Citation: ZHANG Da-Qin, JIA Zhi-Gang, LUO Guang-Cheng, WANG Hong-Zhou, LI Chao-Yong, WU Lin, CHEN Qi-Hou. CDs-Induced Polymorphous CaCO₃ Mineralization and Formation Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1557-1566. doi: 10.11862/CJIC.2020.179 shu

CDs-Induced Polymorphous CaCO₃ Mineralization and Formation Mechanism

School of Chemistry and Chemical Engineering, Anhui University of technology, Maanshan, Anhui 243002, China

Corresponding author: JIA Zhi-Gang, zjchemyue@126.com
Received Date: 27 November 2019
Revised Date: 19 June 2020

Figures(10)

Carbon dots (CDs) with various chemical structures can be obtained under the condition of different heat treat temperatures. The morphology and phase of CaCO₃ has been successfully controlled by the as-prepared CDs. Peanut-like, dumbbell-like and sphere-like particles were prepared in the presence of CDs. The CDs with changeable chemical structures, such as carboxyl group, aldehyde group, hydroxyl group, were deemed to be responsible for the variation in morphology. The as-obtained samples were characterized by scanning electron microscope (SEM), Fourier transform infrared spectrometer (FTIR), photoluminescence (PL) and X-ray diffraction (XRD). The growth mechanism of CaCO₃ twin sphere particles was investigated in detail. Ostwald ripening and oriented aggregation mechanisms were proposed to be the drive power of the final morphology formation in the presence of CDs.
- material science,
- crystal growth,
- carbon dot,
- synthesis method
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沈阳化工大学材料科学与工程学院沈阳 110142

CDs-Induced Polymorphous CaCO3 Mineralization and Formation Mechanism

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通讯作者: 陈斌, bchen63@163.com

CDs-Induced Polymorphous CaCO₃ Mineralization and Formation Mechanism