Citation: YU Fan, HU Bing-Qian, XIONG Xin, LU Wang-Ting, LI Bao. Amorphous Cobalt Sulfide Derived From Metal-Organic Framework and Its Water Splitting Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1873-1880. doi: 10.11862/CJIC.2020.222 shu

Amorphous Cobalt Sulfide Derived From Metal-Organic Framework and Its Water Splitting Properties

YU Fan ^1,, ,
HU Bing-Qian ¹ ,
XIONG Xin ¹ ,
LU Wang-Ting ¹ ,
LI Bao ^2,,

1.
Key Laboratory of Optoelectronic Chemical Materials and Devices(Ministry of Education), School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056, China
2.
School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: YU Fan, yufan0714@163.com LI Bao, libao@hust.edu.cn
Received Date: 29 March 2020
Revised Date: 28 August 2020

Figures(9)

Herein, we report the preparation of amorphous cobalt sulfide electrode materials using MOF as template and its application in electrocatalytic decomposition of water. Firstly, a new cobalt-based metal-organic framework was prepared by using nitrogen -containing system. Then, a series of amorphous cobalt sulfide samples were prepared by changing curing time, temperature and sulfur sources, such as sodium sulfide and thioacetamide. The materials were characterized by powder X-ray diffraction, scanning electron microscope, X-ray photoelectron spectroscopy and infrared spectra, and their structural characteristics were explained. The electrolysis performance of each sample was characterized in detail, and the structure-activity relationship of each system was established. Combined with various structural characterization and electrochemical performance tests, it was found that when the sulfuration temperature and sulfuration time were controlled to 60℃ and 6 h, respectively, the related samples exhibited the hydrogen evolution reaction and oxygen evolution reaction potential of 178 and 246 mV when the current density was 10 mA·cm^-2 in 1.0 mol·L^-1 KOH solution, along with the excellent durability. CCDC:2010582.
- metal-organic framework,
- cobalt sulfide,
- hydrogen energy,
- water electrolysis
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