Citation: WU Xiao-Min, MAO Jian, ZHOU Zhi-Peng, ZHANG Chen, BU Jing-Ting, LI Zhen. Building a High-Performance Supercapacitor with Nitrogen-Doped Graphene Quantum Dots/MOF-Derived Porous Carbon Nanosheets[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1298-1308. doi: 10.11862/CJIC.2020.139 shu

Building a High-Performance Supercapacitor with Nitrogen-Doped Graphene Quantum Dots/MOF-Derived Porous Carbon Nanosheets

School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

Corresponding author: LI Zhen, lizhen@shu.edu.cn
Received Date: 27 December 2019
Revised Date: 2 April 2020

Figures(7)

Co-MOF two-dimensional nanosheets were first grown on a carbon cloth by solution method, and MOFderived porous carbon nanosheets were obtained after high temperature annealing and etching process. Co-MOF derived porous carbon nanosheets/carbon cloths (CNSs/CC) was used as the carbon-based framework, and highly active nitrogen-doped graphene quantum dots (N-GQDs) were loaded by electrochemical deposition to prepare hierarchical porous structures N-GQD/CNS/CC composite material as electrode material for supercapacitors. The N-GQD/CNS/CC electrode, as a self-supporting and adhesive-free electrode, delivered a specific capacitance of 423 F·g^-1 at 1 A·g^-1. According to the mechanism of energy storage and capacitance contribution, the N-GQD/CNS/CC composite is an ideal supercapacitor electrode material with high capacitance, due to synergetic effect between CNS grown in situ on carbon fiber with high double-layer capacitance and N-GQDs loaded on the surface with high pseudo-capacitance. The highly conductive, hierarchical porous structure of the electrode material is beneficial to the electron transport and the diffusion of electrolyte ions, which presents good kinetic performance, high rate performance and rapid charge-discharge capability. A symmetrical supercapacitor based on N -GQD/CNS/CC electrode exhibited a high energy density of 250 W·kg^-1 at power density of 7.9 Wh·kg^-1, while the capacitance retention after 10 000 cycles reached 91.2%, which indicates that the N-GQD/CNS/CC composite is an all-carbon electrode material with stable electrochemical performance and high capacitance performance.
- porous carbon nanosheets,
- nitrogen-doped,
- quantum dots,
- electrochemistry,
- supercapacitors
1. [1]
  Zhang C, Wei Y L, Cao P F, et al. Renewable Sustainable Energy Rev., 2018, 82:3091-3106 doi: 10.1016/j.rser.2017.10.030
2. [2]
  CHEN Chan-Juan, HU Zhong-Ai, HU Ying -Ying, et al. Acta Phys.-Chim. Sin., 2014, 30(12):2256-2262 doi: 10.3866/PKU.WHXB201409302
3. [3]
  ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, et al. Acta Phys.-Chim. Sin., 2014, 30(5):881-890
4. [4]
  TONG Yong-Li, DAI Mei-Zhen, XING Lei, et al. Acta Phys.-Chim. Sin., 2020, 36(7):1903046
5. [5]
  DU Wei-Shi, LÜ Yao-Kang, CAI Zhi-Wei, et al. Acta Phys.-Chim. Sin., 2017, 33(9):1828-1837
6. [6]
  May G J, Davidson A, Monahov B. J. Energy Storage, 2018, 15:145-157 doi: 10.1016/j.est.2017.11.008
7. [7]
  Kazempour S J, Moghaddam M P, Haghifam M R, et al. Renew. Energy, 2009, 34(12):2630-2639 doi: 10.1016/j.renene.2009.04.027
8. [8]
  Diaz-Gonzalez F, Sumper A, Gomis-Bellmunt O, et al. Renewable Sustainable Energy Rev., 2012, 16(4):2154-2171
9. [9]
  Kaldellis J K, Zafirakis D. Energy, 2007, 32(12):2295-2305 doi: 10.1016/j.energy.2007.07.009
10. [10]
  He D L, Zhao W, Li P, et al. Appl. Surf. Sci., 2019, 465:303312
11. [11]
  LI Xue-Qin, CHANG Lin, ZHAO Shen-Long, et al. Acta Phys.-Chim. Sin., 2017, 33(1):130-148
12. [12]
  XIN Ran-Ran, MIAO Hang-Jin, JIANG Wei, et al. Chinese J. Inorg. Chem., 2019, 35(10):1781-1790 doi: 10.11862/CJIC.2019.222
13. [13]
  Divya K C, Ostergaard J. Electr. Power Syst. Res., 2009, 79(4):511-520
14. [14]
  GUO Nan-Nan, ZHANG Su, WANG Lu Xiang, et al. Acta Phys.-Chim. Sin., 2020, 36(2):1903055
15. [15]
  Cao X H, Zheng B, Shi W H, et al. Adv. Mater., 2015, 27(32):4695-4701 doi: 10.1002/adma.201501310
16. [16]
  Li X, Gu T L, Wei B Q. Nano Letti., 2012, 12(12):6366-6371 doi: 10.1021/nl303631e
17. [17]
  Dahal B, Mukhiya T, Ojha G P, et al. Electrochim. Acta, 2019, 301:209-219 doi: 10.1016/j.electacta.2019.01.171
18. [18]
  Li S M, Yang K, Ya P, et al. Appl. Surf. Sci., 2020, 503:144090 doi: 10.1016/j.apsusc.2019.144090
19. [19]
  Li Z X, Yang B L, Kong L J, et al. Carbon, 2019, 144:540548
20. [20]
  Jiang W C, Pan J Q, Liu X G. J. Power Sources, 2019, 409:13-23 doi: 10.1016/j.jpowsour.2018.10.086
21. [21]
  JIA Zhao-Yang, LIU Mei-Nan, ZHAO XinLuo, et al. Acta Phys.-Chim. Sin., 2017, 33(12):2510-2516 doi: 10.3866/PKU.WHXB201705311
22. [22]
  ZHU Jia-Yao, DONG Yue, ZHANG Su, et al. Acta Phys.-Chim. Sin., 2020, 36(2):1903052
23. [23]
  Xue Q, Huang H, Wang L, et al. Nanoscale, 2013, 5(24):12098-12103 doi: 10.1039/c3nr03623e
24. [24]
  Wang L, Wang Y L, Xu T, et al. Nat. Commun., 2014, 5:6367
25. [25]
  Li Z, Cao L, Qin P, et al. Carbon, 2018, 139:67-75 doi: 10.1016/j.carbon.2018.06.042
26. [26]
  Li Z, Liu X, Wang L, et al. Small, 2018, 14(39):1801498 doi: 10.1002/smll.201801498
27. [27]
  Pan D Y, Huang H, Wang X Y, et al. J. Mater. Chem. A, 2014, 2(29):11454-11464 doi: 10.1039/C4TA01613K
28. [28]
  Li Z, Bu F, Wei J J, et al. Nanoscale, 2018, 10(48):2287122883
29. [29]
  Li Z, Li Y F, Wang L, et al. Electrochim. Acta, 2017, 235:561-569 doi: 10.1016/j.electacta.2017.03.147
30. [30]
  Li Z, Qin P, Wang L, et al. Electrochim. Acta, 2016, 208:260266
31. [31]
  Li Z, Wei J J, Ren J, et al. Carbon, 2019, 154:410-419 doi: 10.1016/j.carbon.2019.08.040
32. [32]
  Ding Y C, Hu L H, He D C, et al. Chem. Eng. J., 2020, 380:122489 doi: 10.1016/j.cej.2019.122489
33. [33]
  Li Q, Zhou J J, Liu R, et al. Dalton Trans., 2019, 48(46):17163-17168 doi: 10.1039/C9DT03821C
34. [34]
  LIANG Xu, JIA Yu-Feng, LIU Zong-Huai, et al. Acta Phys.-Chim. Sin., 2020, 36(2):1903034
35. [35]
  Wang N, Zhao P, Liang K, et al. Chem. Eng. J., 2017, 307:105-112 doi: 10.1016/j.cej.2016.08.074
36. [36]
  Wei J, Zhou D D, Sun Z K, et al. Adv. Funct. Mater., 2013, 23(18):2322-2328 doi: 10.1002/adfm.201202764
37. [37]
  Yang Q J, Liu Y, Yan M, et al. Chem. Eng. J., 2019, 370:666676
38. [38]
  Brezesinski T, Wang J, Tolbert S H, et al. Nat. Mater., 2010, 9(2):146-151
39. [39]
  Puthusseri D, Aravindan V, Madhavi S, et al. Energy Environ. Sci., 2014, 7(2):728-735
40. [40]
  Gong C C, Wang X Z, Ma D H, et al. Electrochim. Acta, 2016, 220:331-339 doi: 10.1016/j.electacta.2016.10.120
41. [41]
  He X J, Li R C, Qiu J S, et al. Carbon, 2012, 50(13):49114921
42. [42]
  Ling Z, Wang Z Y, Zhang M D, et al. Adv. Funct. Mater., 2016, 26(1):111-119
43. [43]
  WU Zhong-Yu, FAN Lei, TAO You-Rong, et al. Chinese J. Inorg. Chem., 2018, 34(7):1249-1260
44. [44]
  Ma G F, Guo D Y, Sun K J, et al. RSC Adv., 2015, 5(79):64704-64710 doi: 10.1039/C5RA11179J
1. [1]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
2. [2]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
5. [5]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
6. [6]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
7. [7]
  Kuaibing Wang , Feifei Mao , Weihua Zhang , Bo Lv . Design and Practice of a Comprehensive Teaching Experiment for Preparing Biomass Carbon Dots from Rice Husk. University Chemistry, 2025, 40(5): 342-350. doi: 10.12461/PKU.DXHX202407042
8. [8]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
9. [9]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
10. [10]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
11. [11]
  Yu SU , Xinlian FAN , Yao YIN , Lin WANG . From synthesis to application: Development and prospects of InP quantum dots. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2105-2123. doi: 10.11862/CJIC.20240126
12. [12]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
13. [13]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
14. [14]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
15. [15]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
16. [16]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
17. [17]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
18. [18]
  Zeqiu Chen , Limiao Cai , Jie Guan , Zhanyang Li , Hao Wang , Yaoguang Guo , Xingtao Xu , Likun Pan . 电容去离子提锂技术中电极材料的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100089-. doi: 10.1016/j.actphy.2025.100089
19. [19]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
20. [20]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

Get Citation

PDF

XML

Metrics

PDF Downloads(44)
Abstract views(2911)
HTML views(1179)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142