Citation: CAO Qun, WU Shi-Kui, LI Yan. Preparation and Adsorption Properties of Hollow Magnetic Carbon Nanospheres Using Acorn as Carbon Source[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1233-1240. doi: 10.11862/CJIC.2020.148 shu

Preparation and Adsorption Properties of Hollow Magnetic Carbon Nanospheres Using Acorn as Carbon Source

CAO Qun ¹ ,
WU Shi-Kui ^1,2,, ,
LI Yan ²

1.
College of Pharmacy, Inner Mongolia Medical University, Hohhot 010110, China
2.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: WU Shi-Kui, shikuiwu@yahoo.com
Received Date: 17 July 2019
Revised Date: 25 April 2020

Figures(9)

Magnetic hollow carbon nanospheres (MHCNS) with uniform particle size were prepared by high temperature calcination using acorn as carbon source. MHCNS-1 can be obtained by HCl soaking treatment, and then treated with HNO₃ and NH₃·H₂O to obtain MHCNS-2. MHCNS-2 had a uniform particle size with a diameter of 20~40 nm and a wall thickness of 3~5 nm. The size of MHCNS can be adjusted by changing the amount and ratio of Ni²⁺ and KOH. The prepared products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometer and transmission electron microscopy (TEM). The growth mechanism of MHCNS was analyzed. The results of the adsorption performance of MHCNS-2 on the organic dye methylene blue (MB) show that MHCNS-2 has strong adsorption performance. When the concentration of MB solution was 100 mg·L^-1, the adsorption amount could reach 185 mg·g^-1. The results of MHCNS-2 on drug-loaded drug release of ibuprofen showed that the drug-loading rate of MHCNS-2 was up to 44% and the drug release rate was 70%, which means that it has good drug-loading and drug-releasing ability.
- magnetic hollow carbon nanospheres (MHCNS),
- acorns,
- adsorption,
- dyes,
- drug-loaded microspheres,
- drug release
1. [1]
2. [2]
  Prieto G, Tuysuz H, Duyckaerts N, et al. Chem. Rev., 2016, 116(22):14056-14119 doi: 10.1021/acs.chemrev.6b00374
3. [3]
  Parlett C M, Wilson K, Lee A F. Chem. Soc. Rev., 2013, 42(9): 3876-3893 doi: 10.1039/C2CS35378D
4. [4]
  Zhang J W, Jiang Y T, Shi S L, et al. Chem. Commun., 2019, 55(34):4989-4992 doi: 10.1039/C9CC01572H
5. [5]
  Carraro G, Sugranez R, Maccato C, et al. Thin Solid Films, 2014, 564(1):121-127
6. [6]
7. [7]
  Radovic L R, Bockrath B. J. Am. Chem. Soc., 2005, 127(16): 5917-5927 doi: 10.1021/ja050124h
8. [8]
  Yu Y, Gu L, Zhu C, et al. J. Am. Chem. Soc., 2009, 131(44): 15984-15985 doi: 10.1021/ja906261c
9. [9]
  Tsai W Y, Taberna P L, Simon P. J. Am. Chem. Soc., 2014, 136(24):8722-8728 doi: 10.1021/ja503449w
10. [10]
11. [11]
  Kennedy L J, Vijaya J J, Sekaran G. Mater. Chem. Phys., 2005, 91(2):471-476
12. [12]
  Liu D Q, Jia Z, Wang D L. Carbon, 2016, 100:664-677 doi: 10.1016/j.carbon.2016.01.069
13. [13]
  Yang W, Ding F, Shao G, et al. Carbon, 2017, 111:419-427 doi: 10.1016/j.carbon.2016.10.025
14. [14]
  Zheng C, Zhou X F, Cao H L, et al. J. Power Sources, 2014, 258(15):290-296
15. [15]
  Long C, Zhuang J L, Xiao Y, et al. J. Power Sources, 2016, 310(1):145-153
16. [16]
  Guo H L, Gao Q M. Int. J. Hydrogen Energy, 2010, 35(14):7547-7554 doi: 10.1016/j.ijhydene.2010.04.169
17. [17]
  Rani R, Kumar V, Rizzolio F. ACS Med. Chem. Lett., 2018, 9(1):4-5 doi: 10.1021/acsmedchemlett.7b00523
18. [18]
  Zhou L B, Jing Y, Liu Y B, et al. Theranostics, 2018, 8(3):663 -675 doi: 10.7150/thno.21927
19. [19]
  Zhao Y, Jiang L. Adv. Mater., 2009, 21(36):3621- 3638 doi: 10.1002/adma.200803645
20. [20]
  Vix - Guterl C, Frackowiak E, Jurewicz K, et al. Carbon, 2005, 43(6):1293-1302 doi: 10.1016/j.carbon.2004.12.028
21. [21]
  Hu B, Wang K, Wu L, et al. Adv. Mater., 2010, 22(7):813-828 doi: 10.1002/adma.200902812
22. [22]
  Sevilla M, Parra J B, Fuertes A B. ACS Appl. Mater. Interfaces, 2013, 5(13):6360-6368 doi: 10.1021/am401423b
23. [23]
  Wu S K, Shen X P, Zhu G X, et al. Carbon, 2017, 116 :68-76 doi: 10.1016/j.carbon.2017.01.085
24. [24]
  Zhang X T, Chen W X. Microporous Mesoporous Mater., 2015, 206:194-201 doi: 10.1016/j.micromeso.2014.12.002
25. [25]
26. [26]
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