Citation: JIN Hui-Dong, GU Yin-Dong, LIAN Yue-Bin, XUE Song-Lin, FANG Yuan-Yuan, DENG Zhao, Sakamoto Masanori, Teranishi Toshiharu, PENG Yang. Disulfide-Bridged Dimeric Cobalt Porphyrin: Synthesis and Electroreduction of Dioxygen[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2377-2384. doi: 10.11862/CJIC.2020.237 shu

Disulfide-Bridged Dimeric Cobalt Porphyrin: Synthesis and Electroreduction of Dioxygen

JIN Hui-Dong ^1,2,# ,
GU Yin-Dong ^1,2,# ,
LIAN Yue-Bin ^1,2 ,
XUE Song-Lin ^1,2,, ,
FANG Yuan-Yuan ³ ,
DENG Zhao ^1,2 ,
Sakamoto Masanori ⁴ ,
Teranishi Toshiharu ⁴ ,
PENG Yang ^1,2,,

1.
College of Energy, Soochow Institute for Energy and Materials InnovationS, Soochow University, Suzhou, Jiangsu 215006, China
2.
Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies, Suzhou, Jiangsu 215006, China
3.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China
4.
Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan

Corresponding author: XUE Song-Lin, ricardoxue@163.com PENG Yang, ypeng@suda.edu.cn
Received Date: 21 May 2020
Revised Date: 13 July 2020

Figures(10)

A disulfide-bridged dimeric cobalt porphyrin 2Co has been successfully synthesized. The cyclic voltammogram (CV) curves of 2Co exhibited three oxidation and two reduction potentials in CH₂Cl₂, indicating that the 2Co enable stabilizing multi-negative and positive charges. The ORR catalytic property of 2Co in acid media were investigated. The reduction of O₂ using the dimer 2Co as catalyst showed high stability and activity to give the higher the value of transferred electrons number (n) between 3.5 and 3.6 under dioxygen. The catalytic performance of 2Co indicates that dimerization of cobalt porphyrins have a slightly positive influence on the catalytic properties for oxygen reduction reactions (ORRs) in the acidic medium.
- cobalt porphyrin,
- dimer,
- O₂,
- electroreduction
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