Citation: JI Chong-Xing, ZHU De-Cheng, CHEN Yi-Xin, ZHU Xian-Yu, HUANG Ji-Chung, LI De-Cheng. Improved Electrochemical Properties of MgMn₂O₄ Through AZO-Coating via Sol-gel Method[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 841-849. doi: 10.11862/CJIC.2020.096 shu

Improved Electrochemical Properties of MgMn₂O₄ Through AZO-Coating via Sol-gel Method

College of Energy, Soochow University, Suzhou, Jiangsu 215006, China

Corresponding author: LI De-Cheng, lidecheng@suda.edu.cn
Received Date: 12 November 2019
Revised Date: 24 February 2020

Figures(12)

The effects of AZO coating on its structure, morphology and electrochemical properties of the MgMn₂O₄ were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), charge and discharge tests and so on. It is shown that Al-doped ZnO (AZO) coating can effectively improve both the electronic conductivity and Li⁺ diffusion, consequently improved its rate capability. Moreover, AZO coating can also remain the continuous conductive network of the electrode, therefore improve its cyclic stability. The reversible capacity of 5%(w/w) AZO-coated MgMn₂O₄ was 590.3 mAh·g^-1 after 200 cycles, much higher than that of the bare MgMn₂O₄ (295.9 mAh·g^-1) and the reported value in literatures.
- lithium-ion battery,
- anode material,
- binary manganese-based spinel structure,
- sol-gel method,
- AZO
1. [1]
  Liu W, Farrington G C, Chaput F, et al. J. Electrochem. Soc., 1996, 143(3):879-884
2. [2]
  Sathiya M, Hemalatha K, Ramesha K, et al. Chem. Mater., 2012, 24(10):1846-1853 doi: 10.1021/cm300466b
3. [3]
  Hu Y S, Adelhelm P, Smarsly B M, et al. Adv. Funct. Mater., 2007, 17(12):1873-1878 doi: 10.1002/adfm.200601152
4. [4]
  Reddy A L, Shaijumon M, Gowda S R, et al. Nano Lett., 2009, 9(3):1002 doi: 10.1021/nl803081j
5. [5]
  Ding Y L, Xie J, Cao G S, et al. Adv. Funct. Mater., 2011, 21(2):348-355
6. [6]
  Poizot P, Laruelle S, Grugeon S, et al. Nature, 2000, 407:496-499 doi: 10.1038/35035045
7. [7]
  Etacheri V, Marom R, Elazari R, et al. Energy Environ. Sci., 2011, 4:3242-3262
8. [8]
  Li L, Jiang G X, Ma J M, et al. Mater. Res. Bull., 2018, 104:53-59 doi: 10.1016/j.materresbull.2018.03.051
9. [9]
  Zhao H, Liu L, Xiao X L, et al. Solid State Sci., 2015, 39:23-28 doi: 10.1016/j.solidstatesciences.2014.11.006
10. [10]
  Zhang W J. J. Power Sources, 2011, 196(1):13-24 doi: 10.1016/j.jpowsour.2010.07.020
11. [11]
  ZHANG Long-Hai, HOU Lin-Rui, LIAN Lin, et al. Rare Metal Materials and Engineering, 2016, 45(7):1910-1916
12. [12]
  XIA Bin-Bo, QIU Guang-Chao, SUN Hong-Dan, et al. Chinese J. Inorg. Chem., 2014, 30(4):725-732
13. [13]
  GUO De-Shuang, CHEN Zi-Nan, WANG Deng-Kui, et al. Chinese Journal of Lasers, 2019, 46(4):132-136
14. [14]
  Soundharrajan V, Sambandam B, Kim S, et al. ACS Energy Lett., 2018, 3(8):1998-2004 doi: 10.1021/acsenergylett.8b01105
15. [15]
  Zhu X Y, Quan J B, Huang J C, et al. RSC Adv., 2018, 8(14):7361-7368 doi: 10.1039/C8RA00310F
16. [16]
  Ling C, Mizuno F. Chem. Mate., 2013, 25(15):3062-3071 doi: 10.1021/cm401250c
17. [17]
  Kevin L. Phys. Chem. Chem. Phys., 2015, 17:1637-1643 doi: 10.1039/C4CP04494K
18. [18]
  Zhang G Q, Yu L, Wu H B, et al. Adv. Mater., 2012, 24:4609-4613 doi: 10.1002/adma.201201779
19. [19]
  Feng C Q, Wang W, Chen X, et al. Electrochim. Acta, 2015, 178:847-855 doi: 10.1016/j.electacta.2015.08.070
20. [20]
  Park C M, Kim J H, Kim H, et al. Chem. Soc. Rev., 2010, 39(8):3115-3141 doi: 10.1039/b919877f
21. [21]
  Li D C, Kato Y, Kobayakawa K, et al. J. Power Sources, 2006, 160(2):1342-1348 doi: 10.1016/j.jpowsour.2006.02.080
22. [22]
  Chen C Q, Cui J Z, Duan H L, et al. Acta Mech. Solida Sin., 2011, 24(1):1-26
23. [23]
  Huang L, Waller G H, Ding Y, et al. Nano Energy, 2015, 11:64-70 doi: 10.1016/j.nanoen.2014.09.027
24. [24]
  Huang S Z, Cai Y, Jin J, et al. Nano Energy, 2015, 12:833-844 doi: 10.1016/j.nanoen.2015.01.040
25. [25]
  Huang G, Zhang F, Du X, et al. Chemistry, 2014, 20(35):112-149
26. [26]
  Luo L, Qiao H, Chen K, et al. Electrochim. Acta, 2015, 177:283-289 doi: 10.1016/j.electacta.2015.01.100
27. [27]
  Courtel F M, Abu-Lebdeh Y, Davidson I J. Electrochim. Acta, 2012, 71:123-127 doi: 10.1016/j.electacta.2012.03.108
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
3. [3]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
4. [4]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
6. [6]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
7. [7]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
8. [8]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
9. [9]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
10. [10]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
11. [11]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
12. [12]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
13. [13]
  Yu-Hang Miao , Zheng-Xu Zhang , Xu-Yi Huang , Yuan-Zhao Hua , Shi-Kun Jia , Xiao Xiao , Min-Can Wang , Li-Ping Xu , Guang-Jian Mei . Catalytic asymmetric dearomative azo-Diels–Alder reaction of 2-vinlyindoles. Chinese Chemical Letters, 2024, 35(4): 108830-. doi: 10.1016/j.cclet.2023.108830
14. [14]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
15. [15]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
16. [16]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
17. [17]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
18. [18]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
19. [19]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
20. [20]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1063)
HTML views(174)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Improved Electrochemical Properties of MgMn2O4 Through AZO-Coating via Sol-gel Method

Metrics

通讯作者: 陈斌, bchen63@163.com

Improved Electrochemical Properties of MgMn₂O₄ Through AZO-Coating via Sol-gel Method