Citation: GAO Ling-Ling, LI Meng-Xue, DU Yi-En, CHEN Yong-Qiang. Synthesis and Fluorescent Sensing Properties of Two Metal-Organic Coordination Polymers Based on 6-(3, 5-Dicarboxylphenyl)nicotinic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2359-2366. doi: 10.11862/CJIC.2020.249 shu

Synthesis and Fluorescent Sensing Properties of Two Metal-Organic Coordination Polymers Based on 6-(3, 5-Dicarboxylphenyl)nicotinic Acid

College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, China

Corresponding author: DU Yi-En, duyien124@163.com CHEN Yong-Qiang, chenyongqiang@jzxy.edu.cn
Received Date: 13 May 2020
Revised Date: 11 September 2020

Figures(12)

Two new metal-organic coordination polymers (MOCPs), namely, [Cd(HDCPN)(1, 4-bib)_0.5(H₂O)₂]_n (1) and {[Zn(HDCPN)(1, 2-bimb)]·H₂O}_n (2) have been synthesized based on H₃DCPN and Cd(Ⅱ)/Zn(Ⅱ) under solvothermal condition (H₃DCPN=6-(3, 5-dicarboxylphenyl)nicotinic acid, 1, 4-bib=1, 4-bis(1-imidazoly)benzene, 1, 2-bimb=1, 2-bis (imidazol-1-ylmethyl)benzene) and characterized by X-ray single-crystal diffraction analysis, IR spectrum analysis, thermogravimetric analysis and powder X-ray diffraction analysis. The results show that complexes 1 and 2 are 1D chain structures, which are further extended into a 3D structure by π…π interactions between HDCPN ligand and imidazole ligands. In addition, solid fluorescence of 1 and 2 were detected. The fluorescence experiments demonstrate that 1 has highly selective recognition for Fe³⁺, CrO₄^2- and Cr₂O₇^2- in aqueous solution. Meanwhile, the sensing mechanisms of 1 for Fe³⁺, CrO₄^2- and Cr₂O₇^2- ions were also studied. CCDC: 1532247, 1; 1999116, 2.
- 6-(3, 5-dicarboxylphenyl) nicotinic acid,
- metal-organic coordination polymer,
- luminescent property
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