Citation: ZHANG Lin, WANG Jing, TANG Yan-Ping, GUO Yu-Zhong, HUANG Rui-An. Preparation and Li⁺-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 893-900. doi: 10.11862/CJIC.2020.092 shu

Preparation and Li⁺-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure

1.
College of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Guizhou University of Commerce, Guiyang 550000, China
3.
National Engineering Laboratory for Vacuum Metallurgy, Kunming 650093, China

Corresponding author: GUO Yu-Zhong, yzguocn62@sina.com; HUANG Rui-An,
Received Date: 16 December 2019
Revised Date: 28 February 2020

Figures(7)

In this paper, an ordered mesoporous Si/C composite structure was prepared successfully for the anode materials of Li-ion batteries through the synthesis of SiO₂-ordered mesoporous precursor (SiO₂-OMPs) by a P123-copolymer templet route and then a magnesiothermic reduction reaction (MRR) for the SiO₂-OMPs precursor and ensuing a phenolic-resin based carbon-capsuling treatment. From the observations of SEM/TEM, it is found that the morphology of SiO₂-OMPs can be got well-controlled by HCl concentration and obtained a short rod with densified geometrical stacking under high acid concentration, and the ordered mesoporous symmetry kept unchanged perfectly through later MRR and C-capsuling routes. In addition, the detailed and reasonable analyses based on XRD data reveal that MRR process consists of two-step serial reactions:the Mg₂Si intermediate formation from Mg and SiO₂ reactants and its transition to final Si products by re-reducing SiO₂. The slow feature of the solid/solid diffusive reaction in the second step restrains the completion of whole reduction process, resulting in a low yield of silicon and the existence of some impurity phases. Electrochemical measurements show that the ordered mesoporous Si/C composite exhibited excellent cyclic stability and rate performance, which can be attributed to the robust architect and unblocked mesopore system within such composite structure.
- Si/C composite structure,
- mesoporous materials,
- lithium ion battery,
- anode material,
- electrochemistry
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Li+-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure

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通讯作者: 陈斌, bchen63@163.com

Preparation and Li⁺-Storage Behaviour of Ordered Mesoporous Si/C Composite Structure