Citation: PENG Xiong-Xin, WANG Wen-Min, ZHONG Yu-Fei, XIAO Wei, BAO Guang-Ming, YUAN Hou-Qun. Synthesis, Crystal Structures of Two Lanthanides Complexes with 2, 6-Difluorobenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 921-926. doi: 10.11862/CJIC.2020.097 shu

Synthesis, Crystal Structures of Two Lanthanides Complexes with 2, 6-Difluorobenzoic Acid

1.
School of Science, Jiangxi Agricultural University, Nanchang 330045, China
2.
Assets and Laboratory management, Jiangxi Agricultural University, Nanchang 330045, China
3.
School of Animal Science and Technology, Jiangxi Agricultural University, Nanchang 330045, China

Corresponding author: YUAN Hou-Qun, hqyuan2014@126.com
Received Date: 24 October 2019
Revised Date: 26 December 2019

Figures(3)

Two complexes[Tm(dfba)₂(phen)(μ₂-dfba)]₂ (1) and[Yb(dfba)₂(phen)(μ₂-dfba)]₂ (2) (dfba^-=2, 6-difluoro-benzoate and phen=1, 10-phenanthroline) were synthesized by the reaction of 2, 6-difluorobenzote and phenan-throline with Tm³⁺ and Yb³⁺ ions, respectively. The complexes 1 and 2 were characterized by elemental analysis, FT-IR spectra, thermal gravimetric analysis (TGA) and their crystal structures were determined by single X-ray diffraction. The crystal structures analysis indicated that the complexes 1 and 2 are isostructural. Each Ln³⁺ is coordinated with two dfba^- ligands and one phen molecule to form a[Ln(dfba)₂(phen)]⁺ unit, and the neighboring two[Ln(dfba)₂(phen)]⁺ units are bridged by two different dfba^- ligands to form a binuclear molecule, [Ln(dfba)₂(phen)(μ₂-dfba)]₂ (Ln=Tm, Yb).
- 2, 6-difluorobenzoicacid,
- 1, 10-phenanthroline,
- Tm³⁺,
- Yb³⁺,
- crystal structure
1. [1]
  Wu Y P, Xu G W, Li D S, et al. Inorg. Chem., 2017, 56(3):1402-1411
2. [2]
  Zeng C H, Wang J L, Yang Y Y, et al. J. Mater. Chem. C, 2014, 2:2235-2242 doi: 10.1039/C3TC32309A
3. [3]
  Park K H, Jang K, Son S U, et al. J. Am. Chem. Soc., 2006, 128(27):8740-8741 doi: 10.1021/ja062907o
4. [4]
  Farrusseng D, Aguado S, Pinel C. Angew Chem. Int. Ed., 2009, 48(41):7502-7513 doi: 10.1002/anie.200806063
5. [5]
  Ji X Q, Ma F, Xiong J, et al. Inorg. Chem. Front., 2019, 6:786-790 doi: 10.1039/C8QI01331D
6. [6]
  Su Q Q, Fan K, Jin X X, et al. Inorg. Chem. Front., 2019, 6:1142-1452
7. [7]
  Lee J Y, Olson D H, Pan L, et al. Adv. Funct. Mater., 2007, 17(8):1255-1262 doi: 10.1002/adfm.200600944
8. [8]
  Li J R, Kuppler R J, Zhou H C. Chem. Soc. Rev., 2009, 38(5):1477-1504 doi: 10.1039/b802426j
9. [9]
  Khistiaeva V V, Melnikov A S, Slaxoxa O S, et al. Inorg. Chem. Front., 2018, 5:3015-3027 doi: 10.1039/C8QI00712H
10. [10]
  Raizada M, Sama F, Ashafaq M, et al. Polyhedron, 2018, 139:131-141 doi: 10.1016/j.poly.2017.09.052
11. [11]
  YANG Jian, TAO Jia-Yu, XING Guo-Xiang, et al. Chinese J. Inorg. Chem., 2018, 34(7):1312-1318
12. [12]
  LIU Li-Juan, WANG Yan, HE Jian-Bo. Chinese J. Inorg. Chem., 2017, 33(8):1374-1380
13. [13]
  Leng J D, Liu J L, Tong M L. Chem. Comm., 2012, 48:5286-5288 doi: 10.1039/c2cc30521f
14. [14]
  Majeed Z, Mondal K C, Kostakis G E, et al. Chem. Comm., 2010, 46:2551-2553 doi: 10.1039/b923998g
15. [15]
  Kalyakina A S, Utochnikova V V, Bushmarinov I S, et al. Chem. Eur. J., 2017, 23:14944-14953 doi: 10.1002/chem.201703543
16. [16]
  Li X, Zou Y Q, Song H B, et al. Acta Crystallogr. Sect. C, 2004, C60:m110
17. [17]
  Li X, Zhang Z Y, Zou Y Q. Eur. J. Inorg. Chem., 2005:2909-2918 doi: 10.1002/ejic.200500001
18. [18]
  Li X, Zhang Z Y. J. Chem. Cryst., 2005, 35(11):871-874 doi: 10.1007/s10870-005-4557-6
19. [19]
  Li X, Zhang Z Y, Song H B. J. Mol. Struct., 2005, 751:33-40 doi: 10.1016/j.molstruc.2005.05.005
20. [20]
  Li J J, Fan T T, Qu X L, et al. Dalton Trans., 2016, 45:2924-2935 doi: 10.1039/C5DT04262C
21. [21]
  Wu W H, Lin D, Yan Z. Z. Kristallogr.-New Cryst. Struct., 2016, 231(3):823-826
22. [22]
  Utochnikova V V, Solodukhin N N, Aslandukov A N, et al. Org. Electron., 2017, 44:85-93 doi: 10.1016/j.orgel.2017.01.026
23. [23]
  Kalyakina A S, Utochnikova V V, Bushmarinov I S, et al. Chem. Eur. J., 2017, 23:4944-14953 doi: 10.1002/chem.201701092
24. [24]
  Song J, Wu X, Li X. J. Rare Earths, 2009, 27(6):1092-1095 doi: 10.1016/S1002-0721(08)60395-6
25. [25]
  Wu X S, Zhang Y B, Li X, et al. J. Coord. Chem., 2009, 62(5):797-807 doi: 10.1080/00958970802360988
26. [26]
  Hao L, Liu X. Acta Crystallogr. Sect. E, 2009, E65:m150 doi: 10.1107/S1600536808035174
27. [27]
  WU Xiao-Shuo, LI Xia. Chinese J. Inorg. Chem., 2008, 24(10):1621-1625 doi: 10.3321/j.issn:1001-4861.2008.10.012
28. [28]
  Karipides A G, Jai-nhuknan J, Cantrell J S. Acta Crystallogr. Sect. C, 1996, C52:2740-2742 doi: 10.1107/S0108270196008852
29. [29]
  Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
30. [30]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
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