Citation: LI Rui, SUN Xiao-Gang, ZOU Jing-Yi, HE Qiang. NMAP Interlayer for Inhibiting Shuttle Effect of Lithium-Sulfur Battery[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 673-680. doi: 10.11862/CJIC.2020.088 shu

NMAP Interlayer for Inhibiting Shuttle Effect of Lithium-Sulfur Battery

School of Mechantronics Engineering, Nanchang University, Nanchang 330031, China

Corresponding author: SUN Xiao-Gang, xiaogangsun@163.com
Received Date: 12 September 2019
Revised Date: 26 February 2020

Figures(7)

Nano-NiO was prepared by hydrothermal synthesis and cross-linked with multi-walled carbon nanotubes (MWCNTs) and aramid paper (AP) to form a novel composite interlayer (NMAP). The NMAP interlayer has a three-dimensional porous structure, which not only reduces the loss of active materials, but also captures soluble polysulfides; NMAP material has strong chemical adsorption capacity for adsorbing polysulfide. The morphology and structure of the composite interlayer were observed by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD). The electrochemical test results showed that the first discharge capacity of electrode with NMAP interlayer reached 1 437 mAh·g^-1 at a rate of 0.05C, and the utilization rate of active material was as high as 85.8%. The specific discharge capacity still reached 668 mAh·g^-1 at 4C, and the coulomb efficiency remained at 99.1%, showing excellent magnification and cycling performance.
- lithium-sulfur batteries,
- shuttle effect,
- lithium polysulfides,
- carbon nanotube,
- interlayer
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