Citation: ZHANG Zhi, ZOU Chen-Tao, YANG Zhi-Yuan, YANG Shui-Jin. One-Step Preparation and Photocatalytic Activity of Bi₂MoO₆/CoMoO₄ Embroidery Ball Structure[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1446-1456. doi: 10.11862/CJIC.2020.162 shu

One-Step Preparation and Photocatalytic Activity of Bi₂MoO₆/CoMoO₄ Embroidery Ball Structure

1.
College of Chemistry and Chemical Engineering, Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Normal University, Huangshi, Hubei 435002, China
2.
Institute for Advanced Materials of Hubei Normal University, Huangshi, Hubei 435002, China

Corresponding author: YANG Shui-Jin, yangshuijin@hbnu.edu.cn
Received Date: 8 January 2020
Revised Date: 1 May 2020

Figures(13)

Herein, Bi₂MoO₆/CoMoO₄ embroidery ball structures were synthesized by a simple one-step hydrothermal method that using bismuth nitrate pentahydrate as the bismuth source. By X-ray powder diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier infrared spectroscopy (FT-IR), ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS), fluorescence spectrum (PL), and electrochemical tests were performed to analyze the phase composition, micromorphology, optical properties, and recombination rate of photogenerated charge of the prepared catalyst. The results showed that when introducing Bi₂MoO₆, the light absorption range of the Bi₂MoO₆/CoMoO₄ heterojunctions were significantly enhanced, and the separation of photogenerated charges were also improved. Methylene blue and ceftriaxone sodium were used as pollutants to simulate wastewater, and the photocatalytic degradation activity of the catalyst samples was evaluated under visible light. After irradiation for 60 min, the composite with Bi₂MoO₆ loading of 30%(w/w) composites has the best photocatalytic performance, and the degradation rate constant was twice that of pure CoMoO₄. Based on all the experimental characterizations, the corresponding photocatalytic mechanism of the Bi₂MoO₆/CoMoO₄ system was further studied.
- photocatalysis,
- heterojunction,
- hydrothermal synthesis,
- Bi₂MoO₆,
- CoMoO₄,
- visible light
1. [1]
  Schneider J, Matsuoka M, Takeuchi M, et al. Chem. Rev., 2014, 114:9919-9986 doi: 10.1021/cr5001892
2. [2]
  Gao S T, Feng T, Feng C, et al. J. Colloid Interface Sci., 2016, 466:284-290 doi: 10.1016/j.jcis.2015.12.045
3. [3]
  ZHOU Xin, FENG Tao, GAO Shu-Tao, et al. Chinese J. Inorg. Chem., 2016, 32(5):769-776
4. [4]
  Opoku F, Govender K, Sittert C, et al. Adv. Sustainable Syst., 2017, 1:1700006 doi: 10.1002/adsu.201700006
5. [5]
  Chen D N, Zhang X G, Lee A F. J. Mater. Chem. A, 2015, 3:14487-14516 doi: 10.1039/C5TA01592H
6. [6]
  Ciriminna R, Delisi R, Xu Y J, et al. Org. Process Res. Dev., 2016, 20:403-408 doi: 10.1021/acs.oprd.5b00424
7. [7]
  ZHU Yu-Xiang, XU Shi-Jie, YANG Jing, et al. Chinese J. Inorg. Chem., 2019, 35(12):2331-2336 doi: 10.11862/CJIC.2019.261
8. [8]
  WANG Peng, LI Zhao, ZHOU Ying-Mei, et al. Chinese J. Inorg. Chem., 2019, 35(2):217-224
9. [9]
  HE Yun-Peng, JIN Xue-Yang, LI Wen-Zhuo, et al. Chinese J. Inorg. Chem., 2019, 35(6):996-1004
10. [10]
  LIANG Meng-Jun, DENG Nan, XIANG Xin-Yi, et al. Chinese J. Inorg. Chem., 2019, 35(2):263-270
11. [11]
  Li Y J, Fu Y Z, Zhu M S. Appl. Catal. B, 2020, 260:118149 doi: 10.1016/j.apcatb.2019.118149
12. [12]
  Lu Y, Zhang X, Chu Y C, et al. Appl. Catal. B, 2018, 224:239-248 doi: 10.1016/j.apcatb.2017.10.054
13. [13]
  Wang L, Bahnemann D, Bian L, et al. Angew. Chem. Int. Ed., 2019, 58:8103-8108 doi: 10.1002/anie.201903027
14. [14]
  YANG Bing-Ye, LI Hang, SHANG Ning-Zhao, et al. Chinese J. Inorg. Chem., 2017, 33(3):396-404
15. [15]
  Zhang J, Mao X H, Xiao W, et al. Chin. J. Catal., 2017, 38:2009-2020 doi: 10.1016/S1872-2067(17)62935-8
16. [16]
  Ke J, Duan X G, Luo S, et al. Chem. Eng. J., 2017, 313:1447-1453 doi: 10.1016/j.cej.2016.11.048
17. [17]
  Ponceblanc H, Millet J, Coudurier G, et al. J. Catal., 1993, 142:373-380 doi: 10.1006/jcat.1993.1215
18. [18]
  Low J X, Yu J G, Jaroniec M, et al. Adv. Mater., 2017, 29(20):1601694 doi: 10.1002/adma.201601694
19. [19]
  Mahsa P, Aziz H. J. Photochem. Photobiol. A, 2018, 363:31-43 doi: 10.1016/j.jphotochem.2018.05.027
20. [20]
  Solmaz F, Aziz H, Kunio Y, et al. Mater. Chem. Phys., 2019, 224:10-21 doi: 10.1016/j.matchemphys.2018.11.076
21. [21]
  Qiao X Q, Zhang Z W, Li Q H, et al. J. Mater. Chem. A, 2018, 6:22580-22589 doi: 10.1039/C8TA08294D
22. [22]
  Li S J, Hu S W, Zhang J L, et al. J. Colloid Interface Sci., 2017, 497:93-101 doi: 10.1016/j.jcis.2017.02.069
23. [23]
  Li H, Zhang T X, Pan C, et al. Appl. Surf. Sci., 2017, 391:303-310 doi: 10.1016/j.apsusc.2016.06.167
24. [24]
  Zhao Z W, Zhang W D, Sun Y J, et al. J. Phys. Chem. C, 2016, 120(22):11889-11898 doi: 10.1021/acs.jpcc.6b01188
25. [25]
  Dong G S, Zhao H, Xu Y M, et al. J. Alloys Compd., 2019, 785:563-572 doi: 10.1016/j.jallcom.2019.01.234
26. [26]
  Chen H, Hu L F, Chen M, et al. Adv. Funct. Mater., 2014, 24:934-942 doi: 10.1002/adfm.201301747
27. [27]
  Yan T, Yan Q, Wang X D, et al. Dalton Trans., 2015, 44:1601-1611 doi: 10.1039/C4DT02127D
28. [28]
  Milena R, Aleksandra Z, Aleksandra S, et al. Mater. Res. Bull., 2018, 98:111-120 doi: 10.1016/j.materresbull.2017.10.015
29. [29]
  Li H P, Deng Q H, Liu J Y, et al. Catal. Sci. Technol., 2014, 4:1028-1037 doi: 10.1039/C3CY00940H
30. [30]
  Liu X L, Yang Y X, Guan S Y. Chem. Phys. Lett., 2017, 675:11-14 doi: 10.1016/j.cplett.2017.02.074
31. [31]
  Mahmood N, Tahir M, Mahmood A, et al. Nano Energy, 2015, 11:267-276 doi: 10.1016/j.nanoen.2014.11.015
32. [32]
  Xia X F, Lei W, Hao Q L, et al. Electrochim. Acta, 2013, 99:253-261 doi: 10.1016/j.electacta.2013.03.131
33. [33]
  Mahsa P, Aziz H. J. Colloid Interface Sci., 2017, 491:216-229 doi: 10.1016/j.jcis.2016.12.044
34. [34]
  Gao Z, Yang H P, Cao Y, et al. Nanotechnology, 2019, 30:255704 doi: 10.1088/1361-6528/ab084d
35. [35]
  Lin X, Liu D, Guo X Y, et al. J. Phys. Chem. Solids, 2015, 76:170-177 doi: 10.1016/j.jpcs.2014.09.002
36. [36]
  Sasan H, Ali A. J. Mater. Sci.-Mater. Electron., 2016, 27:4489-4493 doi: 10.1007/s10854-016-4322-y
37. [37]
  Zhou H, Zhong S T, Shen M, et al. J. Alloys Compd., 2018, 769:301-310 doi: 10.1016/j.jallcom.2018.08.007
38. [38]
  Liu D X, Zhang J, Li C, et al. Appl. Catal. B, 2019, 248:459-465 doi: 10.1016/j.apcatb.2019.02.050
39. [39]
  Zhang Q, Dai Z, Cheng G, et al. Ceram. Int., 2017, 43:11296-11304 doi: 10.1016/j.ceramint.2017.05.328
40. [40]
  Yang C M, Gao G M, Zhang J J, et al. Phys. Chem. Chem. Phys., 2017, 19:14431-14441 doi: 10.1039/C7CP02136D
41. [41]
  Zhou J J, Wang R, Liu X L, et al. Appl. Surf. Sci., 2015, 346:278-283 doi: 10.1016/j.apsusc.2015.03.210
42. [42]
  Sun J X, Yuan Y P, Qiu L G, et al. Dalton Trans., 2012, 41:6756-6763 doi: 10.1039/c2dt12474b
43. [43]
  Liang M J, Yang Z Y, Yang Y, et al. J. Mater. Sci.-Mater. Electron., 2019, 30(2):1310-1321 doi: 10.1007/s10854-018-0400-7
44. [44]
  Gong Y, Zhao X, Zhang H, et al. Appl. Catal. B, 2018, 333:35-45
45. [45]
  Tang L, Feng C Y, Deng Y C, et al. Appl. Catal. B, 2018, 230:102-114 doi: 10.1016/j.apcatb.2018.02.031
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

One-Step Preparation and Photocatalytic Activity of Bi2MoO6/CoMoO4 Embroidery Ball Structure

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通讯作者: 陈斌, bchen63@163.com

One-Step Preparation and Photocatalytic Activity of Bi₂MoO₆/CoMoO₄ Embroidery Ball Structure