Citation: WANG Zhi-Chao, SHANG Hong-Jing, GUO Guang-Zhi, TANG Jie, LI Song, WANG Xin-Yu, SUN Jun-Cai. Preparation and Performance of High Stability Cathode Material MnO₂@MgO for Aqueous Zinc-Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 857-863. doi: 10.11862/CJIC.2020.094 shu

Preparation and Performance of High Stability Cathode Material MnO₂@MgO for Aqueous Zinc-Ion Battery

Coellece of Transportation Engineering, Dalian Maritime University, Dalian, Liaoning 116026, China

Corresponding author: LI Song, lisong@dlmu.edu.cn
Received Date: 3 December 2019
Revised Date: 4 March 2020

Figures(8)

MnO₂@MgO core-shell microspheres were synthesized by coprecipitation method and pyrolytic process. The materials were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM). It is found that MgO coating did not change the microstructure of MnO₂, and the coating layer was composed of nanoparticles with a thickness of about 50 nm. As a result, electrochemical property showed that the discharge specific capacity of the coated material was obviously improved. The maximum discharge specific capacity was 274.3 mAh·g^-1 at the current density of 100 mA·g^-1, which was 12.8% higher than that of the uncoated material. Meanwhile, the coated material exhibited excellent cycle stability with 84.1% discharge specific capacity retention after 500 cycles at the current density of 1 000 mA·g^-1. Obviously, the MgO coating layer prevents directly contact between MnO₂ and electrolyte, and suppresses the dissolution of manganese during the charge and discharge process, thus significantly improves the cycle performance of MnO₂.
- manganese dioxide,
- coprecipitation method,
- pyrolytic process,
- coating,
- aqueous zinc-ion battery
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Preparation and Performance of High Stability Cathode Material MnO2@MgO for Aqueous Zinc-Ion Battery

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Preparation and Performance of High Stability Cathode Material MnO₂@MgO for Aqueous Zinc-Ion Battery