Citation: QI Xiao-Wei, LIU Jian, YANG Qian-Ying, ZHANG Hua-Hong, HAN Li-Zhi, ZHANG Xiao-Peng, SHI Zai-Feng. Stretch-Induced Luminescent Changes of a Self-Healing Elastic Polymer Functionalized with Platinum Complex[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 933-940. doi: 10.11862/CJIC.2020.107 shu

Stretch-Induced Luminescent Changes of a Self-Healing Elastic Polymer Functionalized with Platinum Complex

1.
College of Chemistry and Chemical Engineering, Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province, Hainan Normal University, Haikou 571158, China
2.
College of Chemical Engineering, Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: ZHANG Xiao-Peng, xpzhang@hainnu.edu.cn SHI Zai-Feng, zaifengshi@163.com
Received Date: 19 November 2019
Revised Date: 12 March 2020

Figures(10)

An elastic orange-red film (PDMS-PtL1) has been prepared by grafting formyl-containing Pt(Ⅱ) complex Pt(N^C^N)Cl (N^C^N=1, 3-dipyridyl benzene) onto polydimethylsiloxane (PDMS) backbone. The film was highly stretchable (up to 1500% strain) and shows room-temperature self-healing property. Interestingly, stretch-induced luminescent change of the film was observed, where an emission tentatively originating from ³π-π^* of separated platinum moieties was detected after stretching. Luminescence quenching is avoided in this elastic film, and the switch of emission state can be realized by changing external forces.
- platinum complex,
- functional film,
- stretch,
- self-healing,
- luminescent change
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沈阳化工大学材料科学与工程学院沈阳 110142