Citation: DAI Gao-Peng, ZHOU Jing-Hui, LONG Jia-Hao, LI Zun, LIU Li. Preparation and Selective Photoelectrocatalytic Degradation of Diethyl Phthalate of Molecularly Imprinted TiO₂ Nanotube Arrays[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 850-856. doi: 10.11862/CJIC.2020.104 shu

Preparation and Selective Photoelectrocatalytic Degradation of Diethyl Phthalate of Molecularly Imprinted TiO₂ Nanotube Arrays

DAI Gao-Peng ^1,2,, ,
ZHOU Jing-Hui ¹ ,
LONG Jia-Hao ¹ ,
LI Zun ¹ ,
LIU Li ¹

1.
Department of Chemical Engineering, Hubei University of Arts and Sciences, Xiangyang, Hubei 441053, China
2.
Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Xiangyang, Hubei 441053, China

Corresponding author: DAI Gao-Peng, dgp2000@126.com
Received Date: 19 November 2019
Revised Date: 20 March 2020

Figures(8)

Using diethyl phthalate (DEP) as template, molecularly imprinted TiO₂ nanoparticles were deposited on wall of TNA and DEP-molecularly-imprinted TNA (DM-TNA) was fabricated. X-ray diffraction (XRD) analysis demonstrated that crystal structure of DM-TNA was anatase. Scanning electron microscopy (SEM) measurements showed that TiO₂ nanoparticles with a size about 20 nm were uniformly coated on the wall of TNA. The results of photoelectrocatalytic degradation of the mixed solution of DEP and 2, 4-dichlorophenol (DCP) showed that the degradation activity of DEP on the DM-TNA was higher than that on non molecularly imprinted TNA (NM-TNA), while the degradation activity of DCP on the DM-TNA was lower than that on NM-TNA. The rate constant of DM-TNA for the degradation of DEP was 2.76 times that of NM-TNA.
- photocatalysis,
- photodegradation,
- selectivity,
- molecular imprinting,
- TiO₂ nanotube array,
- diethyl phthalate
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Preparation and Selective Photoelectrocatalytic Degradation of Diethyl Phthalate of Molecularly Imprinted TiO₂ Nanotube Arrays