Citation: WU Yu, LIU Jia-Cheng. Self-Assembly with Two Zinc Porphyrins Coordination Polymers for Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1283-1290. doi: 10.11862/CJIC.2020.137 shu

Self-Assembly with Two Zinc Porphyrins Coordination Polymers for Dye-Sensitized Solar Cells

WU Yu ^1,, ,
LIU Jia-Cheng ^2,,

1.
School of Chemistry and Chemical Engineering, Qiannan Normal University for Nationalities, Duyun, Guizhou 558000, China
2.
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

Corresponding author: WU Yu, ywu5@sgmtu.edu.cn LIU Jia-Cheng, jcliu8@nwnu.edu.cn
Received Date: 3 February 2020
Revised Date: 2 April 2020

Figures(10)

Two new zinc porphyrin with different donor units based Mn(Ⅱ) ion coordination polymers (CPsx, x=1, 2) have been designed, synthesized, and well-characterized. Two coordination polymers and anchor porphyrin (ZnPA) self-assembly by metal-ligand axial coordination to modify the nano-structured TiO₂ electrode surface has been investigated in photoelectrochemical device. The assembled processes of CPsx-ZnPA on TiO₂ surface were as follows:a porphyrin molecule (ZnPA) as anchoring group was immobilized on the TiO₂ electrode surface through carboxylic groups, then the desired dye of CPsx was bound to the anchoring group through axially coordination bonded from porphyrin central Zn(Ⅱ) ions of CPsx and the N atom of ZnPA. Our results reveal that the self-assemblies devices show significantly improved photocurrent conversion efficiency. Particularly, CPs2 based solar cell displayed a PCE (power conversion efficiency) of 1.89%, and the J_sc was 4.82 mA·cm^-2. This indicates that the supramolecular coordination polymers self-assembly strategy has been successfully applied in dye-sensitized solar cells (DSSC). Their optical performance and electrochemical impedance spectroscopy were also investigated to further understand the photoelectrochemical results. In addition, the assembled modes of the assemblies immobilized on TiO₂ electrode surfaces were also verified by transmission electron microscopy (TEM).
- dye-sensitized solar cells,
- zinc porphyrin,
- self-assembly,
- coordination polymer
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