Citation: TIAN Wen-Di, LI Xiao-Ze, CAO Jian-Liang, WANG Yan. Synthesis and Triethylamine Sensing Performance of Nanowires Assembled Leaf-like MoO₃ Nanostructure[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1948-1958. doi: 10.11862/CJIC.2020.223 shu

Synthesis and Triethylamine Sensing Performance of Nanowires Assembled Leaf-like MoO₃ Nanostructure

1.
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
College of Safety Science and Engineering, State Collaborative Innovation Center of Coal Work Safety and Clean-Efficiency Utilization, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: WANG Yan, yanwang@hpu.edu.cn
Received Date: 11 March 2020
Revised Date: 22 June 2020

Figures(10)

A multichip leaf-like MoO₃ nanostructure assembled from one-dimensional nanowires has been synthesized by a simple solvothermal method using bis(acetylacetonato) dioxomolybdenum (Ⅵ) in a component solvent of acetic acid and deionized water at relatively lower temperature of 150℃. The field emission scanning electron microscopic (FESEM) and transmission electron microscopy (TEM) observations indicate that the multichip MoO₃ nanostructures are composed of a plurality of fine nanowires with rough surface. The X-ray powder diffraction (XRD), high-resolution transmission electron microscope (HRTEM) results signified that the MoO₃ nanoleaves with the orthorhombic system, a distorted octahedral structure. And, the dominant exposed crystal plane of the leaf-like MoO₃ was (021). In addition, the leaf-like MoO₃ possessed distinctive selectivity, ultrahigh sensitivity and response time (~5 s) towards 2.25 g·m^-3 triethylamine (TEA) at the operating temperature of 300℃, even attained 12.4 at the low detection level (4.5 mg·m^-3). Based on the analysis results, the growth and formation of crystalline phase was deemed to follow the oriented attachment mechanism. Accordingly, the enhanced sensing ability could be mainly ascribed to its unique nanostructure, linear combination of large density, and high specific surface area, which promote the substantial free diffusion of TEA gases into the blade hole, showing excellent response recovery.
- leaf-like MoO₃,
- nanostructure,
- gas sensing material,
- triethylamine,
- fast detection
1. [1]
  Yan H H, Song P, Zhang S, et al. Sens. Actuators B, 2016, 236:201-207 doi: 10.1016/j.snb.2016.05.139
2. [2]
  Ji H C, Zeng W, Li Y Q. Mater. Res. Bull., 2019, 118:110476 doi: 10.1016/j.materresbull.2019.05.001
3. [3]
  Che S W, Behura S K, Berry V. ACS Nano, 2019, 13(11):12929-12938 doi: 10.1021/acsnano.9b05484
4. [4]
  Yao D D, Ou J Z, Latham K, et al. Cryst. Growth Des., 2012, 12(4):1865 doi: 10.1021/cg201500b
5. [5]
  Chen X F, Hu S Q, Liu Y, et al. J. Alloys Compd., 2020, 834:155096 doi: 10.1016/j.jallcom.2020.155096
6. [6]
  Haldar R, Heinke L, Woll C. Adv. Mater., 2019, 32:1905227
7. [7]
  Zalapa-Garibay M A, Torres T D, Arizmendi-Morquecho A M, et al. Results Phys., 2019, 13:102227 doi: 10.1016/j.rinp.2019.102227
8. [8]
  Mohamed M M, Salama T M, Morsy M, et al. Sens. Actuators B, 2019, 299:126960 doi: 10.1016/j.snb.2019.126960
9. [9]
  Sui L L, Song X X, Cheng X L, et al. CrystEngComm, 2015, 17(34):6493-6503 doi: 10.1039/C5CE00693G
10. [10]
  Li J T, Liu H J, Fu H, et al. J. Alloys Compd., 2019, 788:248-256 doi: 10.1016/j.jallcom.2019.02.086
11. [11]
  JIANG Yu-Fang, WU Hai-Yan, CHU Xiang-Feng, et al. Chinese J. Inorg. Chem., 2019, 35(7):1163-1168
12. [12]
  Wu H, Ma Z, Lin Z X, et al. J. Nanomater., 2019, 9(3):388 doi: 10.3390/nano9030388
13. [13]
  Zhai C B, Zhu M M, Jiang L N, et al. Appl. Surf. Sci., 2019, 463:1078-1084 doi: 10.1016/j.apsusc.2018.09.049
14. [14]
  Santos E B, Sigoli F A, Mazali I O. J. Solid State Chem., 2012, 190:80-84 doi: 10.1016/j.jssc.2012.02.012
15. [15]
  Qin H Y, Cao Y L, Xie J, et al. Sens. Actuators B, 2017, 242:769-776 doi: 10.1016/j.snb.2016.11.081
16. [16]
  Zhou J, Xu N S, Deng S Z, et al. Adv. Mater., 2003, 15(21):1835-1840 doi: 10.1002/adma.200305528
17. [17]
  Mo Y F, Tan Z G, Sun L P, et al. J. Alloys Compd., 2020, 812:152166 doi: 10.1016/j.jallcom.2019.152166
18. [18]
  Xia T, Li Q, Liu X D, et al. J. Phys. Chem. B, 2006, 110(5):2006-2012 doi: 10.1021/jp055945n
19. [19]
  Li S Z, Shao C L, Liu Y C, et al. J. Phys. Chem. Solids, 2006, 67(8):1869-1872 doi: 10.1016/j.jpcs.2006.04.017
20. [20]
  Hu S, Wang X. J. Am. Chem. Soc., 2008, 130(26):8126-8127 doi: 10.1021/ja801448c
21. [21]
  Gavrilyuk A, Tritthart U, Gey W. Sol. Energy Mater. Sol. Cells, 2011, 95(7):1846-1851 doi: 10.1016/j.solmat.2011.02.006
22. [22]
  Sui L L, Zhang X F, Cheng X L, et al. ACS Appl. Mater. Inter-faces, 2017, 9(2):1661-1670 doi: 10.1021/acsami.6b11754
23. [23]
  Jiang W H, Meng L L, Zhang S F, et al. Sens. Actuators B, 2019, 299:126888 doi: 10.1016/j.snb.2019.126888
24. [24]
  Li T M, Zeng W, Long H W, et al. Sens. Actuators B, 2016, 231:120-128 doi: 10.1016/j.snb.2016.03.003
25. [25]
  Zeng W, Zhang H, Wang Z C. Appl. Surf. Sci., 2015, 347:73-78 doi: 10.1016/j.apsusc.2015.04.060
26. [26]
  Li Y Q. Physica E, 2017, 94:22-24 doi: 10.1016/j.physe.2017.07.010
27. [27]
  Wang Y, Meng X N, Yao M X, et al. Ceram. Int., 2019, 45(10):13150-13157 doi: 10.1016/j.ceramint.2019.03.250
28. [28]
  Tao Z H, Li Y W, Zhang B, et al. Sens. Actuators B, 2019, 298:126889 doi: 10.1016/j.snb.2019.126889
29. [29]
  Xue D P, Wang P T, Zhang Z Y, et al. Sens. Actuators B, 2019, 296:126710 doi: 10.1016/j.snb.2019.126710
30. [30]
  Ji H C, Zeng W, Li Y Q. Physica E, 2019, 114:113646 doi: 10.1016/j.physe.2019.113646
31. [31]
  HUANG Xiao-Dong, BAI Shou-Li, LI Dian -Qing, et al. Chinese J. Inorg. Chem., 2005, 21(8):1143-1148
32. [32]
  Alsaif M, Latham K, Field M R, et al. Adv. Mater., 2014, 26(23):3931-3937 doi: 10.1002/adma.201306097
33. [33]
  Zhai C B, Zhu M M, Jiang L N, et al. Appl. Surf. Sci., 2019, 463:1078-1084 doi: 10.1016/j.apsusc.2018.09.049
34. [34]
  Hu J, Liang Y F, Sun Y J, et al. Sens. Actuators B, 2017, 252:116-126 doi: 10.1016/j.snb.2017.05.113
35. [35]
  Zhou X, Feng W, Wang C, et al. J. Mater. Chem. A, 2014, 2(41):17683-17690 doi: 10.1039/C4TA04386C
36. [36]
  Lee J H. Sens. Actuators B, 2009, 140(1):319-336 doi: 10.1016/j.snb.2009.04.026
37. [37]
  LI Ping, ZHANG Xiao-Xian, SI Ying, et al. Chinese J. Inorg. Chem., 2020, 36(3):566-574
38. [38]
  Sunu S S, Prabhu E, Jayaraman V, et al. Sens. Actuators B, 2004, 101(1/2):161-174
39. [39]
  De la Fuente J R, Jullian C, Saitz C, et al. J. Org. Chem., 2005, 70(22):8712-8716 doi: 10.1021/jo050796q
40. [40]
  Wu M Z, Zhang X F, Gao S, et al. CrystEngComm, 2013, 15(46):10123-10131 doi: 10.1039/c3ce41471j
41. [41]
  Wang D, Chu X F, Gong M L. Sens. Actuators B, 2006, 117(1):183-187 doi: 10.1016/j.snb.2005.11.022
42. [42]
  Zhang F H, Yang H Q, Xie X L, et al. Sens. Actuators B, 2009, 141(2):381-389 doi: 10.1016/j.snb.2009.06.049
43. [43]
  Wu Y P, Zhou W, Dong W W, et al. Cryst. Growth Des., 2017, 17(4):2158-2165 doi: 10.1021/acs.cgd.7b00102
44. [44]
  Wang Y, Liu J F, Wang M, et al. Inorg. Chem., 2017, 56(3):1504-1510 doi: 10.1021/acs.inorgchem.6b02603
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Triethylamine Sensing Performance of Nanowires Assembled Leaf-like MoO3 Nanostructure

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Triethylamine Sensing Performance of Nanowires Assembled Leaf-like MoO₃ Nanostructure