Citation: DU Ci, CHU Zeng-Yong, HU Tian-Jiao, WU Wen-Jian, LI Xiao-Dong. Effect of Magnetic Field on Tetraphenylporphyrin and Its Co(Ⅱ)/Zn(Ⅱ) Coordination Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1291-1297. doi: 10.11862/CJIC.2020.156 shu

Effect of Magnetic Field on Tetraphenylporphyrin and Its Co(Ⅱ)/Zn(Ⅱ) Coordination Compounds

Department of chemistry and biology, National University of Defense Technology, Changsha 410073, China

Corresponding author: LI Xiao-Dong, xdli0153@sina.com
Received Date: 18 November 2019
Revised Date: 27 March 2020

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To investigate the effect of strong magnetic field on the chemical reactions and properties of biological important molecules, as a part of this research, tetra-phenyl porphyrin and its metalloporphyrin coordination reaction were chosen to extended study. The TPP crystals, obtained at different magnetic field, were measured by X-ray powder diffraction. The yields of cobalt porphyrin (CoTPP) and zinc porphyrin (ZnTPP) at different magnetic field intensities were determined by UV -Vis spectrophotometer. The conversion rates of cobalt porphyrin (CoTPP) and zinc porphyrin (ZnTPP) in different magnetic fields, as well as the reaction kinetics of Co²⁺ and Zn²⁺ coordination with TPP were analyzed, respectively. The results show that the crystallinity of TPP increases with the intensity of magnetic field. The yield and reaction rate of CoTPP and ZnTPP decreased with the increase of magnetic field intensity, but the magnetic field intensity made no effect on the reaction kinetics. According to the research results, high magnetic field is beneficial to the crystallization of tetraphenyl porphyrin, and the orientation of tetraphenyl porphyrin perpendicular to the magnetic field in the solution is the main reason for the decrease of coordination reaction rate. With the increase of magnetic field intensity, the orientation degree of tetraphenyl porphyrin increases.
- high magnetic field,
- tetraphenyl porphyrin,
- coordination reaction,
- crystallization,
- orientation
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