Citation: CHENG Rui-Xue, TIAN Fei-Yang, ZHANG Yun-Qian, TAO Zhu. Three Cucurbit[n]uril-Based Supramolecular Frameworks Assembled by Planar Configuration[Pd_nCl_m]^2- Anions[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1241-1248. doi: 10.11862/CJIC.2020.171 shu

Three Cucurbit[n]uril-Based Supramolecular Frameworks Assembled by Planar Configuration[Pd_nCl_m]^2- Anions

Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China

Received Date: 8 October 2019
Revised Date: 17 April 2020

Figures(4)

Three novel cucurbit[n]uril-based (Q[n]-based) supramolecular frameworks(QSFs) have been successfully prepared by using the planar configuration[Pd_nCl_m]^2- anion as the structure-directing agent, namely {Na₂(H₂O)₆TMeQ[6]}[Pd₂Cl₆]·3H₂O (1), (H₃O)₂{CyH₅Q[5]}[Pd₂Cl₆]·3H₂O (2) and (H₃O)₂{Q[5]}[PdCl₄]·23H₂O (3), respectively. Structural analysis reveals that using the[Pd_nCl_m]^2- anion as the structure-directing agent in different Q[n] systems that can promote the orderly arrangement of Q[n]s, and contribute to the formation of QSFs with different frame structures. For 1, the carbonyl groups of TMeQ[6] bind directly to the Na(Ⅰ) ions to form 1D coordination chains, which can be further built into 3D supramolecular architecture by outer surface interactions between TMeQ[6] and the[Pd₂Cl₆]^2- anions. For 2, under the guidance of[Pd₂Cl₆]^2- anions, CyH₅Q[5] molecules can be orderly arranged to construct a 3D structure with pores which are filled with[Pd₂Cl₆]^2- anions, while it can be found in 3 that Q[5] molecules can also be orderly arranged by[PdCl₄]^2- anions to form a 3D frameworks with a 1D channel. The driving force to result in the formation of such frameworks is attributed to the outer surface interaction of Q[n]s, which is ion-dipole between the electrostatic potential positive outer surface of Q[n]s and the[Pd_nCl_m]^2- anions.CCDC: 1956589, 1; 1956591, 2; 1956590, 3.
- [Pd_nCl_m]^2-,
- structure-directing agent,
- cucurbit[n]uril,
- supramolecular framework,
- outer surface interaction of Q[n]s
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Three Cucurbit[n]uril-Based Supramolecular Frameworks Assembled by Planar Configuration[PdnClm]2- Anions

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通讯作者: 陈斌, bchen63@163.com

Three Cucurbit[n]uril-Based Supramolecular Frameworks Assembled by Planar Configuration[Pd_nCl_m]^2- Anions