Citation: LIU Xue-Fen, YU Zhe-Jian, XU Liang-Xuan, CHEN Hao, WANG Tian-Qi, YANG Peng, LUO Shu-Ping. Fluoric Phenanthrolines and Their Heteroleptic Copper Complexes: Synthesis and Application in Photocatalytic Hydrogen Evolution from Water[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2023-2030. doi: 10.11862/CJIC.2020.248 shu

Fluoric Phenanthrolines and Their Heteroleptic Copper Complexes: Synthesis and Application in Photocatalytic Hydrogen Evolution from Water

1.
Qianjiang college, Hangzhou Normal University, Hangzhou 310018, China
2.
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: YANG Peng, yangpenghz@hznu.edu.cn
Received Date: 24 December 2019
Revised Date: 29 September 2020

Figures(7)

A series of novel bidentate ligands of fluoro phenanthrolines were designed and synthesized, which could formulate a series of heteroleptic copper photosensitizers CP1~CP4 with Cu(MeCN)₄PF₆ and Xantphos as P ligand. The photosensitive activities of this copper complex were researched in water reduction system, and the turnover number (TON) of hydrogen evolution was up to 896. The absorption spectrum and fluorescence emission spectrum of the copper complexes indicated the good stability in solution. The oxidation quenching is the main quenching pathway in water reduction system, which was confirmed by the fluorescence quenching experiments. Moreover, a preliminary explanation and discussion of the structure-activity relationship and the mechanism of photocatalytic hydrogen evolution from water were carried out.
- N ligands,
- ligand design,
- heteroleptic copper complexes,
- photosensitizer,
- water splitting,
- hydrogen evolution
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沈阳化工大学材料科学与工程学院沈阳 110142