Citation: MA Yu-Hua, AINIWA·Munire, ZHU En-Quan, SU Zhi. Hierarchically Porous Nanosized Red Phosphorus with Enhanced Photo-Oxidation and Photo-Reduction Activities[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 949-957. doi: 10.11862/CJIC.2020.106 shu

Hierarchically Porous Nanosized Red Phosphorus with Enhanced Photo-Oxidation and Photo-Reduction Activities

College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, 830054, China

Corresponding author: MA Yu-Hua, 15199141253@163.com SU Zhi, suzhixj@sina.com

Received Date: 2 December 2019
Revised Date: 10 March 2020

Figures(5)

The as-prepared red phosphorus showed a well-defined complicated porous and nano-sized structure, and the uppermost photocatalytic activity for the hydrothermal treatment 24 h red phosphorus (H-RP24h). The rate constants of the H-RP24h photo-oxidation of rhodamine B (RhB) and photo-reduction of Cr(Ⅵ) were 9.2×10^-2 and 3.4×10^-2 min^-1, 23 and 26 times superior to those of commercial red phosphorus, respectively. Further studies demonstrated that hydrothermal treatment effectively decreased the size of red phosphorus, enhanced light response, and accelerated the detachment of photogenerated electrons and holes (h⁺), thus increased its photocatalytic activity. It was found that the core reactive species in the photodegradation process were h⁺ and superoxide ion radicals.
- red phosphorus,
- photo-oxidation,
- photo-reduction,
- photocatalysis,
- hydrothermal synthesis
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