Citation: ZHAO Xiao-Bo, LI Yue-Jun, CAO Tie-Ping, SUN Da-Wei. Preparation and Photocatalytic Hydrogen Production of Bi/Yb³⁺, Er³⁺: TiO₂ Nanofibers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1535-1542. doi: 10.11862/CJIC.2020.174 shu

Preparation and Photocatalytic Hydrogen Production of Bi/Yb³⁺, Er³⁺: TiO₂ Nanofibers

1.
College of Chemistry, Baicheng Normal University, Baicheng, Jilin 137000, China
2.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: LI Yue-Jun, bc640628@163.com
Received Date: 13 March 2020
Revised Date: 23 May 2020

Figures(11)

Bi deposited Yb³⁺, Er³⁺ codped TiO₂ nanofiber photocatalysts were synthesized from Yb³⁺ and Er³⁺ co-doped TiO₂ substrate by combining electrospinning technique and hydrothermal method. Using triethanolamine as a sacrificial agent, we studied the ultraviolet, visible, near infrared and full spectrum photocatalytic hydrogen production over Bi/Yb³⁺, Er³⁺:TiO₂. The results showed that the full-spectrum illumination for 5 h resulted in a hydrogen production rate of 1 650.3 μmol·g^-1·h^-1. As an emerging non-noble metal, Bi displays unique plasma photocatalytic or assisted photocatalytic properties. The advantages of Bi metal can be further combined with a rich energy level structure of rare earth elements and unique up-conversion luminescence properties. The double synergistic modification of TiO₂ can effectively improve the photocatalytic activity of TiO₂ nanofibers.
- metal Bi,
- Yb³⁺, Er³⁺ co-doped TiO₂ nanofibers,
- hydrothermal synthesis,
- photolysis
1. [1]
  Hisatomi T, Domen K. Nat. Catal., 2019, 2:387-399 doi: 10.1038/s41929-019-0242-6
2. [2]
  Ma Y, Wang X L, Li C, et al. Chem. Rev., 2014, 114(19):9987-10043 doi: 10.1021/cr500008u
3. [3]
  Wang D K, Zeng H, Xiong X, et al. Sci. Bull., 2020, 65(2):113-122 doi: 10.1016/j.scib.2019.10.015
4. [4]
  Wang D K, Ye P, Li K L, et al. Appl. Catal. B, 2020, 260:118182-118190 doi: 10.1016/j.apcatb.2019.118182
5. [5]
  Maeda K, Saito N, Lu D L, et al. J. Phys. Chem. C, 2007, 111(12):4749-4755 doi: 10.1021/jp067254c
6. [6]
  Fujishima A, Honda K. Nature, 1972, 238:37-38 doi: 10.1038/238037a0
7. [7]
  LI Yue-Jun, CAO Tie-Ping, MEI Ze-Min, et al. Chinese J. Inorg. Chem., 2019, 35(1):82-88
8. [8]
  Zalfani M, Hu Z Y, Yu W B, et al. Appl. Catal. B, 2017, 205(15):121-132
9. [9]
  Qin F, Wang R M, Li G F, et al. Catal. Commun., 2013, 42:14-19 doi: 10.1016/j.catcom.2013.07.039
10. [10]
  Dong F, Zhao Z W, Sun Y J, et al. Environ. Sci. Technol., 2015, 49(20):12432-12440 doi: 10.1021/acs.est.5b03758
11. [11]
  CAO Tie-Ping, LI Yue-Jun, MEI Ze-Min, et al. Chinese J. Inorg. Chem., 2017, 33(12):2225-2232
12. [12]
  Qin W P, Zhang D S, Zhao D, et al. Chem. Commun., 2010, 46(13):2304-2306 doi: 10.1039/b924052g
13. [13]
  Wang J, Ma T, Zhang G, et al. Catal. Commun., 2007, 8(3):607-611 doi: 10.1016/j.catcom.2006.08.022
14. [14]
  Obregón S, Colón G. Chem. Commun., 2012, 48(63):7865-7867 doi: 10.1039/c2cc33391k
15. [15]
  Dai K, Peng T Y, Chen H, et al. Environ. Sci. Technol., 2009, 43(5):1540-1545 doi: 10.1021/es802724q
16. [16]
  Cao T P, Li Y J, Shao C L, et al. J. Mater. Chem., 2011, 21(19):6922-6927 doi: 10.1039/c1jm10343a
17. [17]
  McMahon J M, Schatz G C, Gray S K. Phys. Chem. Chem. Phys., 2013, 15(15):5415-5423 doi: 10.1039/C3CP43856B
18. [18]
  Wang Z, Jiang C L, Huang R, et al. J. Phys. Chem. C, 2014, 118(2):1155-1160 doi: 10.1021/jp4065505
19. [19]
  Liu H J, Liu G G, Xie G H, et al. Appl. Surf. Sci., 2011, 257(8):3728-3732 doi: 10.1016/j.apsusc.2010.11.122
20. [20]
  Bai S, Jiang J, Xiong Y J, et al. Chem. Soc. Rev., 2015, 44(10):2893-2939 doi: 10.1039/C5CS00064E
21. [21]
  Linic S, Christopher P, Ingram D B. Nat. Mater., 2011, 10:911-921 doi: 10.1038/nmat3151
22. [22]
  Huang H N, Zhou H F, Zhou J, et al. RSC Adv., 2017, 7(27):16777-16786 doi: 10.1039/C6RA28592A
23. [23]
  He W J, Sun Y J, Jiang G M, et al. Appl. Catal. B, 2018, 232:340-347 doi: 10.1016/j.apcatb.2018.03.047
24. [24]
  Toudert J, Serna R, Jiménez de Castro M. J. Phys. Chem. C, 2012, 116(38):20530-20539 doi: 10.1021/jp3065882
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Hydrogen Production of Bi/Yb3+, Er3+: TiO2 Nanofibers

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Preparation and Photocatalytic Hydrogen Production of Bi/Yb³⁺, Er³⁺: TiO₂ Nanofibers