that complexes [Fe^Ⅲ (PzTp) (CN)₃]₂[Ni₂^Ⅱ(4, 4'-dmobpy)4] [Fe^Ⅲ (PzTp) (CN)₃]₂·2CH₃OH (1) and [Fe^Ⅲ (PzTp) (CN)₃]₂[Ni₂^Ⅱ(4, 4'-dmobpy)₄] (PF₆)₂ (2) exhibit a tetranuclear square structure. Direct current susceptibility measurements indicate that 1 and 2 show intramolecular ferromagnetic interactions between Fe(Ⅲ) and Ni(Ⅱ) ions. Complexes 1 and 2 show the magnetic relaxation property in the absence of dc field, behaving as single-molecule magnets. The fitted relaxation energy barrier E_a/k_B for 1 and 2 were 12.8 and 13.0 K, respectively. CCDC: 1988983, 1; 1988982, 2.
- cyano-bridged,
- single-molecule magnet,
- ferromagnetic interaction
1. [1]
  Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993, 115:1804-1816 doi: 10.1021/ja00058a027
2. [2]
  Sessoli R, Gatteschi D, Caneschi A, et al. Nature, 1993, 365:141-143 doi: 10.1038/365141a0
3. [3]
  Wernsdorfer W, Aliaga-Alcalde N, Hendrickson D N, et al. Nature, 2002, 416:406-409 doi: 10.1038/416406a
4. [4]
  Corrales S A, Cain J M, Uhlig K A, et al. Inorg. Chem., 2016, 55:1367-1369 doi: 10.1021/acs.inorgchem.6b00058
5. [5]
  Leuenberger M N, Loss D. Nature, 2001, 410:789-793 doi: 10.1038/35071024
6. [6]
  Liu R N, Li L C, Wang X L, et al. Chem. Commun., 2010, 46:2566-2568 doi: 10.1039/b918554b
7. [7]
  Milios C J, Inglis R, Vinslava A, et al. J. Am. Chem. Soc., 2007, 129:12505-12511 doi: 10.1021/ja0736616
8. [8]
  Bogani L, Wernsdorfer W. Nat. Mater., 2008, 7:179-186 doi: 10.1038/nmat2133
9. [9]
  Mannini M, Pineider F, Sainctavit P, et al. Nat. Mater., 2009, 8:194-197 doi: 10.1038/nmat2374
10. [10]
  Qian K, Huang X C, Zhou C, et al. J. Am. Chem. Soc., 2013, 135:13302-13305 doi: 10.1021/ja4067833
11. [11]
  Pedersen K S, Bendix J, Clérac R. Chem. Commun., 2014, 50:4396-4415 doi: 10.1039/C4CC00339J
12. [12]
  Li D F, Parkin S, Wang G, et al. J. Am. Chem. Soc., 2006, 128:4214-4215 doi: 10.1021/ja058626i
13. [13]
  Wang C F, Zuo J L, Bartlett B M, et al. J. Am. Chem. Soc., 2006, 128:7162-7163 doi: 10.1021/ja061788+
14. [14]
  Li D F, Clérac R, Parkin S, et al. Inorg. Chem., 2006, 45:5251-5253 doi: 10.1021/ic060379b
15. [15]
  Li D F, Parkin S, Clérac R, et al. Inorg. Chem., 2006, 45:7569-7571 doi: 10.1021/ic060695q
16. [16]
  Zhang Y Z, Mallik U P, Rath N, et al. Chem. Commun., 2010, 46:4953-4955 doi: 10.1039/c0cc00317d
17. [17]
  Wang S, Ding X H, Zuo J L, et al. Coord. Chem. Rev., 2011, 255:1713-1732 doi: 10.1016/j.ccr.2011.01.057
18. [18]
  Zhang Y Z, Mallik U P, Clérac R, et al. Chem. Commun., 2011, 47:7194-7196 doi: 10.1039/c1cc10679a
19. [19]
  Beltran L M C, Long J R. Acc. Chem. Res., 2005, 38:325-334 doi: 10.1021/ar040158e
20. [20]
  Li D F, Parkin S, Wang G B, et al. Inorg. Chem., 2005, 44:4903-4905 doi: 10.1021/ic048367i
21. [21]
  Aguilà D, Prado Y, Koumousi E S, et al. Chem. Soc. Rev., 2016, 45:203-224 doi: 10.1039/C5CS00321K
22. [22]
  Li D F, Parkin S, Wang G B, et al. Inorg. Chem., 2006, 45:1951-1959 doi: 10.1021/ic051044h
23. [23]
  Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003, 42:268-297 doi: 10.1002/anie.200390099
24. [24]
  Ruamps R, Maurice R, Batchelor L, et al. J. Am. Chem. Soc., 2013, 135:3017-3026 doi: 10.1021/ja308146e
25. [25]
  Zhuang P F, Zhang Y J, Zheng H, et al. Dalton. Trans., 2015, 44:3393-3398 doi: 10.1039/C4DT03365E
26. [26]
  Rebilly J, Mallah T. Single-Molecule Magnets and Related Phenomena. Winpenny R. Ed., Berlin, Heidelberg:Springer, 2006:103-131
27. [27]
  Lescouëzec R, Vaissermann J, Lloret F, et al. Inorg. Chem., 2002, 41:5943-5945 doi: 10.1021/ic020374o
28. [28]
  Zhuang P F, Luo L, Liu T, et al. Inorg. Chem. Commun., 2014, 48:8-11 doi: 10.1016/j.inoche.2014.08.004
29. [29]
  SMART, SAINT and XPREP, Area Detector and Integration and Reduction Software, Bruker Analytical Instruments Inc., Madison, WI, 1995.
30. [30]
  Sheldtrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
31. [31]
  Dolomanov O, Bourhis L, Howard J, et al. J. Appl. Crystallogr., 2009, 42:339-341 doi: 10.1107/S0021889808042726
32. [32]
  Wu D Y, Zhang Y J, Huang W, et al. Dalton. Trans., 2010, 39:5500-5503 doi: 10.1039/b925698a
33. [33]
  Pardo E, Verdaguer M, Herson P, et al. Inorg. Chem., 2011, 50:6250-6262 doi: 10.1021/ic200616p
34. [34]
  Zhang Y Z, Mallik U P, Clérac R, et al. Polyhedron, 2013, 52:115-121 doi: 10.1016/j.poly.2012.10.039
35. [35]
  Jiao C Q, Jiang W J, Wen W, et al. Inorg. Chem. Commun., 2016, 74:12-15 doi: 10.1016/j.inoche.2016.10.030
36. [36]
  Hu J X, Zhang Y J, Xu Y, et al. Inorg. Chem. Commun., 2014, 47:155-158 doi: 10.1016/j.inoche.2014.07.039
37. [37]
  Liu W, Wang C F, Li Y Z, et al. Inorg. Chem., 2006, 45:10058-10065 doi: 10.1021/ic061347r
38. [38]
  Li D F, Clérac R, Wang G B, et al. Eur. J. Inorg. Chem., 2007:1341-1346
39. [39]
  Wang C F, Liu W, Song Y, et al. Eur. J. Inorg. Chem., 2008:717-727
40. [40]
  Liu X R, Jiao C Q, Meng Y S, et al. Z. Anorg. Allg. Chem., 2019, 645:428-432 doi: 10.1002/zaac.201800401
41. [41]
  Jiao Y S, Jiao C Q, Meng Y S, et al. Inorg. Chem. Commun., 2018, 93:87-91 doi: 10.1016/j.inoche.2018.05.015
1. [1]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
2. [2]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
3. [3]
  Jun-Jie Fang , Yun-Peng Xie , Xing Lu . Organooxotin and cobalt/manganese heterometallic nanoclusters exhibiting single-molecule magnetism. Chinese Journal of Structural Chemistry, 2025, 44(4): 100515-100515. doi: 10.1016/j.cjsc.2025.100515
4. [4]
  Jinjiang Wu , Zhenhua Zhu , Jinkui Tang . Recent advancements of photo-responsive lanthanide single-molecule magnets. Chinese Chemical Letters, 2025, 36(12): 110577-. doi: 10.1016/j.cclet.2024.110577
5. [5]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
6. [6]
  Xinyi Luo , Ke Wang , Yingying Xue , Xiaobao Cao , Jianhua Zhou , Jiasi Wang . Digital PCR-free technologies for absolute quantitation of nucleic acids at single-molecule level. Chinese Chemical Letters, 2025, 36(2): 109924-. doi: 10.1016/j.cclet.2024.109924
7. [7]
  Hao Gu , Rui Li , Qiuying Li , Sheng Lu , Yahui Chen , Xiaoning Yang , Huili Ma , Zhijun Xu , Xiaoqiang Chen . Multi-dimensional hydrogen bonds regulated emissions of single-molecule system enabling surficial hydrophobicity/hydrophilicity mapping. Chinese Chemical Letters, 2025, 36(5): 110116-. doi: 10.1016/j.cclet.2024.110116
8. [8]
  Qian-Cheng Luo , Xia-Li Ding , Wen-Jie Xu , Yuan-Qi Zhai , Yan-Zhen Zheng . Equatorial aminopyridine ligands stabilize an unusual straightly bridging mode in dimeric dysprosium(Ⅲ) single-molecule magnets. Chinese Chemical Letters, 2025, 36(9): 110304-. doi: 10.1016/j.cclet.2024.110304
9. [9]
  Wen Su , Siying Liu , Qingfu Zhang , Zhongyan Zhou , Na Wang , Lei Yue . Temperature-controlled electrospray ionization tandem mass spectrometry study on protein/small molecule interaction. Chinese Chemical Letters, 2025, 36(5): 110237-. doi: 10.1016/j.cclet.2024.110237
10. [10]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
11. [11]
  Zhao-Bo Hu , Ling-Ao Gui , Long-He Li , Tong-Tong Xiao , Adam T. Hand , Pagnareach Tin , Mykhaylo Ozerov , Yan Peng , Zhongwen Ouyang , Zhenxing Wang , Zi-Ling Xue , You Song . Co^Ⅱ single-ion magnet and its multi-dimensional aggregations: Influence of the structural rigidity on magnetic relaxation process. Chinese Chemical Letters, 2025, 36(2): 109600-. doi: 10.1016/j.cclet.2024.109600
12. [12]
  Saisai Yuan , Yiming Chen , Xijuan Wang , Degui Zhao , Tengyang Gao , Caiyun Wei , Chuanxiang Chen , Yang Yang , Wenjing Hong . Decouple the intermolecular interaction by encapsulating an insulating sheath. Chinese Chemical Letters, 2025, 36(6): 110816-. doi: 10.1016/j.cclet.2025.110816
13. [13]
  Zhibin Ren , Shan Li , Xiaoying Liu , Guanghao Lv , Lei Chen , Jingli Wang , Xingyi Li , Jiaqing Wang . Penetrating efficiency of supramolecular hydrogel eye drops: Electrostatic interaction surpasses ligand-receptor interaction. Chinese Chemical Letters, 2024, 35(11): 109629-. doi: 10.1016/j.cclet.2024.109629
14. [14]
  Cheng Wang , Ji Wang , Dong Liu , Zhi-Ling Zhang . Advances in virus-host interaction research based on microfluidic platforms. Chinese Chemical Letters, 2024, 35(12): 110302-. doi: 10.1016/j.cclet.2024.110302
15. [15]
  Wenya Chi , Ruiyao Liu , Wenbo Zhou , Weilin Li , Yuan Yu . The mechanisms of interaction between biomaterials and cells/cellular microenvironment and the applications in neural injuries. Chinese Chemical Letters, 2025, 36(8): 110587-. doi: 10.1016/j.cclet.2024.110587
16. [16]
  Jinchen Li , Tangxin Xiao , Kai Diao , Zhouyu Wang , Leyong Wang . Supramolecular catalysis enabled by chiral molecular cages with anion-π interaction capability. Chinese Chemical Letters, 2026, 37(1): 111796-. doi: 10.1016/j.cclet.2025.111796
17. [17]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
18. [18]
  Bo Li , Yuanzhe Cheng , Xuyang Ma , Dongxu Zhao , Yang Zhang , Yongxing Sun , Jia Chen , Li Wu , Liang Zhao , Hongdeng Qiu , Yujian He . Facile and scale-up synthesis of cyano-functionalized covalent organic frameworks for selective gold recovery. Chinese Chemical Letters, 2026, 37(1): 111134-. doi: 10.1016/j.cclet.2025.111134
19. [19]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
20. [20]
  Yanyu Jin , Wenzhe Si , Xing Yuan , Hongjun Cheng , Bin Zhou , Li Cai , Yu Wang , Qibao Wang , Junhua Li . Tuning TM–O interaction by acid etching in perovskite catalysts boosting catalytic performance. Chinese Chemical Letters, 2025, 36(5): 110260-. doi: 10.1016/j.cclet.2024.110260

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1066)
HTML views(237)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Magnetism of Cyano-bridged Fe2Ni2 Single-Molecule Magnets

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Magnetism of Cyano-bridged Fe₂Ni₂ Single-Molecule Magnets