Citation: WANG Jia-Hong, CHEN Yao, LIU Ning, SUN Tong-Tong, Atif Saleem. Chitosan Modified Magnetic Carbon-Based Adsorbent: Preparation and Adsorption Mechanism for Cr(Ⅲ)-EDTA in Water[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1249-1258. doi: 10.11862/CJIC.2020.091 shu

Chitosan Modified Magnetic Carbon-Based Adsorbent: Preparation and Adsorption Mechanism for Cr(Ⅲ)-EDTA in Water

WANG Jia-Hong ^1,2,, ,
CHEN Yao ^1,2 ,
LIU Ning ^1,2 ,
SUN Tong-Tong ^1,2 ,
Atif Saleem ^1,2

1.
College of Environmental Science and Engineering, Shaanxi University of Science&Technology, Xi'an 710021, China
2.
Shaanxi Key Laboratory of Green Preparation and Functionalization of Inorganic Materials, Xi'an 710021, China

Corresponding author: WANG Jia-Hong, wangjiahong@sust.edu.cn
Received Date: 30 October 2019
Revised Date: 6 March 2020

Figures(15)

The magnetic carbon-based material (Fe₃O₄@C) was prepared by using ferrocene, and chitosan (CS) modified Fe₃O₄@C composite adsorbent (Fe₃O₄@C-CS) was prepared. The characterization of Fe₃O₄@C-CS by nfrared spectroscopy (FTIR), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), thermogravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS), and the adsorption performance for Cr (Ⅲ)-EDTA in water was systematically studied by initial concentrations, adsorption temperature, time, solution pH and cations. The results show that Fe₃O₄@C has been successfully functionalized by CS. Adsorption isotherm was in accordance with the Langmuir model and the theoretical maximum adsorption capacity was 12.63 mg·g^-1 at 25℃, pH=4.0 and dosage of 0.4 g·L^-1. The adsorption kinetics can be fitted well with the pseudo-second kinetic model, and adsorption behavior is a spontaneous endothermic process. Based on the XPS analysis and adsorption experiments, the electrostatic interaction and surface complexation was the main mechanism of Cr(Ⅲ)-EDTA adsorption on Fe₃O₄@CCS adsorbent. After four adsorption and desorption cycles, Fe₃O₄@C-CS still had high adsorption efficiency for Cr(Ⅲ)EDTA in water.
- chitosan,
- magnetic carbon-based adsorbent,
- Cr(Ⅲ)-EDTA,
- adsorption,
- cations,
- kinetics
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