Citation: ZOU Jing-Yi, SUN Xiao-Gang, LI Rui, HE Qiang. Preparation of High Performance Tin Oxide Anode with Cobalt-Rich Porous Carbon[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1506-1514. doi: 10.11862/CJIC.2020.166 shu

Preparation of High Performance Tin Oxide Anode with Cobalt-Rich Porous Carbon

School of Mechanical and Electrical Engineering, Nanchang University, Nanchang 330031, China

Corresponding author: SUN Xiao-Gang, xiaogangsun@163.com
Received Date: 6 March 2020
Revised Date: 12 May 2020

Figures(8)

One-step carbonization method was used to prepare CoO rich porous carbon (PC(Co)) materials as carrier of tin oxide (SnO₂). PC(Co) materials have rich porous structure which can efficiently carry SnO₂. Furthermore, the CoO in the PC(Co) materials can act on the electrochemical reaction, effectively reducing the formation of LiO₂. But cobalt oxide can consume a lot of lithium ions, so we chose to add lithium fluoride (LiF) which can while replenishing lithium and enhance the stability of the SEI film. By calculation, the loading of the active substance was as high as 1.51 mg·cm^-2. Electrochemical tests show that at a current density of 100 mAh·g^-1, the first discharge specific capacity reached 1 653.63 mAh·g^-1, and the utilization rate of the active material was as high as 93.14%. After 100 cycles, the specific discharge capacity still reached 1 070.68 mAh·g^-1, and the coulombic efficiency remained at 99.81%.
- carbon material,
- nanocomposites,
- lithium fluoride,
- tin oxide,
- lithium ion batteries
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