Citation: DU Ci, CHU Zeng-Yong, HU Tian-Jiao, WU Wen-Jian, LI Xiao-Dong. Effect of Magnetic Field on Tetraphenylporphyrin and Its Co(Ⅱ)/Zn(Ⅱ) Coordination Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1291-1297. doi: 10.11862/CJIC.2020.156 shu

Effect of Magnetic Field on Tetraphenylporphyrin and Its Co(Ⅱ)/Zn(Ⅱ) Coordination Compounds

Department of chemistry and biology, National University of Defense Technology, Changsha 410073, China

Corresponding author: LI Xiao-Dong, xdli0153@sina.com
Received Date: 18 November 2019
Revised Date: 27 March 2020

Figures(10)

To investigate the effect of strong magnetic field on the chemical reactions and properties of biological important molecules, as a part of this research, tetra-phenyl porphyrin and its metalloporphyrin coordination reaction were chosen to extended study. The TPP crystals, obtained at different magnetic field, were measured by X-ray powder diffraction. The yields of cobalt porphyrin (CoTPP) and zinc porphyrin (ZnTPP) at different magnetic field intensities were determined by UV -Vis spectrophotometer. The conversion rates of cobalt porphyrin (CoTPP) and zinc porphyrin (ZnTPP) in different magnetic fields, as well as the reaction kinetics of Co²⁺ and Zn²⁺ coordination with TPP were analyzed, respectively. The results show that the crystallinity of TPP increases with the intensity of magnetic field. The yield and reaction rate of CoTPP and ZnTPP decreased with the increase of magnetic field intensity, but the magnetic field intensity made no effect on the reaction kinetics. According to the research results, high magnetic field is beneficial to the crystallization of tetraphenyl porphyrin, and the orientation of tetraphenyl porphyrin perpendicular to the magnetic field in the solution is the main reason for the decrease of coordination reaction rate. With the increase of magnetic field intensity, the orientation degree of tetraphenyl porphyrin increases.
- high magnetic field,
- tetraphenyl porphyrin,
- coordination reaction,
- crystallization,
- orientation
1. [1]
  [1] Zhang Y B, Tan Y W, Stormer H L, et al. Nature, 2005, 438(7065):201-204 doi: 10.1038/nature04235
2. [2]
  Novoselov K S, Geim A K, Morozov S V, et al. Nature, 2005, 438(7065):197-200 doi: 10.1038/nature04233
3. [3]
  Schaefer W H, Harris T M, Guengerich F P. Biochemistry, 1985, 24(13):3254-3263 doi: 10.1021/bi00334a027
4. [4]
  Traylor T G, Koga N, Deardurff L A. J. Am. Chem. Soc., 1985, 107(23):6504-6510 doi: 10.1021/ja00309a014
5. [5]
  Shikama K, Matsuoka A. Eur. J. Biochem., 2003, 270(20):4041-4051 doi: 10.1046/j.1432-1033.2003.03791.x
6. [6]
  Chakraborti A S. Mol. Cell. Biochem., 2003, 253(1/2):49-54 doi: 10.1023/A:1026097117057
7. [7]
  Yonetani T. J. Biol. Chem., 1966, 241(11):2562-2571
8. [8]
  Hayashi T, Takimura T, Ogoshi H. J. Am. Chem. Soc., 1995, 117(46):11606-11607 doi: 10.1021/ja00151a037
9. [9]
  Li J R, Sculley J, Zhou H C. Chem. Rev., 2012, 112(2):869932
10. [10]
  Horcajada P, Gref R, Baati T, et al. Chem. Rev., 2012, 112:1232-1268 doi: 10.1021/cr200256v
11. [11]
  Stone A, Fleischer E B. J. Am. Chem. Soc., 1968, 90(11):2735-2748 doi: 10.1021/ja01013a001
12. [12]
  WANG Cheng, Zhang T, Lin W B. Chem. Rev., 2011, 112(2):1084-1104
13. [13]
  Papadopoulos A G, Charistos N D, Muñoz-Castro A. ChemPhysChem, 2017, 189(12):1499-1502
14. [14]
  Makarkina A V, Golotvin S S, Chertkov V A. Chem. Heterocycl. Compd., 1995, 31(9):1060-1064 doi: 10.1007/BF01165051
15. [15]
  Yoon D K, Lee S R, Kim Y H, et al. Physica B, 2006, 385386(part 1):801-803
16. [16]
  Kaneko Y, Onodera T, Kasai H, et al. J. Mater. Chem., 2005, 15(2):253-255 doi: 10.1039/b412351d
17. [17]
  Peeks M D, Claridge T D W, Anderson H L. Nature, 2016, 541(7636):200-203
18. [18]
  Bothner-By A A, Gayathri C, van Zijl P C M, et al. Magn. Reson. Chem., 1985, 23(11):935-938 doi: 10.1002/mrc.1260231111
19. [19]
  Waliszewski P, Skwarek R, Jeromin L, et al. J. Photochem. Photobiol., 1999, 52(1/2/3):137-140
20. [20]
  Gurinovich V V, Tsvirko M P. J. Appl. Spectrosc., 2000, 67(6):1016-1022 doi: 10.1023/A:1004180623365
21. [21]
  Morii N, Kido G, Konakahara T, et al. Biomacromolecules, 2005, 6(6):3259-3266 doi: 10.1021/bm050302z
22. [22]
  Adler A D, Sklar L, Longo F R, et al. J. Heterocycl. Chem., 1968, 5(5):669-678 doi: 10.1002/jhet.5570050513
23. [23]
  WANG Zhou-Feng, DENG Wen-Li. Prog. Chem., 2007(4):86-92
24. [24]
  Kano K, Fukuda K, Wakami H, et al. J. Am. Chem. Soc., 2000, 122(31):7494-7502 doi: 10.1021/ja000738g
1. [1]
  Yan Xiao , Shuling Li , Yifan Li , Jianing Fan , Linlin Shi . Discovering the Beauty of Life: Adding Some “Ingredients” to Crystals. University Chemistry, 2024, 39(6): 366-372. doi: 10.3866/PKU.DXHX202312025
2. [2]
  Ming Li , Zhaoyin Li , Mengzhu Liu , Shaoxiang Luo . Unveiling the Artistry of Mordant Dyeing: The Coordination Chemistry Beneath. University Chemistry, 2024, 39(5): 258-265. doi: 10.3866/PKU.DXHX202311085
3. [3]
  Quanguo Zhai , Peng Zhang , Wenyu Yuan , Ying Wang , Shu'ni Li , Mancheng Hu , Shengli Gao . Reconstructing the “Fundamentals of Coordination Chemistry” in Inorganic Chemistry Course. University Chemistry, 2024, 39(11): 117-130. doi: 10.12461/PKU.DXHX202403065
4. [4]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
5. [5]
  Gonglan Ye , Xia Yin , Feng Xu , Peng Yang , Yingpeng Wu , Huilong Fei . Innovations in “Four-in-One” Inorganic Chemistry Education. University Chemistry, 2024, 39(8): 136-141. doi: 10.3866/PKU.DXHX202401071
6. [6]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
7. [7]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
8. [8]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
9. [9]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
10. [10]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
11. [11]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
12. [12]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
13. [13]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
14. [14]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
15. [15]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
16. [16]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
17. [17]
  Jinglun Wang , Hu Zhou , Baishu Zheng , Guobin Li , Ming Yue , Zhihua Zhou . Exploration and Practice of “Four Cooperations and Four Integrations” to Cultivate Innovative Talents in Chemical Materials in Local Colleges. University Chemistry, 2024, 39(7): 93-98. doi: 10.12461/PKU.DXHX202405013
18. [18]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
19. [19]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
20. [20]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(704)
HTML views(229)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142