Citation: XU Zhong-Xuan, LI Li-Feng, XU Shi-Fei, CHEN Xue-Ting. Two Zinc(Ⅱ) Coordination Polymers with 4-Fold Interpenetration Frameworks and dia Nets Based on 5-(Hydroxymethyl) Isophthalic Acid: Syntheses, Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2087-2092. doi: 10.11862/CJIC.2020.230 shu

Two Zinc(Ⅱ) Coordination Polymers with 4-Fold Interpenetration Frameworks and dia Nets Based on 5-(Hydroxymethyl) Isophthalic Acid: Syntheses, Crystal Structures and Fluorescence Properties

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: XU Zhong-Xuan, xuzhongxuan4201@163.com
Received Date: 4 May 2020
Revised Date: 25 June 2020

Figures(4)

Under solvothermal condition, 5-(hydroxymethyl) isophthalic acid (H₂HIPA) and Zn(Ⅱ) ions reacted with 1, 4-bis(2-methyl-1H-imidazol-1-yl) benzene (1, 4-BMIB) and 1, 2-di(pyridin-4-yl)ethene (dpee) to obtain two coordination polymers[Zn(HIPA)(1, 4-BMIB)]_n (1) and {[Zn(HIPA)(dpee)]·0.5dpee}_n (2), respectively. Single crystal X-ray diffraction analyses reveal that Zn(Ⅱ) center adopts a slightly distorted tetrahedral geometry in complex 1. And then, Zn (Ⅱ) ions are further connected together by HIPA^2- and 1, 4-BMIB ligands to form a 3D framework with nano-channels, which is up to 1.2 nm×2.0 nm. For such a very empty framework, structural interpenetration is difficult to avoid. Further analysis finds that the whole framework of complex 1 is a 4-fold interpenetration structure. From a topological viewpoint, the Zn(Ⅱ) ions are 4-connected nodes, whilst HIPA^2- and 1, 4-BMIB ligands are simple linkers. So, the whole framework of 1 is topologically represented as a 4-connected dia net. Although the Zn(Ⅱ) center in complex 2 has a different pentagonal bipyramid model, the HIPA^2- and dpee as simple linkers are connected by two Zn (Ⅱ) centers, respectively. Therefore, the final framework of 2 is still a 4-fold interpenetration dia net like 1. Furthermore, the dpee not only participates in constructing the framework as auxiliary ligand, but also exists in complex 2 as guest molecule. UV-Vis spectra showed that complexes 1 and 2 had strong absorption spectra in ultraviolet region, while solid fluorescence measurements revealed that they possessed blue fluorescence properties with emission peaks at about 414 and 440 nm, respectively.CCDC: 2000801, 1; 2000802, 2.
- zinc(Ⅱ) complex,
- 5-(hydroxymethyl) isophthalic acid,
- 4-fold interpenetration structure,
- dia net,
- fluorescence property
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