Citation: WU Xiao-Min, MAO Jian, ZHOU Zhi-Peng, ZHANG Chen, BU Jing-Ting, LI Zhen. Building a High-Performance Supercapacitor with Nitrogen-Doped Graphene Quantum Dots/MOF-Derived Porous Carbon Nanosheets[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1298-1308. doi: 10.11862/CJIC.2020.139 shu

Building a High-Performance Supercapacitor with Nitrogen-Doped Graphene Quantum Dots/MOF-Derived Porous Carbon Nanosheets

  • Corresponding author: LI Zhen, lizhen@shu.edu.cn
  • Received Date: 27 December 2019
    Revised Date: 2 April 2020

Figures(7)

  • Co-MOF two-dimensional nanosheets were first grown on a carbon cloth by solution method, and MOFderived porous carbon nanosheets were obtained after high temperature annealing and etching process. Co-MOF derived porous carbon nanosheets/carbon cloths (CNSs/CC) was used as the carbon-based framework, and highly active nitrogen-doped graphene quantum dots (N-GQDs) were loaded by electrochemical deposition to prepare hierarchical porous structures N-GQD/CNS/CC composite material as electrode material for supercapacitors. The N-GQD/CNS/CC electrode, as a self-supporting and adhesive-free electrode, delivered a specific capacitance of 423 F·g-1 at 1 A·g-1. According to the mechanism of energy storage and capacitance contribution, the N-GQD/CNS/CC composite is an ideal supercapacitor electrode material with high capacitance, due to synergetic effect between CNS grown in situ on carbon fiber with high double-layer capacitance and N-GQDs loaded on the surface with high pseudo-capacitance. The highly conductive, hierarchical porous structure of the electrode material is beneficial to the electron transport and the diffusion of electrolyte ions, which presents good kinetic performance, high rate performance and rapid charge-discharge capability. A symmetrical supercapacitor based on N -GQD/CNS/CC electrode exhibited a high energy density of 250 W·kg-1 at power density of 7.9 Wh·kg-1, while the capacitance retention after 10 000 cycles reached 91.2%, which indicates that the N-GQD/CNS/CC composite is an all-carbon electrode material with stable electrochemical performance and high capacitance performance.
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    1. [1]

      Zhang C, Wei Y L, Cao P F, et al. Renewable Sustainable Energy Rev., 2018, 82:3091-3106  doi: 10.1016/j.rser.2017.10.030

    2. [2]

      CHEN Chan-Juan, HU Zhong-Ai, HU Ying -Ying, et al. Acta Phys.-Chim. Sin., 2014, 30(12):2256-2262  doi: 10.3866/PKU.WHXB201409302

    3. [3]

      ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, et al. Acta Phys.-Chim. Sin., 2014, 30(5):881-890
       

    4. [4]

      TONG Yong-Li, DAI Mei-Zhen, XING Lei, et al. Acta Phys.-Chim. Sin., 2020, 36(7):1903046
       

    5. [5]

      DU Wei-Shi, LÜ Yao-Kang, CAI Zhi-Wei, et al. Acta Phys.-Chim. Sin., 2017, 33(9):1828-1837
       

    6. [6]

      May G J, Davidson A, Monahov B. J. Energy Storage, 2018, 15:145-157  doi: 10.1016/j.est.2017.11.008

    7. [7]

      Kazempour S J, Moghaddam M P, Haghifam M R, et al. Renew. Energy, 2009, 34(12):2630-2639  doi: 10.1016/j.renene.2009.04.027

    8. [8]

      Diaz-Gonzalez F, Sumper A, Gomis-Bellmunt O, et al. Renewable Sustainable Energy Rev., 2012, 16(4):2154-2171
       

    9. [9]

      Kaldellis J K, Zafirakis D. Energy, 2007, 32(12):2295-2305  doi: 10.1016/j.energy.2007.07.009

    10. [10]

      He D L, Zhao W, Li P, et al. Appl. Surf. Sci., 2019, 465:303312

    11. [11]

      LI Xue-Qin, CHANG Lin, ZHAO Shen-Long, et al. Acta Phys.-Chim. Sin., 2017, 33(1):130-148
       

    12. [12]

      XIN Ran-Ran, MIAO Hang-Jin, JIANG Wei, et al. Chinese J. Inorg. Chem., 2019, 35(10):1781-1790  doi: 10.11862/CJIC.2019.222
       

    13. [13]

      Divya K C, Ostergaard J. Electr. Power Syst. Res., 2009, 79(4):511-520

    14. [14]

      GUO Nan-Nan, ZHANG Su, WANG Lu Xiang, et al. Acta Phys.-Chim. Sin., 2020, 36(2):1903055
       

    15. [15]

      Cao X H, Zheng B, Shi W H, et al. Adv. Mater., 2015, 27(32):4695-4701  doi: 10.1002/adma.201501310

    16. [16]

      Li X, Gu T L, Wei B Q. Nano Letti., 2012, 12(12):6366-6371  doi: 10.1021/nl303631e

    17. [17]

      Dahal B, Mukhiya T, Ojha G P, et al. Electrochim. Acta, 2019, 301:209-219  doi: 10.1016/j.electacta.2019.01.171

    18. [18]

      Li S M, Yang K, Ya P, et al. Appl. Surf. Sci., 2020, 503:144090  doi: 10.1016/j.apsusc.2019.144090

    19. [19]

      Li Z X, Yang B L, Kong L J, et al. Carbon, 2019, 144:540548

    20. [20]

      Jiang W C, Pan J Q, Liu X G. J. Power Sources, 2019, 409:13-23  doi: 10.1016/j.jpowsour.2018.10.086

    21. [21]

      JIA Zhao-Yang, LIU Mei-Nan, ZHAO XinLuo, et al. Acta Phys.-Chim. Sin., 2017, 33(12):2510-2516  doi: 10.3866/PKU.WHXB201705311

    22. [22]

      ZHU Jia-Yao, DONG Yue, ZHANG Su, et al. Acta Phys.-Chim. Sin., 2020, 36(2):1903052

    23. [23]

      Xue Q, Huang H, Wang L, et al. Nanoscale, 2013, 5(24):12098-12103  doi: 10.1039/c3nr03623e

    24. [24]

      Wang L, Wang Y L, Xu T, et al. Nat. Commun., 2014, 5:6367
       

    25. [25]

      Li Z, Cao L, Qin P, et al. Carbon, 2018, 139:67-75  doi: 10.1016/j.carbon.2018.06.042

    26. [26]

      Li Z, Liu X, Wang L, et al. Small, 2018, 14(39):1801498  doi: 10.1002/smll.201801498

    27. [27]

      Pan D Y, Huang H, Wang X Y, et al. J. Mater. Chem. A, 2014, 2(29):11454-11464  doi: 10.1039/C4TA01613K

    28. [28]

      Li Z, Bu F, Wei J J, et al. Nanoscale, 2018, 10(48):2287122883

    29. [29]

      Li Z, Li Y F, Wang L, et al. Electrochim. Acta, 2017, 235:561-569  doi: 10.1016/j.electacta.2017.03.147

    30. [30]

      Li Z, Qin P, Wang L, et al. Electrochim. Acta, 2016, 208:260266

    31. [31]

      Li Z, Wei J J, Ren J, et al. Carbon, 2019, 154:410-419  doi: 10.1016/j.carbon.2019.08.040

    32. [32]

      Ding Y C, Hu L H, He D C, et al. Chem. Eng. J., 2020, 380:122489  doi: 10.1016/j.cej.2019.122489

    33. [33]

      Li Q, Zhou J J, Liu R, et al. Dalton Trans., 2019, 48(46):17163-17168  doi: 10.1039/C9DT03821C

    34. [34]

      LIANG Xu, JIA Yu-Feng, LIU Zong-Huai, et al. Acta Phys.-Chim. Sin., 2020, 36(2):1903034
       

    35. [35]

      Wang N, Zhao P, Liang K, et al. Chem. Eng. J., 2017, 307:105-112  doi: 10.1016/j.cej.2016.08.074

    36. [36]

      Wei J, Zhou D D, Sun Z K, et al. Adv. Funct. Mater., 2013, 23(18):2322-2328  doi: 10.1002/adfm.201202764

    37. [37]

      Yang Q J, Liu Y, Yan M, et al. Chem. Eng. J., 2019, 370:666676

    38. [38]

      Brezesinski T, Wang J, Tolbert S H, et al. Nat. Mater., 2010, 9(2):146-151
       

    39. [39]

      Puthusseri D, Aravindan V, Madhavi S, et al. Energy Environ. Sci., 2014, 7(2):728-735
       

    40. [40]

      Gong C C, Wang X Z, Ma D H, et al. Electrochim. Acta, 2016, 220:331-339  doi: 10.1016/j.electacta.2016.10.120

    41. [41]

      He X J, Li R C, Qiu J S, et al. Carbon, 2012, 50(13):49114921

    42. [42]

      Ling Z, Wang Z Y, Zhang M D, et al. Adv. Funct. Mater., 2016, 26(1):111-119

    43. [43]

      WU Zhong-Yu, FAN Lei, TAO You-Rong, et al. Chinese J. Inorg. Chem., 2018, 34(7):1249-1260
       

    44. [44]

      Ma G F, Guo D Y, Sun K J, et al. RSC Adv., 2015, 5(79):64704-64710  doi: 10.1039/C5RA11179J

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