Citation: SUN Ai-Jing, BU De-Yan, ZHANG Hui, WANG Zuo-Xiang. Syntheses, Crystal Structures and Characterization of Two Polymeric Cadmium(Ⅱ) Complexes Based on 2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1959-1966. doi: 10.11862/CJIC.2020.213 shu

Syntheses, Crystal Structures and Characterization of Two Polymeric Cadmium(Ⅱ) Complexes Based on 2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: WANG Zuo-Xiang, wangzx0908@aliyun.com
Received Date: 2 February 2020
Revised Date: 6 June 2020

Figures(6)

Two polymeric cadmium (Ⅱ) complexes derived from 2-methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole (L), [Cd₂(L)₂(μ-SCN)₄]_n (1) and[Cd₂(L)₂(μ-Cl)₄]_n (2), were synthesized and characterized by single crystal X-ray diffraction, UV-visible spectra, fluorescence and thermogravimetric analysis (TGA). Complexes 1 and 2 crystallize in triclinic and monoclinic system, respectively. The space groups of complexes 1 and 2 are P\begin{document}$\bar 1$\end{document} and P2₁/n, respectively. Complex 1 is a double-bridged cadmium(Ⅱ) polymer bridged by two thiocyanate anions, and the central Cd1(Ⅱ) ions have distorted octahedral geometries[CdN₄S₂]. Complex 2 is a double-bridged cadmium(Ⅱ) polymer bridged by two chloride anions, and the central cadmium(Ⅱ) ions have distorted octahedral geometries[CdCl₄N₂]. Both complexes 1 and 2 have fluorescence properties.
- 1, 3, 4-oxadiazole,
- synthesis,
- crystal structure,
- cadmium(Ⅱ) complex,
- fluorescence
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