Citation: CHEN Jin-Wei, ZHAO Zhen-Yu, LI Yu, ZOU Xun-Zhong, FENG An-Sheng. Syntheses, Crystal Structures, Luminescence and Photocatalytic Activity of Three Dinuclear Zinc(Ⅱ) and Cadmium(Ⅱ) Coordination Compounds Based on 4, 4'-Dimethyl-2, 2'-biphenyldicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1344-1352. doi: 10.11862/CJIC.2020.157 shu

Syntheses, Crystal Structures, Luminescence and Photocatalytic Activity of Three Dinuclear Zinc(Ⅱ) and Cadmium(Ⅱ) Coordination Compounds Based on 4, 4'-Dimethyl-2, 2'-biphenyldicarboxylic Acid

1.
School of Light Chemical Engineering/Guangdong Research Center for Special Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Intelligent Manufacturing and Equipment, Shenzhen Institute of Information Technology, Shenzhen, Guangdong 518172, China

Corresponding author: ZHAO Zhen-Yu, yxpzzy01@163.com LI Yu, liyuletter@163.com
Received Date: 1 November 2019
Revised Date: 8 March 2020

Figures(13)

Three 0D dinuclear zinc(Ⅱ) and cadmium(Ⅱ) coordination compounds, namely[Zn₂(μ-dbda)₂(phen)₂(H₂O)₂] (1), [Zn₂(μ-dbda)₂(2, 2'-bipy)₂] (2), and[Cd₂(μ-dbda)₂(2, 2'-bipy)₂(H₂O)₂]·2H₂O (3), have been constructed hydrothermally using H₂dbda (H₂dbda=4, 4'-dimethyl-2, 2'-biphenyldicarboxylic acid), phen (phen=1, 10-phenanthroline), 2, 2' -bipy (2, 2'-bipy=2, 2'-bipyridine), and zinc or cadmium chlorides. Single-crystal X-ray diffraction analyses reveal that three compounds crystallize in the triclinic or monoclinic systems, space groups P1 or P2₁/n. All compounds disclose a discrete dimer structure, which is assembled to a 3D supramolecular framework through O-H…O hydrogen bonds. The luminescent and photocatalytic properties of three compounds were investigated, showing that compound 3 is a promising photocatalyst for the UV-light-driven degradation of methylene blue as a model organic dye pollutant.
- coordination compound,
- 4, 4'-dimethyl-2, 2'-biphenyldicarboxylic acid,
- luminescence,
- photocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142