Citation: WANG Zhi-Chao, SHANG Hong-Jing, GUO Guang-Zhi, TANG Jie, LI Song, WANG Xin-Yu, SUN Jun-Cai. Preparation and Performance of High Stability Cathode Material MnO₂@MgO for Aqueous Zinc-Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 857-863. doi: 10.11862/CJIC.2020.094 shu

Preparation and Performance of High Stability Cathode Material MnO₂@MgO for Aqueous Zinc-Ion Battery

Coellece of Transportation Engineering, Dalian Maritime University, Dalian, Liaoning 116026, China

Corresponding author: LI Song, lisong@dlmu.edu.cn
Received Date: 3 December 2019
Revised Date: 4 March 2020

Figures(8)

MnO₂@MgO core-shell microspheres were synthesized by coprecipitation method and pyrolytic process. The materials were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM). It is found that MgO coating did not change the microstructure of MnO₂, and the coating layer was composed of nanoparticles with a thickness of about 50 nm. As a result, electrochemical property showed that the discharge specific capacity of the coated material was obviously improved. The maximum discharge specific capacity was 274.3 mAh·g^-1 at the current density of 100 mA·g^-1, which was 12.8% higher than that of the uncoated material. Meanwhile, the coated material exhibited excellent cycle stability with 84.1% discharge specific capacity retention after 500 cycles at the current density of 1 000 mA·g^-1. Obviously, the MgO coating layer prevents directly contact between MnO₂ and electrolyte, and suppresses the dissolution of manganese during the charge and discharge process, thus significantly improves the cycle performance of MnO₂.
- manganese dioxide,
- coprecipitation method,
- pyrolytic process,
- coating,
- aqueous zinc-ion battery
1. [1]
  Kundu D, Adams B D, Duffort V, et al. Nat. Energy, 2016, 1(10):16119 doi: 10.1038/nenergy.2016.119
2. [2]
  Konarov A, Voronina N, Jo J H, et al. ACS Energy Lett., 2018, 3(10):2620-2640 doi: 10.1021/acsenergylett.8b01552
3. [3]
  Ingale N D, Gallaway J W, Nyce M, et al. J. Power Sources, 2015, 276:7-18 doi: 10.1016/j.jpowsour.2014.11.010
4. [4]
  Wang X Y, Ma L W, Sun J C. ACS Appl. Mater. Interfaces, 2019, 11(44):41297-41303 doi: 10.1021/acsami.9b13103
5. [5]
  Wang X Y, Ma L W, Sun J C, et al. Appl. Surf. Sci., 2020, 502:144207 doi: 10.1016/j.apsusc.2019.144207
6. [6]
  Liu Z, Pulletikurthi G, Endres F, et al. ACS Appl. Mater. Interfaces, 2016, 8(19):12158-12164 doi: 10.1021/acsami.6b01592
7. [7]
  Sun Y, Zhang J J, Sun X N, et al. CrystEngComm, 2019, 21:7468-7475 doi: 10.1039/C9CE01407A
8. [8]
  FENG Xiao-Miao, YAN Zhen-Zhen, CHEN Ning-Na. Chinese J. Inorg. Chem., 2014, 30(11):2509-2515
9. [9]
  Lee S Y, Wu L, Poyraz A S, et al. Adv. Mater., 2017, 29(43):1703186 doi: 10.1002/adma.201703186
10. [10]
  Sun Y, Huang N B, Sun X N, et al. Int. J. Hydrogen Energy, 2017, 42:20016-20025 doi: 10.1016/j.ijhydene.2017.05.234
11. [11]
  Zhang N, Cheng F Y, Liu J X, et al. Nat. Commun., 2017, 8(1):405
12. [12]
  Tang B Y, Shan L T, Liang S Q, et al. Energy. Environ. Sci., 2019, 12:3288-3304 doi: 10.1039/C9EE02526J
13. [13]
  Alfaruqi M H, Islam S, Putro D Y, et al. Electrochim. Acta, 2018, 276:1-11 doi: 10.1016/j.electacta.2018.04.139
14. [14]
  Wu B K, Zhang G B, Mai L Q, et al. Small, 2018, 14(13):1703850 doi: 10.1002/smll.201703850
15. [15]
  Fu Y Q, Wei Q L, Sun S H, et al. Adv. Energy Mater., 2018, 8(26):1801445 doi: 10.1002/aenm.201801445
16. [16]
  HUANG Ji-Chun, MEI Lin, MA Zheng, et al. Chinese J. Inorg. Chem., 2017, 33(7):1236-1242
17. [17]
  XIA Bing-Bo, QIU Guang-Chao, SUN Hong-Dan, et al. Chinese J. Inorg. Chem., 2014, 30(4):725-732
18. [18]
  Jiang Y, Yang Z, Luo W, et al. Phys. Chem. Chem. Phys., 2013, 15(8):2954-2960 doi: 10.1039/c2cp44394e
19. [19]
  Huang S, Tu J P, Jian X M, et al. J. Power Sources, 2014, 245:698-705 doi: 10.1016/j.jpowsour.2013.07.032
20. [20]
  Yu P, Zhang X, Chen Y, et al. Mater. Lett., 2010, 64(1):61-64 doi: 10.1016/j.matlet.2009.10.007
21. [21]
  Zhang N, Cheng F, Liu Y C, et al. J. Am. Chem. Soc., 2016, 138(39):12894-12901 doi: 10.1021/jacs.6b05958
22. [22]
  Jin G Z, Xiao X X, Li S, et al. Electrochim. Acta, 2015, 178:689-698 doi: 10.1016/j.electacta.2015.08.032
23. [23]
  ZHANG Ying-Jie, XIA Shu-Biao, DONG Peng, et al. Chinese J. Inorg. Chem., 2014, 30(3):529-535
24. [24]
  Han E S, Li Y P, Zhu L Z, et al. Solid State Ionics, 2014, 255:113-119 doi: 10.1016/j.ssi.2013.12.018
25. [25]
  Jiang B Z, Xu C J, Wu C L, et al. Electrochim. Acta, 2017, 229:422-428 doi: 10.1016/j.electacta.2017.01.163
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Preparation and Performance of High Stability Cathode Material MnO₂@MgO for Aqueous Zinc-Ion Battery