Citation: ZHU De-Cheng, CHEN Yi-Xin, JI Chong-Xing, ZHU Xian-Yu, LI De-Cheng. Structure and Electrochemical Properties of LiCe_xEu_1-xTiO₄ through Ion Exchange Method[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1925-1933. doi: 10.11862/CJIC.2020.197 shu

Structure and Electrochemical Properties of LiCe_xEu_1-xTiO₄ through Ion Exchange Method

College of Energy, Soochow University, Suzhou, Jiangsu 215006, China

Corresponding author: LI De-Cheng, lidecheng@suda.edu.cn
Received Date: 30 April 2020
Revised Date: 28 June 2020

Figures(12)

Using Cerium (Ⅲ) nitrate hexahydrate as Ce source, LiCe_xEu_1-xTiO₄ was synthesized by sol-gel and ion exchange method. The structural, morphological and electrochemical properties of LiCe_xEu_1-xTiO₄ were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), cyclic voltammogram (CV), and charge-discharge cycling tests. The results show that the introduction of Ce³⁺ into the lattice can significantly improve the dynamic properties of the material, which is probably related to Ce-Eu-Ti synergistic effect. This synergistic effect appears as the complicated modulations in terms of lattice parameters and resulted in Ti and Ce in mixed valences. LiEu_0.995Ce_0.005TiO₄ shows the best electrochemical performances.
- lithium-ion battery,
- anode material,
- perovskite structure,
- ion-exchange method,
- electrochemical performance
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Structure and Electrochemical Properties of LiCexEu1-xTiO4 through Ion Exchange Method

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通讯作者: 陈斌, bchen63@163.com

Structure and Electrochemical Properties of LiCe_xEu_1-xTiO₄ through Ion Exchange Method