Citation: DING Guo-Yu, GAO Yuan, LI Ya-Hui, ZHU Zhen, WANG Qiu-Lin, JING Xin-Guo, YAN Feng-Qian, XU Guo-Jun, YUE Zhi-Hao, LI Xiao-Min, SUN Fu-Gen. In Situ Reactive Coating of Fast Ionic Conductor LiTi₂(PO₄)₃ on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Materials for High-Performance Li-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2307-2314. doi: 10.11862/CJIC.2020.239 shu

In Situ Reactive Coating of Fast Ionic Conductor LiTi₂(PO₄)₃ on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Materials for High-Performance Li-Ion Batteries

Institute of Photovoltaics, Nanchang University, Nanchang 330031, China

Corresponding author: SUN Fu-Gen, sunfugen@ncu.edu.cn
Received Date: 23 June 2020
Revised Date: 26 July 2020

Figures(5)

A uniform fast ionic conductor LiTi₂(PO₄)₃ (LTP) coating layer on the surface of Ni-rich layered metal oxide LiNi_0.8Co_0.1Mn_0.1O₂ (LNCM811) cathode material, was constructed via an in situ reaction of the residual LiOH and Li₂CO₃ on the LNCM811 surface with the added C₈H₂₀O₄Ti and (NH₄)H₂PO₄. This in situ reactive coating approach is favorable to remove the undesired LiOH and Li₂CO₃ which are residual on the LNCM811 surface. Moreover, the obtained uniform LTP coating layers could not only protect the LNCM811 cathode materials from the sidereaction with the electrolytes, but also ensure the fast Li⁺ conductivity for the LNCM811 cathode materials during the charge and discharge cycling. Therefore, owing to the multifunctional effects of the LTP coating, the LTP coated LNCM811 cathode materials exhibited excellent cyclic stability and rate performances with a high initial capacity of 200.1 mAh·g^-1 at 0.2C, the high reversible capacities of 155.7 mAh·g^-1 after the 200th cycle at 0.2C, 126.4 mAh·g^-1 at 2C and 111.9 mAh·g^-1 at 5C.
- energy storage technology,
- lithium-ion battery,
- cathode materials,
- LiNi_0.8Co_0.1Mn_0.1O₂,
- LiTi₂(PO₄)₃ coating,
- fast ionic conductor
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In Situ Reactive Coating of Fast Ionic Conductor LiTi2(PO4)3 on LiNi0.8Co0.1Mn0.1O2 Cathode Materials for High-Performance Li-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

In Situ Reactive Coating of Fast Ionic Conductor LiTi₂(PO₄)₃ on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Materials for High-Performance Li-Ion Batteries