Citation: ZHANG Zhi, ZOU Chen-Tao, YANG Zhi-Yuan, YANG Shui-Jin. One-Step Preparation and Photocatalytic Activity of Bi₂MoO₆/CoMoO₄ Embroidery Ball Structure[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1446-1456. doi: 10.11862/CJIC.2020.162 shu

One-Step Preparation and Photocatalytic Activity of Bi₂MoO₆/CoMoO₄ Embroidery Ball Structure

1.
College of Chemistry and Chemical Engineering, Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Normal University, Huangshi, Hubei 435002, China
2.
Institute for Advanced Materials of Hubei Normal University, Huangshi, Hubei 435002, China

Corresponding author: YANG Shui-Jin, yangshuijin@hbnu.edu.cn
Received Date: 8 January 2020
Revised Date: 1 May 2020

Figures(13)

Herein, Bi₂MoO₆/CoMoO₄ embroidery ball structures were synthesized by a simple one-step hydrothermal method that using bismuth nitrate pentahydrate as the bismuth source. By X-ray powder diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier infrared spectroscopy (FT-IR), ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS), fluorescence spectrum (PL), and electrochemical tests were performed to analyze the phase composition, micromorphology, optical properties, and recombination rate of photogenerated charge of the prepared catalyst. The results showed that when introducing Bi₂MoO₆, the light absorption range of the Bi₂MoO₆/CoMoO₄ heterojunctions were significantly enhanced, and the separation of photogenerated charges were also improved. Methylene blue and ceftriaxone sodium were used as pollutants to simulate wastewater, and the photocatalytic degradation activity of the catalyst samples was evaluated under visible light. After irradiation for 60 min, the composite with Bi₂MoO₆ loading of 30%(w/w) composites has the best photocatalytic performance, and the degradation rate constant was twice that of pure CoMoO₄. Based on all the experimental characterizations, the corresponding photocatalytic mechanism of the Bi₂MoO₆/CoMoO₄ system was further studied.
- photocatalysis,
- heterojunction,
- hydrothermal synthesis,
- Bi₂MoO₆,
- CoMoO₄,
- visible light
1. [1]
  Schneider J, Matsuoka M, Takeuchi M, et al. Chem. Rev., 2014, 114:9919-9986 doi: 10.1021/cr5001892
2. [2]
  Gao S T, Feng T, Feng C, et al. J. Colloid Interface Sci., 2016, 466:284-290 doi: 10.1016/j.jcis.2015.12.045
3. [3]
  ZHOU Xin, FENG Tao, GAO Shu-Tao, et al. Chinese J. Inorg. Chem., 2016, 32(5):769-776
4. [4]
  Opoku F, Govender K, Sittert C, et al. Adv. Sustainable Syst., 2017, 1:1700006 doi: 10.1002/adsu.201700006
5. [5]
  Chen D N, Zhang X G, Lee A F. J. Mater. Chem. A, 2015, 3:14487-14516 doi: 10.1039/C5TA01592H
6. [6]
  Ciriminna R, Delisi R, Xu Y J, et al. Org. Process Res. Dev., 2016, 20:403-408 doi: 10.1021/acs.oprd.5b00424
7. [7]
  ZHU Yu-Xiang, XU Shi-Jie, YANG Jing, et al. Chinese J. Inorg. Chem., 2019, 35(12):2331-2336 doi: 10.11862/CJIC.2019.261
8. [8]
  WANG Peng, LI Zhao, ZHOU Ying-Mei, et al. Chinese J. Inorg. Chem., 2019, 35(2):217-224
9. [9]
  HE Yun-Peng, JIN Xue-Yang, LI Wen-Zhuo, et al. Chinese J. Inorg. Chem., 2019, 35(6):996-1004
10. [10]
  LIANG Meng-Jun, DENG Nan, XIANG Xin-Yi, et al. Chinese J. Inorg. Chem., 2019, 35(2):263-270
11. [11]
  Li Y J, Fu Y Z, Zhu M S. Appl. Catal. B, 2020, 260:118149 doi: 10.1016/j.apcatb.2019.118149
12. [12]
  Lu Y, Zhang X, Chu Y C, et al. Appl. Catal. B, 2018, 224:239-248 doi: 10.1016/j.apcatb.2017.10.054
13. [13]
  Wang L, Bahnemann D, Bian L, et al. Angew. Chem. Int. Ed., 2019, 58:8103-8108 doi: 10.1002/anie.201903027
14. [14]
  YANG Bing-Ye, LI Hang, SHANG Ning-Zhao, et al. Chinese J. Inorg. Chem., 2017, 33(3):396-404
15. [15]
  Zhang J, Mao X H, Xiao W, et al. Chin. J. Catal., 2017, 38:2009-2020 doi: 10.1016/S1872-2067(17)62935-8
16. [16]
  Ke J, Duan X G, Luo S, et al. Chem. Eng. J., 2017, 313:1447-1453 doi: 10.1016/j.cej.2016.11.048
17. [17]
  Ponceblanc H, Millet J, Coudurier G, et al. J. Catal., 1993, 142:373-380 doi: 10.1006/jcat.1993.1215
18. [18]
  Low J X, Yu J G, Jaroniec M, et al. Adv. Mater., 2017, 29(20):1601694 doi: 10.1002/adma.201601694
19. [19]
  Mahsa P, Aziz H. J. Photochem. Photobiol. A, 2018, 363:31-43 doi: 10.1016/j.jphotochem.2018.05.027
20. [20]
  Solmaz F, Aziz H, Kunio Y, et al. Mater. Chem. Phys., 2019, 224:10-21 doi: 10.1016/j.matchemphys.2018.11.076
21. [21]
  Qiao X Q, Zhang Z W, Li Q H, et al. J. Mater. Chem. A, 2018, 6:22580-22589 doi: 10.1039/C8TA08294D
22. [22]
  Li S J, Hu S W, Zhang J L, et al. J. Colloid Interface Sci., 2017, 497:93-101 doi: 10.1016/j.jcis.2017.02.069
23. [23]
  Li H, Zhang T X, Pan C, et al. Appl. Surf. Sci., 2017, 391:303-310 doi: 10.1016/j.apsusc.2016.06.167
24. [24]
  Zhao Z W, Zhang W D, Sun Y J, et al. J. Phys. Chem. C, 2016, 120(22):11889-11898 doi: 10.1021/acs.jpcc.6b01188
25. [25]
  Dong G S, Zhao H, Xu Y M, et al. J. Alloys Compd., 2019, 785:563-572 doi: 10.1016/j.jallcom.2019.01.234
26. [26]
  Chen H, Hu L F, Chen M, et al. Adv. Funct. Mater., 2014, 24:934-942 doi: 10.1002/adfm.201301747
27. [27]
  Yan T, Yan Q, Wang X D, et al. Dalton Trans., 2015, 44:1601-1611 doi: 10.1039/C4DT02127D
28. [28]
  Milena R, Aleksandra Z, Aleksandra S, et al. Mater. Res. Bull., 2018, 98:111-120 doi: 10.1016/j.materresbull.2017.10.015
29. [29]
  Li H P, Deng Q H, Liu J Y, et al. Catal. Sci. Technol., 2014, 4:1028-1037 doi: 10.1039/C3CY00940H
30. [30]
  Liu X L, Yang Y X, Guan S Y. Chem. Phys. Lett., 2017, 675:11-14 doi: 10.1016/j.cplett.2017.02.074
31. [31]
  Mahmood N, Tahir M, Mahmood A, et al. Nano Energy, 2015, 11:267-276 doi: 10.1016/j.nanoen.2014.11.015
32. [32]
  Xia X F, Lei W, Hao Q L, et al. Electrochim. Acta, 2013, 99:253-261 doi: 10.1016/j.electacta.2013.03.131
33. [33]
  Mahsa P, Aziz H. J. Colloid Interface Sci., 2017, 491:216-229 doi: 10.1016/j.jcis.2016.12.044
34. [34]
  Gao Z, Yang H P, Cao Y, et al. Nanotechnology, 2019, 30:255704 doi: 10.1088/1361-6528/ab084d
35. [35]
  Lin X, Liu D, Guo X Y, et al. J. Phys. Chem. Solids, 2015, 76:170-177 doi: 10.1016/j.jpcs.2014.09.002
36. [36]
  Sasan H, Ali A. J. Mater. Sci.-Mater. Electron., 2016, 27:4489-4493 doi: 10.1007/s10854-016-4322-y
37. [37]
  Zhou H, Zhong S T, Shen M, et al. J. Alloys Compd., 2018, 769:301-310 doi: 10.1016/j.jallcom.2018.08.007
38. [38]
  Liu D X, Zhang J, Li C, et al. Appl. Catal. B, 2019, 248:459-465 doi: 10.1016/j.apcatb.2019.02.050
39. [39]
  Zhang Q, Dai Z, Cheng G, et al. Ceram. Int., 2017, 43:11296-11304 doi: 10.1016/j.ceramint.2017.05.328
40. [40]
  Yang C M, Gao G M, Zhang J J, et al. Phys. Chem. Chem. Phys., 2017, 19:14431-14441 doi: 10.1039/C7CP02136D
41. [41]
  Zhou J J, Wang R, Liu X L, et al. Appl. Surf. Sci., 2015, 346:278-283 doi: 10.1016/j.apsusc.2015.03.210
42. [42]
  Sun J X, Yuan Y P, Qiu L G, et al. Dalton Trans., 2012, 41:6756-6763 doi: 10.1039/c2dt12474b
43. [43]
  Liang M J, Yang Z Y, Yang Y, et al. J. Mater. Sci.-Mater. Electron., 2019, 30(2):1310-1321 doi: 10.1007/s10854-018-0400-7
44. [44]
  Gong Y, Zhao X, Zhang H, et al. Appl. Catal. B, 2018, 333:35-45
45. [45]
  Tang L, Feng C Y, Deng Y C, et al. Appl. Catal. B, 2018, 230:102-114 doi: 10.1016/j.apcatb.2018.02.031
1. [1]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
4. [4]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
5. [5]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
6. [6]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
7. [7]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
8. [8]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
9. [9]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
10. [10]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
11. [11]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
12. [12]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
13. [13]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
14. [14]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
15. [15]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
16. [16]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
17. [17]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
18. [18]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
19. [19]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
20. [20]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(1522)
HTML views(304)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

One-Step Preparation and Photocatalytic Activity of Bi2MoO6/CoMoO4 Embroidery Ball Structure

Metrics

通讯作者: 陈斌, bchen63@163.com

One-Step Preparation and Photocatalytic Activity of Bi₂MoO₆/CoMoO₄ Embroidery Ball Structure