Citation: GAO Xian-Long, MO Wen-Long, MA Feng-Yun, FAN Xing. Effect of Promoter on the Ni-Al Alloy & the Corresponding Raney-Ni Catalyst and Hydrogenation Performance of 1, 4-Butylenediol[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 958-968. doi: 10.11862/CJIC.2020.102 shu

Effect of Promoter on the Ni-Al Alloy & the Corresponding Raney-Ni Catalyst and Hydrogenation Performance of 1, 4-Butylenediol

Key Laboratory of Coal Clean Conversion & Chemical Engineering Process(Xinjiang Uyghur Autonomous Region), College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: MO Wen-Long, mowenlong@xju.edu.cn
Received Date: 19 December 2019
Revised Date: 13 March 2020

Figures(13)

Three promoters (MgO, CuO, Co₂O₃) were introduced individually into the commercial Ni-Al alloy powder by impregnation method, and the modified alloys were leached by 10%(w/w) NaOH solution to prepare Raney-Ni catalysts. Effect of promoter on the elemental composition, crystal structure, pore structure, surface morphology and surface acidity of the Ni-Al alloy and the corresponding Raney-Ni catalyst was investigated by energy dispersive X-ray (EDX), X-ray diffraction (XRD), N₂ adsorption-desorption, transmission electron microscope (TEM), NH₃ temperature programmed desorption (NH₃-TPD) and X-ray photoelectron spectroscopy (XPS) methods. Results showed that the element content, specific surface area and surface morphology of the catalyst modified by different promoter proposed significant difference. Large amount of Ni- the active component on the Cu-modified catalyst was detected with the content of about 90%(w/w), showing excellent dispersion, and the catalyst presented small average pore size (3.87 nm). Evaluation results showed that the catalyst displayed well hydrogenation performance, with 1, 4-butenediol (BED) conversion of 100%, both 1, 4-butanediol (BDO) selectivity and yield of 59.62%, which was related to the high Ni content, the moderate amount of acid sites and the small Cu crystal for improving Ni dispersion without serious sintering by the "confinement effect".
- Raney-Ni catalyst,
- 1, 4-butenediol,
- 1, 4-butanediol,
- promoter,
- hydrogenation
1. [1]
  Zhang Q, Zhang Y, Li H T. Chin. J. Catal., 2013, 34:1159-1166 doi: 10.1016/S1872-2067(12)60525-7
2. [2]
  Ildikó M, Bodor Z, Réka S, et al. J. Biomol. Struct. Dyn., 2016, 35:1-16
3. [3]
  Minh D P, Michèle B, Pinel C, et al. Top. Catal., 2010, 53:1270-1273 doi: 10.1007/s11244-010-9580-y
4. [4]
  Tanielyan S, Schmidt S, Marin N, et al. Top. Catal., 2010, 53:1145-1149 doi: 10.1007/s11244-010-9550-4
5. [5]
  Kou Z N, Zhi Z N, Xu G H, et al. Appl. Catal. A, 2013, 467:196-201 doi: 10.1016/j.apcata.2013.07.025
6. [6]
  Amarasekara A S, Lawrence Y M, Fernandez A D, et al. Biofuels, 2018, 47:1-5
7. [7]
  Bendova D H, Weidlich D T. Sep. Sci. Technol., 2017, 53:1-5
8. [8]
  Luo G H, Wang Y L, Sun D M, et al. China Petroleum Processing & Petrochemical Technology, 2017, 19:14-20
9. [9]
  Lei H, Song Z, Tan D L, et al. Appl. Catal. A, 2001, 214:69-76 doi: 10.1016/S0926-860X(01)00481-1
10. [10]
  LEI Hao(雷浩). Dalian Institute of Chemical Physics(中国科学院大连化学物理研究所博士论文), 2003.
11. [11]
  Hort E V, Graham D E. US Patent, 2967893. 1961-01-10.
12. [12]
  Codignola F, Vergini G, Gronchi P, et al. US Patent, 4288641. 1981-09-18.
13. [13]
  Michalska K, Kowalik P, Konkol M, et al. Appl. Catal. A, 2016, 523:54-60 doi: 10.1016/j.apcata.2016.05.016
14. [14]
  Peyrovi M H, Toosi M R. React. Kinet. Catal. Lett., 2008, 94:115-119 doi: 10.1007/s11144-008-5277-7
15. [15]
  Louloudi A, Papayannakos N. Appl. Catal. A, 2000, 204:167-176 doi: 10.1016/S0926-860X(00)00516-0
16. [16]
  Zielinski M. Appl. Catal. A, 2012, 449:15-22 doi: 10.1016/j.apcata.2012.09.033
17. [17]
  Savva P G, Goundani K, Vakros M, et al. Appl. Catal. B, 2008, 79:199-207 doi: 10.1016/j.apcatb.2007.10.023
18. [18]
  XU Lei-Jin, KONG Ling-Niao, LIU Wei, et al. Chemical Production and Technology, 2013, 20:36-41 doi: 10.3969/j.issn.1006-6829.2013.06.010
19. [19]
  Wang X F, Wang F, Chen M Y, et al. J. Fuel Chem. Technol., 2005, 33:612-616
20. [20]
  Huo L F, Wang X F, Hou X Y, et al. J. Fuel Chem. Technol., 2007, 35:595-598
21. [21]
  Han X, Zhou R, Lai G H, et al. Catal. Today, 2004, 93:433-437
22. [22]
  Li Y, Zhou R X, Lai G H. React. Kinet. Catal. Lett., 2006, 88:105-110 doi: 10.1007/s11144-006-0116-1
23. [23]
  Xue J, Cui F, Huang Z W, et al. Chin. J. Catal., 2012, 33:1642-1649 doi: 10.1016/S1872-2067(11)60434-8
24. [24]
  Tümer H V, Feuge R O, Cousins E R. J. Am. Oil Chem. Soc., 1964, 41:212-214 doi: 10.1007/BF03024651
25. [25]
  Knies S, Berweiler M, Panster P, et al. Stud. Surf. Sci. Catal., 2000, 130:2249-2254 doi: 10.1016/S0167-2991(00)80803-4
26. [26]
  Chai M Q, Liu X Y, Li L, et al. Chin. J. Catal., 2017, 38:1338-1346 doi: 10.1016/S1872-2067(17)62869-9
27. [27]
  Cai B, Zhou X C, Miao Y C, et al. ACS Sustainable Chem. Eng., 2017, 5:1322-1331 doi: 10.1021/acssuschemeng.6b01677
28. [28]
  Baijot V, Mehdi D R, Rossi C, et al. Combust. Flame, 2017, 180:10-19 doi: 10.1016/j.combustflame.2017.02.031
29. [29]
  Bian Z, Kawi S. ChemCatChem, 2017, 10:320-328
30. [30]
  Jiang B, Zhang C, Wang K Q, et al. Appl. Therm. Eng., 2016, 109:99-108 doi: 10.1016/j.applthermaleng.2016.08.041
31. [31]
  FANG Jie, LI Na, CHENG Lang, et al. Journal of Fuel Chemistry and Technology, 2019, 47:725-736 doi: 10.3969/j.issn.0253-2409.2019.06.010
32. [32]
  Annette T, Bernd H. Top. Catal., 2002, 19:215-223 doi: 10.1023/A:1015324425793
33. [33]
  Stanciulescu M, Bulsink P, Caravaggio G, et al. Appl. Surf. Sci., 2014, 300:201-207 doi: 10.1016/j.apsusc.2014.01.175
34. [34]
  Wang D, Zhang Y, Li H T. J. Catal., 2012, 33:1229-1235
35. [35]
  Tanielyan S K, Santosh R M, Augustine R L, et al. Org. Process Res. Dev., 2017, 21:327-335 doi: 10.1021/acs.oprd.6b00375
36. [36]
  Chaudhari R V, Jaganathan R, Kolhe D S, et al. Appl. Catal. A, 1987, 29:141-159 doi: 10.1016/S0166-9834(00)82613-5
37. [37]
  Telkar M M, Rode C V, Rane V H, et al. Appl. Catal. A, 2001, 216:13-22 doi: 10.1016/S0926-860X(01)00547-6
1. [1]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
2. [2]
  Keke Han , Wenjun Rao , Xiuli You , Haina Zhang , Xing Ye , Zhenhong Wei , Hu Cai . Two new high-temperature molecular ferroelectrics [1,5-3.2.2-Hdabcni]X (X = ClO₄⁻, ReO₄⁻). Chinese Chemical Letters, 2024, 35(6): 108809-. doi: 10.1016/j.cclet.2023.108809
3. [3]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323
4. [4]
  Peiyan Zhu , Yanyan Yang , Hui Li , Jinhua Wang , Shiqing Li . Rh(Ⅲ)‐Catalyzed sequential ring‐retentive/‐opening [4 + 2] annulations of 2H‐imidazoles towards full‐color emissive imidazo[5,1‐a]isoquinolinium salts and AIE‐active non‐symmetric 1,1′‐biisoquinolines. Chinese Chemical Letters, 2024, 35(10): 109533-. doi: 10.1016/j.cclet.2024.109533
5. [5]
  Bairu Meng , Zongji Zhuo , Han Yu , Sining Tao , Zixuan Chen , Erik De Clercq , Christophe Pannecouque , Dongwei Kang , Peng Zhan , Xinyong Liu . Design, synthesis, and biological evaluation of benzo[4,5]thieno[2,3-d]pyrimidine derivatives as novel HIV-1 NNRTIs. Chinese Chemical Letters, 2024, 35(6): 108827-. doi: 10.1016/j.cclet.2023.108827
6. [6]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
7. [7]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
8. [8]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
9. [9]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
10. [10]
  Zhirong Yang , Shan Wang , Ming Jiang , Gengchen Li , Long Li , Fangzhi Peng , Zhihui Shao . One stone three birds: Ni-catalyzed asymmetric allenylic substitution of allenic ethers, hydroalkylation of 1,3-enynes and double alkylation of enynyl ethers. Chinese Chemical Letters, 2024, 35(8): 109518-. doi: 10.1016/j.cclet.2024.109518
11. [11]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2023.100309
12. [12]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
13. [13]
  Wujun Jian , Mong-Feng Chiou , Yajun Li , Hongli Bao , Song Yang . Cu-catalyzed regioselective diborylation of 1,3-enynes for the efficient synthesis of 1,4-diborylated allenes. Chinese Chemical Letters, 2024, 35(5): 108980-. doi: 10.1016/j.cclet.2023.108980
14. [14]
  Hai-Yang Song , Jun Jiang , Yu-Hang Song , Min-Hang Zhou , Chao Wu , Xiang Chen , Wei-Min He . Supporting-electrolyte-free electrochemical [2 + 2 + 1] annulation of benzo[d]isothiazole 1,1-dioxides, N-arylglycines and paraformaldehyde. Chinese Chemical Letters, 2024, 35(6): 109246-. doi: 10.1016/j.cclet.2023.109246
15. [15]
  Zhiwei Chen , Heyun Sheng , Xue Li , Menghan Chen , Xin Li , Qiuling Song . Efficient capture of difluorocarbene by pyridinium 1,4-zwitterionic thiolates: A concise synthesis of difluoromethylene-containing 1,4-thiazine derivatives. Chinese Chemical Letters, 2024, 35(4): 108937-. doi: 10.1016/j.cclet.2023.108937
16. [16]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
17. [17]
  Jun Xiong , Ke-Ke Chen , Neng-Bin Xie , Wei Chen , Wen-Xuan Shao , Tong-Tong Ji , Si-Yu Yu , Yu-Qi Feng , Bi-Feng Yuan . Demethylase-assisted site-specific detection of N¹-methyladenosine in RNA. Chinese Chemical Letters, 2024, 35(5): 108953-. doi: 10.1016/j.cclet.2023.108953
18. [18]
  Ling-Hao Zhao , Hai-Wei Yan , Jian-Shuang Jiang , Xu Zhang , Xiang Yuan , Ya-Nan Yang , Pei-Cheng Zhang . Effective assignment of positional isomers in dimeric shikonin and its analogs by ¹H NMR spectroscopy. Chinese Chemical Letters, 2024, 35(5): 108863-. doi: 10.1016/j.cclet.2023.108863
19. [19]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
20. [20]
  An Lu , Yuhao Guo , Yi Yan , Lin Zhai , Xiangyu Wang , Weiran Cao , Zijie Li , Zhixia Zhao , Yujie Shi , Yuanjun Zhu , Xiaoyan Liu , Huining He , Zhiyu Wang , Jian-Cheng Wang . Nanomedicine integrating the lipidic derivative of 5-fluorouracil, miriplatin and PD-L1 siRNA for enhancing tumor therapy. Chinese Chemical Letters, 2024, 35(6): 108928-. doi: 10.1016/j.cclet.2023.108928

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(980)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142