Citation: GONG Lei, LIU Min, XIANG Jun. Preparation and Microwave Absorption Properties of ZnO Nanoparticles Anchored on Submicron-Diameter Carbon Fibers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2113-2123. doi: 10.11862/CJIC.2020.226 shu

Preparation and Microwave Absorption Properties of ZnO Nanoparticles Anchored on Submicron-Diameter Carbon Fibers

School of Science, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China

Corresponding author: XIANG Jun, jxiang@just.edu.cn
Received Date: 22 May 2020
Revised Date: 3 September 2020

Figures(9)

ZnO nanoparticles anchored submicron-diameter carbon fibers (denoted as ZnO/SDCFs) composites were synthesized by electrospinning combined with hydrothermal method. The influences of pH value of the reaction solution on the structure, composition, electromagnetic (EM) characteristics and microwave absorption properties of the products are investigated in details. The results show that with increasing pH value of the solution, the complex permittivity, dielectric loss and EM attenuation ability of as-obtained ZnO/SDCFs composites decrease monotonously due to the increase of ZnO content in composites, in contrast, the EM impedance matching is improved gradually. Compared as the pure SDCFs, the microwave absorption capacities of ZnO/SDCFs composites are enhanced at different degrees. Among all the samples, the ZnO/SDCFs-8 composite prepared in solution with a pH value of 8 owns the best overall absorption properties, which is mainly attributed to the better balance between its EM attenuation capability and impedance matching. For the paraffin composites with only 2.5% (mass fraction) ZnO/SDCFs-8 as absorbent, the minimum reflection loss (RL) reached -44.1 dB at 17.7 GHz, and the effective absorption bandwidth with RL values less than -10 dB was as wide as 6.1 GHz ranging from 11.9 to 18 GHz at a relatively thin matching thickness of 1.7 mm. Moreover, the effective absorption bandwidth can be further increased to 11.8 GHz (6.2~18 GHz) when the absorber thickness was 3.0 mm.
- carbon fibers,
- ZnO,
- nanoparticles,
- electrospinning,
- hydrothermal synthesis,
- microwave absorption performance
1. [1]
  Huang T, Wu Z C, Yu Q, et al. Chem. Eng. J., 2019, 359:69-78 doi: 10.1016/j.cej.2018.11.108
2. [2]
  Liu H H, Li Y J, Yuan M W, et al. ACS Appl. Mater. Interfaces, 2018, 10:22591-22601 doi: 10.1021/acsami.8b05211
3. [3]
  Luo J H, Zhang K, Cheng M L, et al. Chem. Eng. J., 2020, 380:122625 doi: 10.1016/j.cej.2019.122625
4. [4]
  Lei W, Liu L, Yang Z H, et al. ACS Appl. Mater. Interfaces, 2018, 10:8965-8975 doi: 10.1021/acsami.8b00320
5. [5]
  Wu N N, Xu D M, Wang Z, et al. Carbon, 2019, 145:433-444 doi: 10.1016/j.carbon.2019.01.028
6. [6]
  Zhang M, Li Z J, Wang T, et al. Chem. Eng. J., 2019, 362:619-627 doi: 10.1016/j.cej.2019.01.039
7. [7]
  Liu Q H, Cao Q, Bi H, et al. Adv. Mater., 2016, 28:486-490 doi: 10.1002/adma.201503149
8. [8]
  Zhang X J, Zhu J Q, Yin P G, et al. Adv. Funct. Mater., 2018, 28:1800761 doi: 10.1002/adfm.201800761
9. [9]
  Zhang M, Liu H, Ding S Q, et al. Composites Part B, 2019, 179:107525 doi: 10.1016/j.compositesb.2019.107525
10. [10]
  Shu R W, Li W J, Wu Y, et al. Chem. Eng. J., 2019, 362:513-524 doi: 10.1016/j.cej.2019.01.090
11. [11]
  Cao M S, Han C, Wang X X, et al. J. Mater. Chem. C, 2018, 6:4586-4602 doi: 10.1039/C7TC05869A
12. [12]
  Qin F, Brosseau C. J. Appl. Phys., 2012, 111:061301 doi: 10.1063/1.3688435
13. [13]
  MA Xing-Jin, PENG Hua-Long, YANG Hui-Li, et al. Chin. Sci. Bull., 2019, 64(31):3188-3195
14. [14]
  Zhang X M, Ji G B, Liu W, et al. J. Mater. Chem. C, 2016, 4:1860-1870 doi: 10.1039/C6TC00248J
15. [15]
  Li X H, Feng J, Du Y P, et al. J. Mater. Chem. A, 2015, 3:5535-5546 doi: 10.1039/C4TA05718J
16. [16]
  Xiang J, Zhang X H, Ye Q, et al. Mater. Res. Bull., 2014, 60:589-595 doi: 10.1016/j.materresbull.2014.09.032
17. [17]
  Li Z J, Lin H, Ding S Q, et al. Carbon, 2020, 167:148-159 doi: 10.1016/j.carbon.2020.05.070
18. [18]
  Wang L X, Guan Y K, Qiu X, et al. Chem. Eng. J., 2017, 326:945-955 doi: 10.1016/j.cej.2017.06.006
19. [19]
  Xiang J, Li J L, Zhang X H, et al. J. Mater. Chem. A, 2014, 2:16905-16914 doi: 10.1039/C4TA03732D
20. [20]
  Wang L, Li X, Li Q Q, et al. Small, 2019, 15:1900900 doi: 10.1002/smll.201900900
21. [21]
  Zhao S C, Yang L L, Tian X D, et al. Nano Res., 2018, 11:530-541 doi: 10.1007/s12274-017-1664-6
22. [22]
  Mo Z C, Yang R L, Lu D W, et al. Carbon, 2019, 144:433-439 doi: 10.1016/j.carbon.2018.12.064
23. [23]
  Qi Y J, Qi L, Liu L P, et al. Carbon, 2019, 150:259-267 doi: 10.1016/j.carbon.2019.05.026
24. [24]
  Wang X L, Huang X, Chen Z R, et al. J. Mater. Chem. C, 2015, 3:10146-10153 doi: 10.1039/C5TC02689J
25. [25]
  Xu S, Wang Z L. Nano Res., 2011, 4:1013-1098 doi: 10.1007/s12274-011-0160-7
26. [26]
  Mishra Y K, Adelung R. Mater. Today, 2018, 21:631-651 doi: 10.1016/j.mattod.2017.11.003
27. [27]
  Liu J, Cao W Q, Jin H B, et al. J. Mater. Chem. C, 2015, 3:4670-4677 doi: 10.1039/C5TC00426H
28. [28]
  GUO Lan, FU Min-Gong, WAN Yi-Qun, et al. Chinese J. Inorg. Chem., 2007, 23(7):1251-1254
29. [29]
  XIANG Jun, ZHANG Xiong-Hui, YE Qin, et al. Chinese J. Inorg. Chem., 2014, 30(4):845-852
30. [30]
  Polsongkram D, Chamninok P, Pukird S, et al. Physica B, 2008, 403:3713-3717 doi: 10.1016/j.physb.2008.06.020
31. [31]
  Gu W H, Lv J, Quan B, et al. J. Alloys Compd., 2019, 806:983-991 doi: 10.1016/j.jallcom.2019.07.334
32. [32]
  Song W L, Cao M S, Wen B, et al. Mater. Res. Bull., 2012, 47:1747-1754 doi: 10.1016/j.materresbull.2012.03.045
33. [33]
  Luo H L, Xiong G Y, Chen X Q, et al. J. Alloys Compd., 2014, 593:7-15 doi: 10.1016/j.jallcom.2014.01.096
34. [34]
  Feng W, Wang Y M, Chen J C, et al. Phys. Chem. Chem. Phys., 2017, 19:14596-14605 doi: 10.1039/C7CP02039B
35. [35]
  Deng B W, Xiang Z, Xiong J, et al. Nano-Micro Lett., 2020, 12:55 doi: 10.1007/s40820-020-0398-2
36. [36]
  WANG Xi-Xi, CAO Mao-Sheng. Surf. Technol., 2020, 49(2):18-28
37. [37]
  Liu T, Xie X B, Pang Y, et al. J. Mater. Chem. C, 2016, 4:1727-1735 doi: 10.1039/C5TC03874J
38. [38]
  Li Q, Zhang Z, Qi L P, et al. Adv. Sci., 2019, 6:1801057 doi: 10.1002/advs.201801057
39. [39]
  Xiang J, Hou Z R, Zhang X K, et al. J. Alloys Compd., 2018, 737:412-420 doi: 10.1016/j.jallcom.2017.12.047
40. [40]
  Zeng J, Fan H Q, Wang Y L, et al. J. Alloys Compd., 2012, 524:59-62 doi: 10.1016/j.jallcom.2012.02.068
41. [41]
  Feng W, Wang Y M, Chen J C, et al. Carbon, 2016, 108:52-60 doi: 10.1016/j.carbon.2016.06.084
42. [42]
  Lu M M, Cao W Q, Shi H L, et al. J. Mater. Chem. A, 2014, 2:10540-10547 doi: 10.1039/c4ta01715c
43. [43]
  Qin H, Liao Q L, Zhang G J, et al. Appl. Surf. Sci., 2013, 286:7-11 doi: 10.1016/j.apsusc.2013.08.078
44. [44]
  Li H F, Wang J, Huang Y H, et al. Mater. Sci. Eng. B, 2010, 175:81-85 doi: 10.1016/j.mseb.2010.07.007
45. [45]
  Wu F, Xia Y L, Wang Y, et al. J. Mater. Chem. A, 2014, 2:20307-20315 doi: 10.1039/C4TA04959D
46. [46]
  Yang S, Guo X, Chen P, et al. J. Alloys Compd., 2019, 797:1310-1319 doi: 10.1016/j.jallcom.2019.05.190
47. [47]
  Song C Q, Yin X W, Han M K, et al. Carbon, 2017, 116:50-58 doi: 10.1016/j.carbon.2017.01.077
48. [48]
  Han M K, Yin X W, Kong L, et al. J. Mater. Chem. A, 2014, 2:16403-16409 doi: 10.1039/C4TA03033H
49. [49]
  Han M K, Yin X W, Ren S, et al. RSC Adv., 2016, 6:6467-6474 doi: 10.1039/C5RA25295D
50. [50]
  Liu P J, Yao Z J, Zhou J T, et al. J. Mater. Chem. C, 2016, 4:9738-9749 doi: 10.1039/C6TC03518C
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