Citation: TU Fang-Fang, XIE Jian, GUO Feng, ZHAO Xin-Bing, WANG Yu-Ping, CHEN Dong, XIANG Jia-Yuan, CHEN Jian. Preparation and Electrochemical Performance of Li_6.4La₃Zr_1.4Ta_0.6O₁₂/Polymer-Based Solid Composite Electrolyte[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1515-1523. doi: 10.11862/CJIC.2020.169 shu

Preparation and Electrochemical Performance of Li_6.4La₃Zr_1.4Ta_0.6O₁₂/Polymer-Based Solid Composite Electrolyte

1.
Zhejiang Narada Power Source Corporation Limited, Hangzhou 311100, China
2.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: TU Fang-Fang, fangfangtu1990@126.com
Received Date: 7 March 2020
Revised Date: 7 May 2020

Figures(4)

A solid composite electrolyte was prepared through a solution-casting method with polypropylene carbonate (PPC) and polyethylene oxide (PEO) as polymer blends, and Li_6.4La₃Zr_1.4Ta_0.6O₁₂(LLZTO) particles as multifunctional fillers. The effects of LLZTO content and PPC/PEO mass ratio on the ionic conductivity of solid composite electrolyte were studied. Results show that the ionic conductivity at room temperature reached the highest value of 1.14×10^-4 S·cm^-1 when LLZTO content was 30%(w/w) and the mass ratio of PPC to PEO was 1:1. The incorporation of LLZTO and PPC into PEO repressed the crystallinity of polymer electrolyte, increased ionic conductivity, electrochemical stability window (4.7 V) and Li+ transference number (0.25), and reinforces interfacial stability between solid electrolyte and lithium anode. The capacity retention rates of the LiFePO₄/Li cell with solid composite electrolyte remain 82% after 70 cycles at room temperature and 79% after 100 cycles at 60℃. The discharge capacity reaches 120.7 and 112.6 mAh·g^-1 at 0.5C and 1C, respectively.
- lithium secondary batteries,
- solid inorganic-organic hybrid electrolyte,
- Li_6.4La₃Zr_1.4Ta_0.6O₁₂,
- polypropylene carbonate,
- polymer blends
1. [1]
  Goodenough J B, Kim Y. Chem. Mater., 2010, 22(3):587-603
2. [2]
  Quartarone E, Mustarelli P. Chem. Soc. Rev., 2011, 40(5):2525-2540
3. [3]
  ZHANG Yong-Long, XIA Hui-Ling, LIN Jiu, et al. Energy Storage Sci. Technol., 2018, 7(6):994-1002
4. [4]
  Bates J B, Dudney N J, Neudecker B, et al. Solid State Ionics, 2000, 135(1/2/3/4):33-45
5. [5]
  Kerman K, Luntz A, Viswanathan V, et al. J. Electrochem. Soc., 2017, 164(7):A1731-A1744
6. [6]
  Zhang Z Z, Shao Y J, Lotsch B, et al. Energy Environ. Sci., 2018, 11(8):1945-1976
7. [7]
  Kato Y, Hori S, Saito T, et al. Nat. Energy, 2016, 1(4):16030
8. [8]
  Abhilash K P, Selvin P C, Nalini B, et al. J. Phys. Chem. Solids, 2016, 91:114-121
9. [9]
  Arbi K, Jimenez R, Šalkus T, et al. Solid State Ionics, 2015, 271:28-33
10. [10]
  Deng Y, Eames C, Fleutot B, et al. ACS Appl. Mater. Interfaces, 2017, 9(8):7050-7058
11. [11]
  LÜ Xiao-Juan, WU Ya-Nan, MENG Fan-Li, et al. J. Ceram., 2019, 40(2):148-152
12. [12]
  SUN Qiu-Shi, ZHU Chong-Jia, XIE Jian, et al. Chinese J. Inorg. Chem., 2019, 35(5):865-870
13. [13]
  Thangadurai V, Kaack H, Weppner W J F. J. Am. Ceram. Soc., 2003, 86(3):437-440
14. [14]
  Gao Z H, Sun H B, Fu L, et al. Adv. Mater., 2018, 30(17):1705702
15. [15]
  Fu K, Gong Y H, Dai J Q, et al. Proc. Natl. Acad. Sci. U.S.A., 2016, 113(26):7094-7099
16. [16]
  Zhu P, Yan C Y, Dirican M, et al. J. Mater. Chem. A, 2018, 6(10):4279-4285
17. [17]
  Liang J Y, Zeng X X, Zhang X D, et al. J. Am. Chem. Soc., 2019, 141(23):9165-9169
18. [18]
  Zhang X, Liu T, Zhang S F, et al. J. Am. Chem. Soc., 2017, 139(39):13779-13785
19. [19]
  Zhang J J, Zhao J H, Yue L P, et al. Adv. Energy Mater., 2015, 5(24):1501082
20. [20]
  YANG Pei-Xia, CUI Wen-Yu, XING Dong-Jun, et al. Chinese J. Inorg. Chem., 2011, 27(11):2143-2149
21. [21]
  Stephan A M. Eur. Polym. J., 2006, 42(1):21-42
22. [22]
  Chen L, Li Y T, Li S P, et al. Nano Energy, 2018, 46:176-184
23. [23]
  Yue L P, Ma J, Zhang J J, et al. Energy Storage Mater., 2016, 5:139-164
24. [24]
  Zhang Y H, Lu W, Cong L N, et al. J. Power Sources, 2019, 420:63-72
25. [25]
  DONG Tian-Tian, ZHANG Jian-Jun, CHAI Jing-Chao, et al. Acta Polym. Sin., 2017, 6:906-921
26. [26]
  Huang H J, Ding F, Zhong H, et al. J. Mater. Chem. A, 2018, 6(20):9539-9549
27. [27]
  Yu X Y, Xiao M, Wang S J, et al. J. Appl. Polym. Sci., 2010, 115(5):2718-2722
28. [28]
  Logéat A, Köhler T, Eisele U, et al. Solid State Ionics, 2012, 206(3):33-38
29. [29]
  Zhao Y R, Wu C, Peng G, et al. J. Power Sources, 2016, 301:47-53
30. [30]
  QI De-Jiang, BI Xiao-Guo, RU Hong-Qiang. J. Mater. Metall., 2011, 10(2):125-135
31. [31]
  Zheng J, Hu Y Y. ACS Appl. Mater. Interfaces, 2018, 10(4):4113-4120
32. [32]
  Li Z, Huang H M, Zhu J K, et al. ACS Appl. Mater. Interfaces, 2019, 11(1):784-791
33. [33]
  Chen F, Yang D J, Zha W P, et al. Electrochim. Acta, 2017, 258:1106-1114
34. [34]
  GUO Tian, CHEN Yu-Qi, HE Hong-Cai, et al. Electron. Compon. Mater., 2019, 38(7):25-31
35. [35]
  Xue Z G, He D, Xie X L. J. Mater. Chem. A, 2015, 3(38):19218-19253
36. [36]
  Zhang J J, Zang X, Wen H J, et al. J. Mater. Chem. A, 2017, 5(10):4940-4948
37. [37]
  Zhang Y H, Chen F, Tu R, et al. J. Power Sources, 2014, 268:960-964
38. [38]
  Zhou J, Fedkiw P S. Solid State Ionics, 2004, 166(3/4):275-293
39. [39]
  Evans J, Vincent C A, Bruce P G. Polymer, 1987, 28(13):2324-2328
40. [40]
  Chen L, Liu Y C, Fan L Z. J. Electrochem. Soc., 2017, 164(9):A1834-A1840
41. [41]
  Li D, Chen L, Wang T S, et al. ACS Appl. Mater. Interfaces, 2018, 10(8):7069-7078
42. [42]
  Zhang J X, Zhao N, Zhang M, et al. Nano Energy, 2016, 28:447-454
1. [1]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
2. [2]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
3. [3]
  Wei LI , Jianjie XU , Linlin WANG , Chuanbing HOU , Hongliang HAN , Qionghua JIN . Synthesis, structure, and photocatalytic properties of {PMo₁₂}-based rare-earth tetraisopropyl ethylenediphosphonate complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2077-2091. doi: 10.11862/CJIC.20260220
4. [4]
  Jiancheng LAN , Xiaolan FU , Meiling FAN , Naibo ZHAO , Yu'nan ZHOU . High-performance Ta-based halide electrolytes via co-sintering method. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2162-2168. doi: 10.11862/CJIC.20260071
5. [5]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
6. [6]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
7. [7]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
8. [8]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
9. [9]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
10. [10]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
11. [11]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
12. [12]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
13. [13]
  Da Wang , Xiaobin Yin , Jianfang Wu , Yaqiao Luo , Siqi Shi . All-Solid-State Lithium Cathode/Electrolyte Interfacial Resistance: From Space-Charge Layer Model to Characterization and Simulation. Acta Physico-Chimica Sinica, 2024, 40(7): 2307029-0. doi: 10.3866/PKU.WHXB202307029
14. [14]
  Chi Zhou , Zeyu Yuan , Zhibin Hu , Yaqun Wu , Liping Duan , Yichen Du , Xiaosi Zhou . Energy storage mechanisms and optimization strategies of polymer cathodes for potassium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(11): 100363-0. doi: 10.1016/j.actphy.2026.100363
15. [15]
  Hongbo Hou , Qian Yang , Yi Gao , Yang Ou , Zhuang Wang , Shun Yi , Jingfeng He , Li Ma , Fanbin Meng . Progress in supercritical CO₂ foamed polymer composites for electromagnetic protection: from rational structural design to absorption-dominated performance. Acta Physico-Chimica Sinica, 2026, 42(10): 100300-0. doi: 10.1016/j.actphy.2026.100300
16. [16]
  Gengjia Chen , Junjie Ou . Application of the van Deemter Equation in Instrumental Analysis Teaching: A Case of Organic Polymer Monolithic Columns. University Chemistry, 2025, 40(11): 362-368. doi: 10.12461/PKU.DXHX202502003
17. [17]
  Rui Yang , Hui Li , Qingfei Meng , Wenjie Li , Jiliang Wu , Yongjin Fang , Chi Huang , Yuliang Cao . Influence of PC-based Electrolyte on High-Rate Performance in Li/CrO_x Primary Battery. Acta Physico-Chimica Sinica, 2024, 40(9): 2308053-0. doi: 10.3866/PKU.WHXB202308053
18. [18]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
19. [19]
  Zhiming Cui , Yuanlong Wu . 综合创新实验：基于原位聚合技术的固态锂金属电池的构筑及性能评价. University Chemistry, 2026, 41(9): 313-323. doi: 10.12461/PKU.DXHX202508043
20. [20]
  Lin He , Lin Chen , Rundong Chen , Xianlong Zhou , Shuai Zhang , Bingquan Xia . Two-dimensional Ta₂C cocatalyst for enhanced H₂O₂ photosynthesis and organic pollutant degradation. Acta Physico-Chimica Sinica, 2026, 42(11): 100367-0. doi: 10.1016/j.actphy.2026.100367

Get Citation

PDF

XML

Metrics

PDF Downloads(75)
Abstract views(10161)
HTML views(4092)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Performance of Li6.4La3Zr1.4Ta0.6O12/Polymer-Based Solid Composite Electrolyte

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Performance of Li_6.4La₃Zr_1.4Ta_0.6O₁₂/Polymer-Based Solid Composite Electrolyte