Citation: LI Yu, ZENG Fu-Ran, ZHOU Feng, LI Shan-Ji. Syntheses, Crystal Structures, Luminescence and Photocatalytic Activity of Cu(Ⅱ), Zn(Ⅱ) and Mn(Ⅱ) Coordination Polymers Based on Ether-Bridged Carboxylic Acids[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2124-2134. doi: 10.11862/CJIC.2020.243 shu

Syntheses, Crystal Structures, Luminescence and Photocatalytic Activity of Cu(Ⅱ), Zn(Ⅱ) and Mn(Ⅱ) Coordination Polymers Based on Ether-Bridged Carboxylic Acids

LI Yu ¹ ,
ZENG Fu-Ran ¹ ,
ZHOU Feng ^2,, ,
LI Shan-Ji ^3,,

1.
Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China;
2.
School of Mechanical and Electrical Engineering, Foshan Polytechnic, Foshan, Guangdong 528137, China;
3.
School of Petrochemical Engineering, Guangzhou Institute of Technology, Guangzhou 510725, China

Corresponding author: ZHOU Feng, 63419822@qq.com LI Shan-Ji, hnlsj2004@163.com
Received Date: 13 June 2020
Revised Date: 1 September 2020

Figures(13)

Two 2D coordination polymers, namely {[Cu₃(μ₄-dpna)₂(2,2'-bipy)₂]·4H₂O}_n (1) and {[Zn₃(μ₄-dpna)₂(2,2'-bipy)₂(H₂O)₂]·6H₂O}_n (2) as well as two 1D coordination polymers, namely {[M₂(μ₄-deta)(phen)₂(H₂O)]·3H₂O}_n (M=Mn (3), Zn (4)) have been constructed hydrothermally using H₃dpna (H₃dpna=5-(3',4'-dicarboxylphenoxy)nicotic acid) or H₄deta (H₄deta=2,3,2',3'-diphenyl ether tetracarboxylic acid) as a principal building block, 2,2'-bipy (2,2'-bipy=2,2'-bipyridine) or phen (phen=1,10-phenanthroline) as a auxiliary ligand, and copper, zinc or manganese chlorides. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses (TGA), and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that compounds 1 and 2 crystallize in the monoclinic system, space groups P2₁/c or C2/c. Compounds 1 and 2 disclose two different 2D sheet structures. The structural difference of compounds 1 and 2 is driven by the Cu(Ⅱ)/Zn(Ⅱ) nodes. Compounds 3 and 4 are isostructural and crystallize in the monoclinic system, space group P2₁/n. Both compounds show a 1D chain structure. The luminescent and photocatalytic properties of the compounds were investigated, showing that compounds 2 and 4 can effectively degrade methylene blue as a model organic dye pollutant.CCDC: 2004109, 1; 2004110, 2; 2004481, 3; 2004482, 4.
- coordination polymer,
- ether-bridged carboxylic acid,
- luminesce,
- photocatalytic properties
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