Citation: LIU Tian-Bao, PENG Yan-Fen. Synthesis, Structure and Photocatalytic Properties of a 10-Connected 3D Coordination Polymer Based on[Cu₄(μ₂-OH)₂N₁₂][J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1327-1332. doi: 10.11862/CJIC.2020.150 shu

Synthesis, Structure and Photocatalytic Properties of a 10-Connected 3D Coordination Polymer Based on[Cu₄(μ₂-OH)₂N₁₂]

LIU Tian-Bao ,
PENG Yan-Fen ^,

College of Materials and Environmental Engineering, Key Laboratory of Micro-Nano Powder and Advanced Energy Materials of Anhui Higher Education Institutes, Chizhou University, Chizhou, Anhui 247000, China

Corresponding author: PENG Yan-Fen, pengyanfen1978@126.com
Received Date: 22 September 2019
Revised Date: 25 April 2020

Figures(9)

One new coordination polymer, {[Cu₂(OH)(btre)_1.5(1, 2, 4-btc)]·13H₂O}_n (1·13H₂O) (btre=1, 2-bis(4H-1, 2, 4-triazole)ethane, 1, 2, 4-btc=1, 2, 4-benzenetricarboxylate), was synthesized under room temperature condition and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy and powder X-ray diffraction. Sing-crystal X-ray structural analysis shows that compound 1 features a 3D framework based on the tetranuclear[Cu₄ (μ₂-OH)₂N₁₂]. The 3D coordination network of 1 is a 10-connected network with (3¹²·4²⁸·5⁵) topology based on the tetranuclear copper cluster nodes. The thermogravimetric (TG) analysis and photocatalytic degradation of methyl orange (MO) of 1·13H₂O were studied.
- 10-connected network,
- copper(Ⅱ) coordination polymer,
- photocatalysis,
- 1, 2-bis(4H-1, 2, 4-triazole)ethane
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Synthesis, Structure and Photocatalytic Properties of a 10-Connected 3D Coordination Polymer Based on[Cu4(μ2-OH)2N12]

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Synthesis, Structure and Photocatalytic Properties of a 10-Connected 3D Coordination Polymer Based on[Cu₄(μ₂-OH)₂N₁₂]