Citation: LING Ling, JIANG Qi-Qi, BAIYIN Meng-He. Solvothermal Synthesis and Characterization of Quaternary Selenides K₈Cd_2.79Hg_9.21Se₁₆ and Rb₄Hg_3.04Cd_2.96Se₈ Containing Cadmium and Mercury[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 811-818. doi: 10.11862/CJIC.2020.090 shu

Solvothermal Synthesis and Characterization of Quaternary Selenides K₈Cd_2.79Hg_9.21Se₁₆ and Rb₄Hg_3.04Cd_2.96Se₈ Containing Cadmium and Mercury

College of Chemistry & Environmental Science, Innner Mongolia Normal University, Hohhot 010022, China

Corresponding author: BAIYIN Meng-He, baiymh@imnu.edu.cn
Received Date: 29 July 2019
Revised Date: 7 January 2020

Figures(6)

Two-dimensional (2D) quaternary selenides containing cadmium mercury, K₈Cd_2.79Hg_9.21Se₁₆ (1) and Rb₄Hg_3.04Cd_2.96Se₈ (2), were synthesized utilizing solvothermal method. Single crystal X-ray analyses reveal that compound 1 crystallizes in the orthorhombic space group Pbcn, with a=1.082 71(17) nm, b=0.678 73(10) nm, c=1.415 0(2) nm, Z=1; compound 2 crystallizes in the orthorhombic space group Ibam, with a=0.640 72(10) nm, b=1.160 25(16) nm, c=1.452 0(2) nm, Z=2. Compound 1 contains anion layer (Cd_2.79Hg_9.21Se₁₆)_n^8n- of eight-membered ring Cd₂Hg₂Se₄ and six-membered ring CdHg₂Se₃. Compound 2 contains anion layer (Hg_3.04Cd_2.96Se₈)_n^4n- of eight-membered ring Cd₂(Cd/Hg)₂Se₄, four-membered ring CdHgSe₂ and (Cd/Hg)₂Se₂. These two compounds were structurally characterized by scanning electron micrograph and energy-dispersive X-ray spectroscopy analysis, powder X-ray diffraction measurement, thermal analysis, solid-state optical diffuse reflectance and fluorescence properties.
- quaternary selenides,
- solvothermal synthesis,
- crystal structure,
- fluorescence properties
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Solvothermal Synthesis and Characterization of Quaternary Selenides K8Cd2.79Hg9.21Se16 and Rb4Hg3.04Cd2.96Se8 Containing Cadmium and Mercury

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通讯作者: 陈斌, bchen63@163.com

Solvothermal Synthesis and Characterization of Quaternary Selenides K₈Cd_2.79Hg_9.21Se₁₆ and Rb₄Hg_3.04Cd_2.96Se₈ Containing Cadmium and Mercury