Citation: GAO Ling-Ling, NIU Xiao-Yan, DU Yi-En, HU Tuo-Ping. Luminescence Sensing and Magnetic Property of Three Metal-Organic Complexes Based on 3, 5-Di(2', 5'-dicarboxylphenyl)benozoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1383-1392. doi: 10.11862/CJIC.2020.161 shu

Luminescence Sensing and Magnetic Property of Three Metal-Organic Complexes Based on 3, 5-Di(2', 5'-dicarboxylphenyl)benozoic Acid

1.
College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, China
2.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China

Corresponding author: DU Yi-En, duyien124@163.com HU Tuo-Ping, hutuopingsx@126.com
Received Date: 4 December 2019
Revised Date: 1 February 2020

Figures(16)

Three new metal-organic complexes(MOCs), namely {[Pb₂(HL)(phen)]·2H₂O}_n (1), {[Ni(H₃L)(4, 4'-bipy)_1.5 (H₂O)₄]·6H₂O}_n (2) and {[Ni₂(HL)(1, 4-bibb)(H₂O)]·(CH₃CN)·H₂O}_n (3), have been synthesized by the V-pattern multicarboxylic acid ligand of H₅L (H₅L=3, 5-di(2', 5'-dicarboxylpyl)benozoic acid, phen=1, 10-phenanthroline, 4, 4'-bipy=4, 4'-bipyridine, 1, 4-bibb=1, 4-bis(benzimidazole)benzene) and Pb(Ⅱ)/Ni(Ⅱ) under solvothermal condition. 1 is a 1D chains structure with the binuclear[Pb₂(μ₂-COO)₂(μ₁-COO)₄] SBUs. 2 shows 2D lamellar networks with the point symbol of {4.6²}₂{4².6².8²}. 3 presents a 3D network structure with the point symbol of {6².8⁴}{6⁴.8²}₂. The fluorescence measurements show that 1 has highly sensitive detection for Fe³⁺ and Cr₂O₇^2- ions in aqueous solution by luminescence quenching effect. Meanwhile, the possible sensing mechanisms of 1 to Fe³⁺ and Cr₂O₇^2- were also investigated. Then, the variable-temperature magnetic susceptibility measurements reveal that 3 has antiferromagnetic interactions between the Ni(Ⅱ) ions.
- 3, 5-di(2', 5'-dicarboxylphenyl)benozoic acid,
- metal-organic framework,
- luminescent properties,
- magnetic property
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